Ref. Ares(2021)2234504 - 31/03/2021
EUROPEAN COMMISSION
DIRECTORATE-GENERAL
JOINT RESEARCH CENTRE
Directorate B – Growth and Innovation
Circular Economy and Industrial Leadership
Seville, 31 March 2021
Final meeting of the Technical Working Group (TWG)
for the review of the BAT reference document
for the Textiles Industry (TXT BREF)
25 May – 11 June 2021 (tentative)
BACKGROUND PAPER (BP)
Purpose of this background paper and of the final Technical Working Group (TWG)
meeting
The objective of this background paper is to outline the main issues proposed to be discussed at
the final meeting of the Technical Working Group for the review of the BAT reference
document for
‘the Textiles Industry' (TXT BREF) under the Industrial Emissions Directive
(IED) (2010/75/EU).
The meeting is intended to be held as web-based meeting in the period 25 May to 11 June 2021
with the objective of agreeing upon the remaining work needed to finalise the review of the
TXT BREF. In particular, it is proposed that the TWG meeting focuses on:
I. agreeing on the draft BAT conclusions and therefore on the actual text in Chapter 5 (and
related items) of the TXT BREF;
II. agreeing on the main corresponding modifications proposed for the sections on
'Techniques to consider in the determination of BAT';
III. identifying elements that should be mentioned in Chapter 7 of the TXT BREF (i.e.
Concluding remarks and recommendations for future work);
IV. agreeing upon the remaining work needed for finalising the BREF review.
This BP includes:
background information for the final TWG meeting;
a summary of the main TWG comments received on the first draft of the revised TXT BREF
(published in December 2019) and the EIPPCB assessment of those comments;
the proposed modifications to the draft TXT BREF resulting from the TWG members'
comments, focusing on the proposed changes to the draft BAT conclusions;
the proposals to include, when appropriate, in the Concluding remarks and recommendations
for future work chapter of the BREF.
Edificio Expo, C/ Inca Garcilaso, 3 – E-41092 Sevilla, Spain
Telephone: +34-954 488 284. Fax: +34-954 488 426.
E-mail: xxxxxxxxxxxxx@xx.xxxxxx.xx, Internet: http://eippcb.jrc.ec.europa.eu/
link to page 5 link to page 6 link to page 6 link to page 7 link to page 8 link to page 11 link to page 11 link to page 11 link to page 15 link to page 18 link to page 18 link to page 18 link to page 20 link to page 20 link to page 21 link to page 21 link to page 22 link to page 22 link to page 23 link to page 23 link to page 23 link to page 24 link to page 24 link to page 24 link to page 27 link to page 27 link to page 40 link to page 47 link to page 47 link to page 54 link to page 56 link to page 56 link to page 60 link to page 65 link to page 65 link to page 65 link to page 70 link to page 74 link to page 74 link to page 78 link to page 78 link to page 78 link to page 80 link to page 85 link to page 100 link to page 106 link to page 106 link to page 109
Background paper – Final meeting for the review of the TXT BREF
Table of contents
BACKGROUND INFORMATION ............................................................................... 2
BEFORE COMING TO THE MEETING ................................................................... 2
AIM AND STRUCTURE OF THIS BACKGROUND PAPER ................................. 2
WORKING PLAN .......................................................................................................... 2
ABBREVIATIONS FREQUENTLY USED IN THIS BACKGROUND PAPER .... 2
1 ITEMS PROPOSED FOR DISCUSSION AT THE FINAL TXT TWG
MEETING ................................................................................................................ 2
1.1
SCOPE ............................................................................................................................ 2
1.2
DEFINITIONS .................................................................................................................. 2
1.3
GENERAL CONSIDERATIONS .......................................................................................... 2
1.3.1
Emission levels associated with the best available techniques (BAT-AELs)
for emissions to air ............................................................................................... 2
1.3.2
Emission levels associated with the best available techniques (BAT-AELs)
for emissions to water .......................................................................................... 2
1.3.3
Specific energy consumption levels associated with the best available
techniques ............................................................................................................ 2
1.3.4
Specific water consumption levels associated with the best available
techniques ............................................................................................................ 2
1.3.5
Specific wool grease recovery level associated with the best available
techniques ............................................................................................................ 2
1.3.6
Caustic soda recovery level associated with the best available techniques ......... 2
1.4
GENERAL BAT CONCLUSIONS ...................................................................................... 2
1.4.1
Overall environmental performance .................................................................... 2
1.4.1.1
Techniques for improving the overall environmental performance ..........................2
1.4.2
Monitoring ........................................................................................................... 2
1.4.2.1
Monitoring emissions to water .................................................................................2
1.4.2.2
Monitoring channelled emissions to air ....................................................................2
1.4.3
Water use and waste water generation ................................................................. 2
1.4.3.1
Techniques for reducing water consumption and waste water generation ................2
1.4.3.2
BAT-AEPLs for specific water consumption ...........................................................2
1.4.4
Energy efficiency ................................................................................................. 2
1.4.4.1
Techniques for using energy efficiently ...................................................................2
1.4.4.2
Techniques for increasing energy efficiency of thermal treatment ...........................2
1.4.4.3
BAT-AEPLs for specific energy consumption .........................................................2
1.4.5
Chemicals ............................................................................................................ 2
1.4.5.1
Techniques for improving the overall environmental performance ..........................2
1.4.5.2
Techniques for reducing the consumption of chemicals ...........................................2
1.4.5.3
Techniques for preventing or reducing emissions to water of poorly
biodegradable substances ..........................................................................................2
1.4.6
Emissions to water ............................................................................................... 2
1.4.6.1
Techniques for reducing the waste water volume, the pollutant loads discharged
to the waste water treatment plant and the emissions to water .................................2
1.4.6.2
Techniques for reducing emissions to water .............................................................2
1.4.6.3
BAT-AELs for direct discharges to a receiving water body .....................................2
1.4.6.4
BAT-AELs for indirect discharges to a receiving water body ..................................2
1.4.7
Emissions to soil and groundwater ...................................................................... 2
1.4.7.1
Techniques to prevent or reduce emissions to soil and groundwater ........................2
1.4.8
Emissions to air .................................................................................................... 2
2
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 109 link to page 110 link to page 110 link to page 111 link to page 111 link to page 118 link to page 119 link to page 121 link to page 121 link to page 124 link to page 124 link to page 125 link to page 125 link to page 125 link to page 125 link to page 125 link to page 125 link to page 127 link to page 127 link to page 128 link to page 130 link to page 130 link to page 130 link to page 130 link to page 130 link to page 130 link to page 131 link to page 131 link to page 133 link to page 133 link to page 133 link to page 135 link to page 135 link to page 144 link to page 144 link to page 146 link to page 147 link to page 147 link to page 149 link to page 149 link to page 149 link to page 150 link to page 151 link to page 151 link to page 152 link to page 152 link to page 152 link to page 158 link to page 159 link to page 160 link to page 160
Background paper – Final meeting for the review of the TXT BREF
1.4.8.1
Techniques for reducing channelled emissions to air ............................................... 2
1.4.8.2
Techniques for reducing channelled emissions of organic compounds (e.g.
formaldehyde) to air ................................................................................................. 2
1.4.8.3
BAT-AELs for channelled emissions of organic compounds (e.g.
formaldehyde) to air ................................................................................................. 2
1.4.8.4
Techniques for reducing channelled dust emissions to air ....................................... 2
1.4.8.5
BAT-AEL for channelled dust emissions to air ....................................................... 2
1.4.8.6
Techniques for reducing channelled ammonia emissions to air ............................... 2
1.4.8.7
BAT-AEL for channelled ammonia emissions to air ............................................... 2
1.4.8.8
Techniques for reducing emissions of organic compounds to air from thermal
treatment of synthetic textile materials .................................................................... 2
1.5
BAT CONCLUSIONS FOR THE PRE-TREATMENT OF RAW WOOL FIBRES BY
SCOURING ..................................................................................................................... 2
1.5.1
Techniques for using resources efficiently and for reducing water
consumption and waste generation ..................................................................... 2
1.5.2
BAT-AEPLs for the recovery of wool grease from the pre-treatment of raw
wool fibres by scouring ....................................................................................... 2
1.6
BAT CONCLUSIONS FOR THE PRODUCTION OF YARN AND FABRIC ............................... 2
1.6.1
Techniques for reducing emissions to water ....................................................... 2
1.6.2
Techniques for using energy efficiently .............................................................. 2
1.7
BAT CONCLUSIONS FOR THE PRETREATMENT OF TEXTILE MATERIALS OTHER
THAN RAW WOOL FIBRES .............................................................................................. 2
1.7.1
Techniques for using energy efficiently and reducing water consumption and
waste water generation ........................................................................................ 2
1.7.2
Techniques for using resources and energy efficiently and reducing water
consumption and waste water generation ............................................................ 2
1.7.3
Techniques for preventing or reducing emissions to water of chlorine-
containing compounds and complexing agents ................................................... 2
1.7.4
Technique for using resources efficiently and for reducing the amount of
alkali discharged to the waste water treatment .................................................... 2
1.7.5
BAT-AEPL for the recovery of caustic soda used for mercerisation .................. 2
1.8
BAT CONCLUSIONS FOR DYEING .................................................................................. 2
1.8.1
Techniques for using resources efficiently and reducing emissions to water ..... 2
1.9
BAT CONCLUSIONS FOR FINISHING .............................................................................. 2
1.9.1
Finishing with flame-retardants .......................................................................... 2
1.9.2
Finishing with oil-, water- and soil-repellents ..................................................... 2
1.9.3
Shrink-proof finishing of wool ............................................................................ 2
1.9.4
Mothproofing ...................................................................................................... 2
2 ITEMS CONSIDERED TO BE LARGELY AGREED AND NOT
REQUIRING DISCUSSION AT THE FINAL TXT TWG MEETING ............. 2
2.1
ENTIRE BAT CONCLUSIONS.......................................................................................... 2
2.2
ACRONYMS ................................................................................................................... 2
2.3
GENERAL CONSIDERATIONS ......................................................................................... 2
2.3.1
Best Available Techniques .................................................................................. 2
2.4
GENERAL BAT CONCLUSIONS ...................................................................................... 2
2.4.1
Overall environmental performance .................................................................... 2
2.4.1.1
Techniques for improving the overall environmental performance ......................... 2
2.4.2
Monitoring ........................................................................................................... 2
2.4.2.1
Monitoring resource consumption, waste generation and material recovery ........... 2
2.4.2.2
Monitoring key parameters for relevant waste water streams .................................. 2
2.4.3
Water use and waste water generation ................................................................ 2
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
3
link to page 161 link to page 161 link to page 162 link to page 162 link to page 162 link to page 163 link to page 163 link to page 166 link to page 166 link to page 166 link to page 166 link to page 168 link to page 168 link to page 168 link to page 168 link to page 169 link to page 169 link to page 169 link to page 171 link to page 171 link to page 172 link to page 172 link to page 173 link to page 173 link to page 173 link to page 175 link to page 176 link to page 176 link to page 176 link to page 177 link to page 181
Background paper – Final meeting for the review of the TXT BREF
2.4.4
Energy efficiency ................................................................................................. 2
2.4.4.1
Techniques for increasing energy efficiency when using compressed air ................2
2.4.5
Emissions to air .................................................................................................... 2
2.4.5.1
Techniques to reduce diffuse VOC emissions to air .................................................2
2.4.5.2
Techniques to prevent emissions of organic compounds to air ................................2
2.4.6
Waste ................................................................................................................... 2
2.4.6.1
Techniques to prevent or reduce the quantity of waste .............................................2
2.5
BAT CONCLUSIONS FOR THE PRETREATMENT OF RAW WOOL FIBRES BY SCOURING ... 2
2.5.1
Techniques for using energy efficiently .............................................................. 2
2.5.2
Techniques for using resources efficiently and for reducing the amount of
waste sent for disposal ......................................................................................... 2
2.6
BAT CONCLUSIONS FOR THE PRODUCTION OF YARN AND FABRIC ............................... 2
2.6.1
Techniques for reducing emissions to air and water ............................................ 2
2.7
BAT CONCLUSIONS FOR THE PRETREATMENT OF TEXTILE MATERIALS OTHER
THAN RAW WOOL FIBRES ............................................................................................... 2
2.8
BAT CONCLUSIONS FOR PRINTING ................................................................................ 2
2.8.1
Techniques for reducing water consumption and waste water generation .......... 2
2.8.2
Techniques for using resources efficiently .......................................................... 2
2.8.3
Techniques for preventing ammonia emissions to air and preventing the
generation of urea-containing waste water .......................................................... 2
2.8.4
Techniques for reducing emissions of organic compounds (e.g.
formaldehyde) as well as of ammonia to air from printing with pigments .......... 2
2.9
BAT CONCLUSIONS FOR FINISHING ............................................................................... 2
2.9.1
Easy-care finishing .............................................................................................. 2
2.9.2
Softening .............................................................................................................. 2
2.10
BAT CONCLUSIONS FOR LAMINATION .......................................................................... 2
2.11
DESCRIPTION OF TECHNIQUE ........................................................................................ 2
2.11.1
Technique to monitor emissions to air ................................................................. 2
2.11.2
Techniques to reduce emissions to air ................................................................. 2
2.11.3
Techniques to reduce emissions to water............................................................. 2
2.11.4
Techniques to reduce the consumption of water, energy and chemicals ............. 2
4
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 5
Background paper – Final meeting for the review of the TXT BREF
Background information
The kick-off meeting for the review of the TXT BREF was held from 12-15 June 2018 in
Seville, Spain. The data collection process was officially scheduled from mid-February to end
of-April 2019.
The first draft of the revised TXT BREF was issued on 19 December 2019 and the consultation
period for TWG members ended on 20 March 2020. A total of 1072 comments (750 identified
as major and 322 as minor) were received by the EIPPCB and were made available to the whole
TWG through BATIS. Of these 1072 comments, 639 are addressed in this document, i.e. those
considered to have a bearing on the BAT conclusions.
The distribution of the comments received on the first draft of the revised TXT BREF is
summarised in
Table 1. Table 1: Distribution of the total number of comments submitted on the first draft of the revised
TXT BREF (version of December 2019)
Comments
BREF Chapter/Section
Percentage
Number
(%)
Whole document
9
0.8
Preface
0
0.0
Scope (BREF)
3
0.3
Chapter 1 – General information
14
1.3
Chapter 2 – Applied processes and techniques
45
4.2
Chapter 3 – Emission and consumption levels
29
2.7
Chapter 4 – Techniques to consider in the determination of
279
26.0
BAT
Chapter 5 – BAT conclusions
639
59.6
Chapter 6 – Emerging techniques
11
1.0
Chapter 7 – Concluding remarks and recommendations for
0
0.0
future work
Chapter 8 – Annex I: Textile auxiliaries
40
3.7
Chapter 9 – Annex II: Dyes and pigments
Chapter 10 – Annex III: Wet Processes: Machinery and
1
0.1
Techniques
Chapter 11 – Annex IV: Typical recipes (with some
0
0.0
associated emission factor) in the textile sector
Chapter 12 – Annex V: Typical pollutants (and potential
0
0.0
sources) in air emissions from textile processes
Chapter 13 – Annex VI: auxiliaries classification tools
0
0.0
Chapter 14 – Advanced oxidation processes (Fenton reaction)
0
0.0
Chapter 15 – Annex VII: Plants having taken part in the data
0
0.0
collection
Chapter 16 – Annex VIII: Wool carpet dyeing
0
0.0
Glossary
2
0.2
References
0
0.0
Total:
1072
100
All the comments received and the accompanying additional information have been assessed by
the EIPPCB and have been used in the preparation of this BP. An updated working draft of the
TXT BREF will be made available to the TWG prior to the final meeting.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
5
Background paper – Final meeting for the review of the TXT BREF
It is therefore recommended that TWG members print a coloured copy of this revised
draft as it will help them to identify text under discussion at the final TWG meeting.
Before coming to the meeting
As a TWG member, you should read this background paper (BP) and Chapter x before coming
to the meeting to determine your position on the identified issues. Final TWG meetings are
characterised by deep technical discussions and represent the last opportunity for the TWG to
discuss the contents of the BREF (and of the BAT conclusions in particular).
Whether or not your position differs from any proposal in this BP, you should come to the
meeting prepared to justify your position and,
if you have a different view, to present an
alternative proposal and the evidential basis for that proposal.
IMPORTANT: Please be advised to bring at least the following documents with you to the
meeting (all of these will be made available in BATIS) as the
EIPPCB will not be able to
provide you with printed copies:
this background paper;
the revised proposal for the BAT conclusions (coloured version);
the first draft of the revised TXT BREF dated December 2019 (coloured version);
the updated graphs/figures including the emission levels and other environmental
performance levels.
Aim and structure of this background paper
The aim of this background paper is to structure and enable efficient discussions at the final
TWG meeting. Some items relevant to the BAT conclusions are proposed for discussion at the
final TWG meeting (i.e. items under Section 1 of this BP) while other items are proposed to be
discussed only if requested in advance of the meeting (i.e. items listed in Section 2 of this BP).
Items are listed in Section 2 either because, based on the assessment of the TWG comments,
they refer to BAT conclusions that are not considered to be controversial and therefore do not
seem to require further discussion, or because they are not considered to have a specific bearing
on the text of the BAT conclusions (e.g. some methodological and implementation issues that
have already been discussed within the TXT TWG). Please note that the order of the discussion
items in this background paper will not necessarily be the order of the discussion at the meeting.
TWG members are requested to contact the EIPPCB at least 10 working days before the
TWG final meeting
(i.e. by 11 of May 2021) if they wish
to request the discussion of any
other items from Chapter 5 (i.e. BAT conclusions) at the meeting or to propose
additional agenda items for the meeting. Please note that the possibility of including
additional items in the meeting agenda is extremely limited due to time restrictions.
6
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Each item is presented in this background paper according to the following structure (see also
below):
the location in the first draft (D1) of the TXT BREF (December 2019) where the issue is
presented;
the text in the first draft (D1) of the TXT BREF (December 2019) that the issue relates to;
a summary of the comments on the issue, made by TWG members;
the EIPPCB assessment of the comments;
the EIPPCB proposal to resolve the issues.
Section and page number (.pdf version) in the first draft (D1) of the TXT BREF
(December 2019); BAT conclusion number, if applicable.
Location
in D1
Note that the numbering of the BAT conclusions may differ from that in the first draft
(D1) of the revised TXT BREF (December 2019).
Current text
Text of the sections from the first draft (D1) of the TXT BREF (December 2019) using
in D1
the same colours (e.g. all BAT conclusions are in green).
Individual comments or a summary of the main comments related to the item.
This is done in the following format: reference to individual comments is made in the
format “Origin of the comment followed by the comment number”, e.g. EEB 168.
Summary of The comments are ordered according to the text passage they refer to (e.g. comments on
comments
the introductory sentence of a BAT conclusion come first, then comments on individual
techniques in order of appearance and finally comments on performance levels).
The numbering of the comments corresponds to the numbering in the Excel spreadsheet
that compiles all comments from all TWG members.
EIPPCB
EIPPCB assessment related to the item to be discussed.
assessment
EIPPCB proposal that will be included in the latest version of the draft BAT conclusions
for discussion at the final TWG meeting.
Note that the revised BAT conclusions also include editorial corrections aimed at
EIPPCB
ensuring:
proposal
1) correct and consistent language use throughout the document;
2) consistency with the most recent BAT conclusions.
Such purely editorial corrections may not be tracked in this background paper where it
is evident that there are no substantive consequences.
The acronym ‘D1’ is used only for the purposes of this BP and will not appear in the final
BREF or the BAT conclusions.
Working plan
After this final TWG meeting, the revised draft of the TXT BREF will be completed by the
EIPPCB including the addition of Chapter 7 (Concluding remarks and recommendations for
future work). Afterwards, the TWG will be given another commenting period of about four
weeks that should focus on the changes made as a result of the conclusions of the final meeting.
The EIPPCB will then take these comments into account to produce the final draft (FD) that
will be submitted for opinion to the IED Article 13 Forum. In the final step, the BAT
conclusions will be submitted for formal approval to the Article 75 Committee. This will be
followed by the adoption of the BAT conclusions by the Commission and their publication in
the Official Journal of the European Union.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
7
Background paper – Final meeting for the review of the TXT BREF
Abbreviations frequently used in this background paper
Abbreviation Meaning
AT
Austria
BAT
Best Available Techniques (as defined in Article 3(10) of the IED)
BAT-AEL
Emission levels associated with the BAT (as defined in Article 3(13) of the IED)
Environmental performance level associated with the BAT: BAT-AELs are a subset of
BAT-AEPLs (see also Commission Implementing Decision 2012/119/EU laying down
BAT-AEPL
rules concerning guidance on the collection of data and on the drawing up of BREFs and
on their quality assurance)
BATc
BAT conclusions
BATIS
BAT Information System
BE
Belgium
BOD
Biochemical oxygen demand
BP
Background paper
BREF
BAT reference document (as defined in Article 3(11) of the IED)
CEFIC
Conseil Européen de l’Industrie Chimique (European Chemical Industry Council)
COD
Chemical oxygen demand
BAT
reference
document
for
Common
Waste
Water
and
Waste
Gas
CWW BREF
Treatment/Management Systems in the Chemical Sector
CZ
Czech Republic
D1
First draft of the TXT BREF from December 2019
DAA
Directly associated activity
DE
Germany
DK
Denmark
ECM
Reference Document on Economics and Cross-Media Effects
EEB
European Environmental Bureau
EIPPCB
European IPPC Bureau
EKPIs
Environmental Key Performance Indicators
ELV
Emission Limit Value
EMS
Environmental Management System
European Standard adopted by CEN (European Committee for Standardisation, from its
EN
French name Comité Européen de Normalisation)
EP(s)
Emission point(s)
ES
Spain
EURATEX
The European apparel and textile confederation
FDM BREF
BAT Reference Document on Food Drink and Milk
FI
Finland
FR
France
GOTS
Global Organic Textile
Standard
HOI
Hydrocarbon oil index
IE
Ireland
IED
Industrial Emissions Directive (2010/75/EU)
International Organisation for Standardisation. Also international standard adopted by
ISO
this organisation.
IT
Italy
KEI
Key environmental issue
KoM
Kick-off Meeting
LCP BREF
BAT Reference Document on Large Combustion Plants
LVOC BREF
BAT Reference Document on Large Volume Organic Chemicals
MS
Member State(s)
NL
The Netherlands
OTNOC
Other than normal operating conditions
PL
Poland
PT
Portugal
Regulation EC/1907/2006 on the Registration, Evaluation and Authorisation of
REACH
Chemicals
JRC Reference Report on Monitoring of emissions to air and water from IED
ROM
installations
8
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
RSL
Restricted Substances List
SE
Sweden
SF BREF
Smitheries and foundries BREF
SK
Slovakia
STS BREF
BAT reference document on Surface treatment using Organic Solvents
TOC
Total organic carbon
TVOC
Total volatile organic carbon
TXT BREF
BAT reference document on Textile Industry
TWG
Technical Working Group
UK
United Kingdom
UWWTD
Urban Waste Water Treatment Directive (91/271/ECC)
VOC
Volatile organic compound
WGC BREF
WT BREF
BAT reference document on Waste Treatment
WW
Waste water
(C)WWTP
(Common) Waste water treatment plant
ZDHC
Zero Discharge of Hazardous Chemicals
ZLD
Zero Liquid DIscharge
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
9
Background paper – Final meeting for the review of the TXT BREF
1
ITEMS PROPOSED FOR DISCUSSION AT THE FINAL TXT
TWG MEETING
1.1
Scope
Location in
P. 713 – Chapter 5
D1:
These BAT conclusions concern the following activities specified in Annex I to Directive
2010/75/EU, namely:
6.2. Pre-treatment (operations such as washing, bleaching, mercerisation) or dyeing of
textile fibres or textiles where the treatment capacity exceeds 10 tonnes per day.
6.11. Independently operated treatment of waste water not covered by Directive
91/271/EEC provided that the main pollutant load originates from activities covered
by these BAT conclusions.
These BAT conclusions also cover:
The following activities when they are directly associated with activities specified in
point 6.2 of Annex I to Directive 2010/75/EU:
o coating;
o dry cleaning;
o fabric production;
o finishing;
o lamination;
o printing;
o singeing;
o wool carbonising;
o wool fulling;
o yarn production.
The combined treatment of waste water from different origins provided that the main
Current
pollutant load originates from activities covered by these BAT conclusions and that
text in D1:
the waste water treatment is not covered by Directive 91/271/EEC.
On-site combustion plants which are directly associated with the activities covered by
these BAT conclusions provided that the combustion gases are put into direct contact
with the textile fibres or textiles (such as direct heating, drying, heat-setting) or when
radiant and/or conductive heat is transferred through a solid wall (indirect heating)
without using an intermediary heat transfer fluid.
These BAT conclusions do not cover:
Coating and lamination where the organic solvent consumption capacity of more than
150 kg per hour or more than 200 tonnes per year. This is covered by the BAT
conclusions on surface treatment using organic solvents including preservation of
wood and wood products with chemicals (STS).
Production of man-made fibres and yarns.
Unhairing of hides and skins. This may be covered by the BAT conclusions for the
tanning of hides and skins (TAN).
Other BAT conclusions and reference documents which could be relevant for the
activities covered by these BAT conclusions include the following:
Surface Treatment Using Organic Solvents including Preservation of Wood and
Wood Products with Chemicals (STS);
Tanning of Hides and Skins (TAN);
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
11
Background paper – Final meeting for the review of the TXT BREF
Waste Incineration (WI);
Waste Treatment (WT);
Emissions from Storage (EFS);
Energy Efficiency (ENE);
Industrial Cooling Systems (ICS);
Monitoring of Emissions to Air and Water from IED Installations (ROM);
Economics and Cross-Media Effects (ECM).
These BAT conclusions apply without prejudice to other relevant legislation, e.g. on the
registration, evaluation, authorisation and restriction of chemicals (REACH), on the
classification, labelling and packaging (CLP) or on biocidal products (BPR).
Directly associated activities
To avoid ambiguities in implementation, add the condition that activities are carried
out within the same installation, in addition to being directly associated with
activities specified in point 6.2 of Annex I to Directive 2010/75/EU, in order to be
covered by the BAT conclusions (IT 1).
Replace "yarn production" with "spinning of fibres" as production of man-made
fibres and yarns are not covered by these BAT conclusions (FR_A 1).
Add the following activities to be covered in BAT conclusions: pre-treatments of
cotton and cellulose fibres such as desizing and scouring, wool fulling, pre-treatments
of silk such as scouring and weighting, as some of these terms are mentioned in the
BAT conclusions and in BAT-AEPLs (IT 2).
Combined treatment of waste water
Remove the condition on the origin of the pollutant load at the end of the bullet point
related to the 6.11 activity and delete the bullet point about the combined treatment of
waste water. This is because these two points seem redundant and for consistency
with the CWW and WT BAT conclusions (ES 41).
Quantify the word “main” in the sentence “provided that the main pollutant load
originates from activities covered by these BAT conclusions” (EEB 169).
On-site combustion plants
Replace the bullet point with “On-site energy generation activities which are directly
associated with the activities covered by these BAT conclusions” as otherwise it
Summary
could be understood that only combustion techniques are used to generate energy
of
(EEB 170).
comments:
Delete the second part of the sentence as all combustion plants should be covered by
the BAT conclusions (EEB 170).
Interface with BAT conclusions on surface treatment using organic solvents
including preservation of wood and wood products with chemicals (STS)
Delete the exclusion from the scope of the BAT conclusions of coating and
lamination where the organic solvent consumption capacity is more than 150 kg per
hour or more than 200 tonnes per year as all textiles-related BAT should be covered
in the TXT BAT conclusions. The STS BAT conclusions would apply in addition
(EEB 168).
Add that the BAT conclusions also cover dressing, coating, degreasing and cleaning
where the organic solvent consumption capacity is less than 150 kg per hour or less
than 200 tonnes per year, as these activities are not covered by the STS BREF
(AT 31).
Reference to other BAT conclusions
Delete the list of relevant BAT conclusions and reference documents as it is not
useful and is confusing as to why these documents are mentioned (FR_A 3).
Delete the reference to the BAT conclusions on Tanning of Hides and Skins (TAN) as
they do not include conclusions which might be relevant for the activities covered by
the TXT BREF (DE 94).
12
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Directly associated activities
The scope of the BAT conclusions does not aim to define the directly associated
activities (DAAs) but to list the activities which are covered by the BAT conclusions
when they are DAAs. The definition of the boundaries of an installation and the
identification of DAAs within these boundaries remain in the remit of
implementation1. Moreover, Article 3(3) of the IED specifies that installation means
“a stationary technical unit within which one or more activities listed in Annex I or in
Part 1 of Annex VII are carried out, and any other directly associated activities on the
same site (…)”. Therefore, further clarification about the location of the activities
which are covered by the BAT conclusions when they are DAAs does not seem
necessary.
As concluded at the Kick-off Meeting2 by the Technical Working Group (TWG), the
data and information collection informed the list of potential directly associated
activities. Such data were collected about spinning but not about yarn production,
which could be clarified in a definition.
Concerning desizing and scouring, as pointed out by the comment, these are
processes that are part of the pretreatment of textile fibres or textiles, which is
covered by point 6.2 of Annex I to Directive 2010/75/EU. A reference to these
processes as activities covered by the BAT conclusions when they are DAAs may
therefore be confusing. However, a clarification in the definitions of these processes
could be helpful.
As concluded in the Kick-off Meeting by the Technical Working Group (TWG), the
data and information collection informed the list of potential directly associated
activities. No data were collected about pretreatment of silk.
Wool fulling is already listed as an activity covered by the BAT conclusions when it
is a DAA.
It seems necessary to clarify in the Scope of these BAT conclusions the status of
EIPPCB
activities of “washing and rinsing” related to other activities from definition of
assessment:
activity 6.2 from the IED apart from pre-treatment (e.g. dyeing and finishing).
Combined treatment of waste water
The points related to the 6.11 activity and to the combined treatment of waste water
are both in line with the conclusions taken by the TWG at the Kick-off Meeting (see
Section 2.1.2 of the meeting report).
Neither point is redundant:
o In the first case, it concerns the combined treatment of waste water carried out at
an independently operated WWTP.
o In the second case, it concerns the combined treatment of waste water carried out
at an installation covered by point 6.2 of the IED (for example a textile facility
which also treats waste water from another origin).
The wording related to the combined treatment of waste water has evolved across the
published BAT conclusions and the proposed wording is similar to the most recent
BAT conclusions (FDM and STS).
Data were collected during the data collection about the share of waste water
originating from textile activities. This share is however expressed in percentage in
volume and not in terms of pollutant load, which makes it difficult to further specify
the meaning of “main pollutant load”. As an indication, the lowest share of waste
water originating from textile activities is 14 % as an average over 3 years for Plant
CZ020.
On-site combustion plants
The paragraph on combustion plants aims to specify in which cases combustion
plants are covered by the BAT conclusions. It does not imply that non-combustion
energy generation cannot be used.
Deleting the second part of the sentence would not be in line with the conclusions
taken by the TWG at the Kick-off Meeting (see Section 2.2.2 of the meeting report).
1 See “ANSWERS GIVEN BY DG ENVIRONMENT ON THE IMPLEMENTATION OF THE INDUSTRIAL EMISSIONS
DIRECTIVE
–
CHAPTER
1”at
https://circabc.europa.eu/sd/a/cd4fc56b-cb31-4a39-bed7-
166a4e33e2d2/Chapter%201%20Q%26A.pdf
2 Kick-off Meeting report referenced Ares(2018)4698733 at
https://eippcb.jrc.ec.europa.eu/sites/default/files/2019-
11/TXT_KoM_meeting_report_Sept18.pdf
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
13
Background paper – Final meeting for the review of the TXT BREF
Interface with BAT conclusions on surface treatment using organic solvents
including preservation of wood and wood products with chemicals (STS)
Deleting the exclusion from the scope of the BAT conclusions of coating and
lamination where the organic solvent consumption capacity is more than 150 kg per
hour or more than 200 tonnes per year would not be in line with the conclusions taken
by the TWG at the Kick-off Meeting as it would create an overlap with the STS BAT
conclusions (see Section 2.2.3 of the meeting report).
As mentioned in the Scope, coating is covered by the BAT conclusions when it is
DAA and where the organic solvent consumption capacity is less than 150 kg per
hour or less than 200 tonnes per year.
Concerning degreasing and cleaning, it is not clear how these processes relate to
textiles activities. Solvent-based degreasing and cleaning may be used for machines
but this is the case in many industrial sectors. It is therefore not clear why these
processes should be covered by the TXT BAT conclusions when they are not covered
by the STS BAT conclusions.
Concerning dressing, it may refer to textiles activities but the meaning of this term is
ambiguous. Depending on the sources, it refers to finishing, dyeing3 or sizing4.
Moreover, no information was collected about dressing during the data collection.
Reference to other BAT conclusions
It is common practice in all recent BAT conclusions to list other BAT conclusions
and reference documents which could be relevant for the activities covered by the
BAT conclusions concerned. For example, the ENE BREF may contain useful
information to improve the energy efficiency of the installation.
Concerning the reference to the TAN BAT conclusions, they do not seem relevant for
the activities covered by the TXT BAT conclusions as the latter do not cover
unhairing of hides and skins.
Some activities of the STS BAT conclusions could be relevant for the TXT sector
(e.g. impregnation, coating).
Other points
Although not addressed by any comment, the exclusion from the scope of production
of man-made yarns could be confusing as yarns are always man-made and this would
exclude for example the spinning of wool fibres. This expression refers in fact to the
spinning of man-made fibres, which could be further clarified.
To define yarn production as spinning.
To specify that only the production of yarns made of man-made fibres is excluded
from the scope of the BAT conclusions. To reflect this change to the title of the
EIPPCB
section 5.3.
proposal:
To clarify that “washing and rinsing” is directly associated activity.
To clarify in the Definitions that desizing and scouring are part of the pretreatment
processes.
To remove the reference to the TAN BAT conclusions.
3 https://patents.google.com/patent/DE2715862A1/en
4 https://www.britannica.com/topic/textile/Finishes-enhancing-tactile-qualities
14
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.2
Definitions
Location in
P. 715 – Chapter 5
D1:
For the purposes of these BAT conclusions, the following
definitions apply:
General terms
Term used
Definition
Cellulosic materials
Cellulosic materials include cotton and viscose.
Channelled
Emissions of pollutants to air through any kind of duct, pipe,
emissions
stack, etc.
Continuous
Measurement
using
an
automated
measuring
system
measurement
permanently installed on site.
Desizing
Removal of sizing chemicals.
Diffuse emissions
Non-channelled emissions to air.
Discharge to a receiving water body without further
Direct discharge
downstream waste water treatment.
Dry cleaning
Cleaning of textile materials with an organic solvent.
Existing plant
A plant that is not a new plant.
Physical and/or chemical treatment aiming at giving the textile
Finishing
materials end-use properties such as visual effect, handle
characteristics, waterproofing or non-flammability.
Hazardous waste as defined in point 2 of Article 3 of Directive
Hazardous waste
2008/98/EC.
Indirect discharge
Discharge which is not a direct discharge.
For a batch process, weight ratio between the dry textile
Liquor ratio
materials and the process liquor used.
A major change in the design or technology of a plant with
Major plant upgrade
major adjustments or replacements of the process and/or
abatement technique(s) and associated equipment.
The mass of a given substance or parameter which is emitted
Mass flow
Current
over a defined period of time.
text in D1:
A plant first permitted at the site of the installation following
the publication of these BAT conclusions or a complete
New plant
replacement of a plant following the publication of these BAT
conclusions.
Organic solvent as defined in Article 3(46) of Directive
Organic solvent
2010/75/EU.
Periodic
Measurement at specified time intervals using manual or
measurement
automated methods.
For a continuous process, weight ratio between the liquid taken
Pick-up
up by the textile materials and the dry textile materials.
Substances and/or mixtures as defined in Article 3 of
Regulation EC/1907/2006 and used in the process(es),
Process chemicals
including sizing chemicals, bleaching chemicals, dyes, printing
pastes and finishing chemicals.
Process liquor
Solution and/or suspension containing process chemicals.
Impregnation of yarn with process chemicals aiming to protect
Sizing
the yarn and provide lubrication during weaving.
Synthetic materials
Synthetic materials include polyester, polyamide and acrylic.
Textile materials
Textile fibres and/or textiles.
Thermal treatment of textile materials includes drying, curing,
Thermal treatment
fixing or heat-setting which is carried out as a process step of
the activities covered by these BAT conclusions.
Pollutants and parameters
Term used
Definition
Antimony, expressed as Sb, includes all inorganic and organic
Antimony
antimony compounds, dissolved or bound to particles.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
15
Background paper – Final meeting for the review of the TXT BREF
Adsorbable organically bound halogens, expressed as Cl,
AOX
include adsorbable organically bound chlorine, bromine and
iodine.
Biochemical oxygen demand. Amount of oxygen needed for the
biochemical oxidation of the organic matter to carbon dioxide
BOD
n
in
n days (
n is typically 5 or 7). BODn is an indicator for the
mass concentration of biodegradable organic compounds.
Chromium, expressed as Cr, includes all inorganic and organic
Chromium
chromium compounds, dissolved or bound to particles.
CO
Carbon monoxide.
Chemical oxygen demand. Amount of oxygen needed for the
total chemical oxidation of the organic matter to carbon dioxide
COD
using dichromate. COD is an indicator for the mass
concentration of organic compounds.
Copper, expressed as Cu, includes all inorganic and organic
Copper
copper compounds, dissolved or bound to particles.
Dust
Total particulate matter (in air).
Hydrocarbon oil index. The sum of compounds extractable with
a hydrocarbon solvent (including long-chain or branched
HOI
aliphatic, alicyclic, aromatic or alkyl-substituted aromatic
hydrocarbons).
NH3
Ammonia.
Nickel, expressed as Ni, includes all inorganic and organic
Nickel
nickel compounds, dissolved or bound to particles.
The sum of nitrogen monoxide (NO) and nitrogen dioxide
NOX
(NO2), expressed as NO2.
The sum of sulphur dioxide (SO
SO
2), sulphur trioxide (SO3), and
X
sulphuric acid aerosols, expressed as SO2.
The sum of dissolved sulphides and of those undissolved
Sulphide,
easily sulphides that are easily released upon acidification, expressed
released
as S2–.
Total organic carbon, expressed as C (in water), includes all
TOC
organic compounds.
Total nitrogen, expressed as N, includes free ammonia and
TN
ammonium nitrogen (NH –
–
4 N), nitrite nitrogen (NO2 N), nitrate
nitrogen (NO –
3 N) and organically bound nitrogen.
Total phosphorus, expressed as P, includes all inorganic and
TP
organic phosphorus compounds, dissolved or bound to
particles.
Total suspended solids. Mass concentration of all suspended
TSS
solids (in water), measured via filtration through glass fibre
filters and gravimetry.
TVOC
Total volatile organic carbon, expressed as C (in air).
Volatile organic compound as defined in Article 3(45) of
VOC
Directive 2010/75/EU.
Zinc, expressed as Zn, includes all inorganic and organic zinc
Zinc
compounds, dissolved or bound to particles.
Additional terms
Add the definitions of coating, singeing, flame lamination and fabric production as
these terms are mentioned in the BAT conclusions and in BAT-AEPLs (UK 2).
Hazardous waste
For clarification and coherence, use the hazard classes and definition of the regulation
Summary
on classification, labelling and packaging of substances and mixtures (CLP)
of
(CEFIC 4).
comments:
Thermal treatment
Change the definition as follows: “All thermal treatments where relevant air
emissions can occur like drying after finishing or printing or lamination or coating,
fixing or heat-setting of textiles, certain dyeing processes like thermosol or dyeing
with carriers” because the definition should also cover the thermosol dyeing process
and dyeing with carriers (DE 58, DE 410).
16
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 24
Background paper – Final meeting for the review of the TXT BREF
Chromium, copper, nickel, zinc
Modify the chromium definition as follows: “Chromium, expressed as total Cr,
includes all inorganic and organic chromium compounds, dissolved or bound to
particles” because the monitoring standard measures all types of chromium. The same
applies for copper, nickel and zinc (EURATEX 23, EURATEX 24, EURATEX 25,
EURATEX 26, ES 28, ES 29, ES 30, ES 31).
Additional terms
Coating and lamination are activities mentioned in Annex I and Annex VII to the IED
and it is not the aim of the BAT conclusions to give an interpretation of the IED.
These terms are not defined in the STS BAT conclusions either.
The definitions of flame lamination, singeing and fabric production could add clarity
as they are used in the BAT conclusions.
Hazardous waste
As mentioned in Article 1(3) of the CLP Directive, this Directive does not apply to
waste. The definition of hazardous waste is given in Directive 2008/98/EC and the
same definition has been used in a number of recently published BAT conclusions
(WT, WI).
Thermal treatment
According to Section 2.7.8 of D1, emissions to air from dyeing are generally not
significant except from the thermosol process and from dyeing processes using
carriers.
The thermosol process is specific for dyeing polyester or cotton/polyester blends with
EIPPCB
disperse dyestuffs. The sequence of this process is as follows: impregnation in the
assessment:
dyeing liquor, pre-drying in an infrared oven, drying in hot-flue, thermal fixation at
200 ºC. All steps of pre-drying, drying and thermal fixation are encompassed by the
definition proposed in D1 and specific mention of the thermosol process does not
seem necessary.
Concerning dyeing processes using carriers, according to Section 2.7.8.1 of D1, the
carriers that remain on the fibre after dyeing and washing are partially volatilised
during drying and fixing operations and can give rise to emissions to air. Both drying
and fixing are covered by the definition proposed in D1 and mention of dyeing using
carriers does not seem necessary.
Chromium, copper, nickel, zinc
The monitoring standards mentioned in the BAT conclusions allow the measurement
of all forms of these metals. This is underlined in the definitions proposed in D1:
“(…) includes all inorganic and organic (…) compounds, dissolved or bound to
particles”. While adding “expressed as total Cr” (or Cu, Ni and Zn) could be an
option, it would be a repetition of the definition and would not be in line with the
recently published BAT conclusions (e.g. WI and WT).
To add the definitions of flame lamination, singeing and fabric production.
To add or modify the definitions of desizing, scouring and hazardous substances (see
assessments of BAT 4 in Section
1.4.1.1 or BAT 13 in Section 1.4.5.1).
EIPPCB
The definition of “substances of very high concern” was added and the one of
proposal:
“process chemicals” modified (assessment in 1.4.5.1).
The definition of “thermal treatment” was modified to accommodate the needs of
many BATs (e.g. see assessments in section 1.4.8).
To add a definition of CMR (see assessment in 1.4.2.1).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
17
Background paper – Final meeting for the review of the TXT BREF
1.3
General considerations
1.3.1
Emission levels associated with the best available techniques
(BAT-AELs) for emissions to air
Location in
P. 717 – Chapter 5
D1:
When a mass flow threshold is indicated, the BAT-AELs only apply if the mass
flow of the given substance or parameter emitted from the emission point is above
the associated mass flow threshold.
Emission levels associated with the best available techniques (BAT-AELs) for
emissions to air given in these BAT conclusions refer to concentrations (mass of
emitted substances per volume of waste gas) under the following standard
conditions: dry gas at a temperature of 273.15 K and a pressure of 101.3 kPa,
without correction for oxygen content, and expressed in mg/Nm3.
Current
For averaging periods of BAT-AELs for emissions to air, the following
definition
text in D1:
applies.
Type of
Averaging period Definition
measurement
Average
value
of
three
consecutive
Average over the
Periodic
measurements of at least 30 minutes each.
sampling period
(1)
(1) For any parameter where, due to sampling or analytical limitations, a 30-minute
sampling/measurement and/or an average of three consecutive measurements is
inappropriate, a more representative sampling/measurement procedure may be employed.
General points
Add a provision to avoid the dilution of emissions to air when waste gas streams are
combined, such as “if the waste gases from several parts of the installation are
combined, the requirements to reduce emissions shall be established in a way to
ensure that the emissions generated do not exceed an emission level of the respective
gases where they are disposed of individually” (DE 124).
Mention that the measurements are carried out at the highest expected emission
concentrations under normal operating conditions (DE 126).
Mass flow thresholds
Apply the mass flow thresholds at installation level to which the sum of the mass
flows of the different emission sources would be compared; otherwise, each emission
point could be below the mass flow threshold if the number of emission points is
increased (SE 20, DE 60, DE 75, DE 122).
Summary
On the basis of measurements, flows that do not (significantly) contribute to the total
of
mass flow at plant level may be left out of consideration (SE 20).
comments:
Emissions to air from thermal treatment
The BAT-AELs related to emissions from all thermal treatments should refer to an air
/ textile weight ratio of 20 m3/kg textile to be treated. Indeed, by using a lot of air, the
waste gas emission concentration will be lower. However, a large excess of drying air
is not energy-efficient (DE 85, DE 381).
Averaging periods
Change the definition to “average value of three consecutive individual measurements
of a sampling period of at least 30 minutes each” (DE 61).
Batch processes
Add provisions to ensure a homogeneous implementation, i.e. homogeneous
calculation of the mass flows (e.g. sampling period, number of batches), in particular
when processes are carried out in batches (UK 3).
18
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Add a footnote for the batch processes: “For batch processes, the average of a
representative number of measurements taken over the total batch time or the result of
a measurement carried out over the total batch time, during which emissions occur,
but with a maximum of 4 hours, can be used." (BE 36).
General points
How to establish emission limit values for combined waste gas streams, considering
the pollutant loads of the individual waste gas streams, seems to pertain to the domain
of implementation. In addition, such provisions would not be in line with other
recently published BAT conclusions.
Footnote (1) of BAT 8 mentions that the measurements are carried out at the highest
expected emission state under normal operating conditions and it does not seem
needed to repeat the text in the General considerations.
Mass flow thresholds
Regarding the mass flow threshold preventing increased number of emissions points
BAT 22 instructs to limit them. Furthermore, article 20 of the IED sets that operators
should report MS about any change in the installation that may have consequences for
the environment, meaning that such change would require change of permit and
decision of competent authority (which would need to base their decision on BAT
22).
Following the interventions of the different TWG members during the informal
meeting of 19/02/2021, it seemed that there was not a common position on whether
some emission points with small mass flows are considered relevant and would need
to comply with BAT-AEL, and others irrelevant (or insignificant in terms of
environmental impact) and would not need to comply with BAT-AEL. Approaches to
set such mass flow threshold are described in sections 1.4.8.3, 1.4.8.5 and 1.4.8.7.
However, taking into account plant configurations where the emissions to air from
one source could be discharged through more than one emission point. It could be
clarified in General considerations how to calculate the mass flow taking into account
all the emission points related to a common source could be considered as a single
EIPPCB
emission point.
assessment:
Emissions to air from thermal treatment
Increasing the volume of extracted air leads indeed to the dilution of the pollution in
the waste gas stream. This is the case across all industrial sectors and is not specific to
the textile industry. How the dilution is considered for setting ELVs seems to be more
an implementation issue and follows the provisions set in Article 15(1) of the IED.
Concerning energy efficiency, this is addressed by BAT 10, 11 and 12 and by the
BAT-AEPL set in Table 5.2.
Averaging periods
The wording “average value of three consecutive measurements of at least 30 minutes
each” is a standard wording which has been used in all recently published BAT
conclusions and any change needs to be considered carefully.
When the measurements are carried out on-line, the duration of 30 minutes refers also
to the sampling as the sampling and the measurements are simultaneous. This is not
the case though of off-line measurements where the sampling may last 30 minutes but
the measurement itself is shorter (for example in the case of dust monitoring as per
standard EN 13284-1). This could be reflected in the BAT conclusions.
Batch processes
Concerning the homogeneity of the measurement practices when the textile materials
are processed in batches, this is covered by Footnote (1) of BAT 8 mentioning that
the measurements are carried out at the highest expected emission state under normal
operating conditions.
Footnote (1) applies also to the cases of batch processes. It provides appropriate
guidance on how to perform the sampling/measurements in implementation to the
batch processes.
Averaging periods
To specify the sampling duration in the case of off-line measurements.
EIPPCB
To clarify that several emission points associated with the same source of emission
proposal:
can be considered as single emission point when to calculating the mass flows
To delete the applicability of the BAT-AELs when there is a mass flow threshold
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
19
Background paper – Final meeting for the review of the TXT BREF
1.3.2
Emission levels associated with the best available techniques
(BAT-AELs) for emissions to water
Location in
P. 717 – Chapter 5
D1:
Emission levels associated with the best available techniques (BAT-AELs) for emissions
to water given in these BAT conclusions refer to concentrations (mass of emitted
substances per volume of water), expressed in mg/l.
Averaging periods associated with the BAT-AELs refer to either of the following two
cases:
Current
in the case of continuous discharge, daily average values, i.e. 24-hour flow-
text in D1:
proportional composite samples;
in the case of batch discharge, average values over the release duration taken as flow-
proportional composite samples, or, provided that the effluent is appropriately mixed
and homogeneous, a spot sample taken before discharge.
Time-proportional composite samples can be used provided that sufficient flow stability is
demonstrated.
Summary
Mention that all BAT-AELs for emissions to water apply at the point where the
of
emission leaves the plant, as in the STS BAT conclusions (AT 35).
comments:
According to Article 15(1) of the IED, the emission limit values for polluting
EIPPCB
substances shall apply at the point where the emission leaves the installation.
assessment:
Although it may not be necessary to add a similar provision in the BAT conclusions,
it would bring consistency with other recently published BAT conclusions.
To add a sentence to specify where the BAT-AELs for emissions to water apply.
EIPPCB
To move the provision for time-proportional composite sampling to the case of
proposal:
continuous discharge.
20
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.3.3
Specific energy consumption levels associated with the best
available techniques
Location in
P. 718 – Chapter 5
D1:
The environmental performance levels related to specific energy consumption refer to
yearly averages calculated using the following equation:
energy consumption
specific energy consumption =
activity rate
Current
where:
text in D1:
energy consumption:
the total annual amount of heat and electricity
consumed by a given process, minus the heat
recovered from the process, expressed in MWh/year;
activity rate:
total annual amount of textile materials treated in the
process, expressed in t/year.
Summary
Clarify the definition of activity rate as the textile materials could undergo the same
of
process several times, involving thermal treatments carried out as process steps,
comments:
and/or different processes, each of which may involve thermal treatments (IT 3).
The specific energy consumption was reported through the questionnaires used in the
data collection. These questionnaires specified that the specific energy consumption
was calculated as the energy consumed during a reference year divided by the weight
of textiles treated in this process during the same year. Therefore, counting only once
the amount of textile materials processed several times would not be in line with the
definition used in the questionnaires and for the derivation of BAT-AEPLs. It could
EIPPCB
be helpful however to clarify this point in the BAT conclusions.
assessment:
Although no comments were made on this issue, the proposed BAT-AEPLs in
Table 5.2 concern only thermal treatment and not all the processes, which could be
reflected in the General considerations.
In accordance with assessments in section 1.4.4.3 the indicative levels are proposed
instead of BAT-AEPLs. This can be reflected in the equation for calculating specific
energy consumption.
To clarify that the amount of textile materials treated in the process includes the
EIPPCB
textile materials processed several times in the same process.
proposal:
To replace “process” with “thermal treatment”.
To change from BAT-AEPLs to “indicative levels”.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
21
link to page 21
Background paper – Final meeting for the review of the TXT BREF
1.3.4
Specific water consumption levels associated with the best
available techniques
Location in
P. 718 – Chapter 5
D1:
The environmental performance levels related to specific water consumption refer to
yearly averages calculated using the following equation:
water consumption
specific water consumption =
activity rate
where:
Current
text in D1:
water consumption:
the total annual amount of water consumed by a given
process including water used for washing and rinsing
the textile materials and for cleaning the equipment,
minus the water reused or recycled to the process,
expressed in m3/year;
activity rate:
total annual amount of textile materials treated in the
process, expressed in t/year.
Clarify that specific water consumption at a process level concerns only the water
consumed by the process concerned and does not contain other waste water flows
(UK 4).
Summary
Clarify the definition of water consumption as follows: “the total annual amount of
of
water consumed by a given specific process (e.g. mercerisation) (…)” as Table 5.1
comments:
refers to specific processes (IT 5).
Clarify the definition of activity rate as follows: “total annual amount of textile
materials treated in the specific processes (e.g. mercerisation), expressed in t/year” as
Table 5.1 refers to specific processes (IT 6).
The proposed definition of water consumption corresponds to the total annual amount
of water consumed by a given process. It does not seem necessary to add that it
excludes the water not consumed by this process. Moreover, BAT 5 specifies that the
monitoring is broken down to the process level.
EIPPCB
It is not entirely clear whether the addition of the word “specific” in the definitions of
assessment:
water consumption and activity rate would add clarity. However, examples of
processes could be helpful.
In accordance with assessments in section 1.4.3.2 the indicative levels are proposed
instead of BAT-AEPLs. This can be reflected in the equation for calculating specific
water consumption.
To add examples of processes.
EIPPCB
To clarify that the amount of textile materials treated in the process includes the
proposal:
textile materials processed several times in the same process (see Section
1.3.3).
To change from BAT-AEPLs to “indicative levels”.
22
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.3.5
Specific wool grease recovery level associated with the best
available techniques
Location in
P. 718 – Chapter 5
D1:
The environmental performance level related to specific wool grease recovery refers to a
yearly average calculated using the following equation:
amount of wool grease recovered
specific wool grease recovery =
activity rate
Current
where:
text in D1:
amount of wool grease recovered:
the total annual amount of wool
grease recovered from the pre-treatment of raw wool
fibres by scouring, expressed in kg/year;
activity rate:
total annual amount of raw wool pre-treated by scouring,
expressed in t/year.
Summary
of
No comments.
comments:
EIPPCB
Not applicable.
assessment:
EIPPCB
No change.
proposal:
1.3.6
Caustic soda recovery level associated with the best available
techniques
Location in
P. 719 – Chapter 5
D1:
The environmental performance level related to caustic soda recovery refers to a yearly
average calculated using the following equation:
amount of caustic soda recovered
caustic soda recovery =
amount of caustic soda before recovery
where:
Current
text in D1:
amount of caustic soda recovered:
the total annual amount of caustic
soda
recovered
from
spent
mercerisation
rinsing
water,
expressed in kg/year;
amount of caustic soda before recovery:
total annual amount of caustic soda
in the spent mercerisation rinsing
water, expressed in kg/year.
Summary
of
No comments.
comments:
EIPPCB
Not applicable.
assessment:
EIPPCB
No change.
proposal:
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
23
Background paper – Final meeting for the review of the TXT BREF
1.4
General BAT conclusions
1.4.1
Overall environmental performance
1.4.1.1
Techniques for improving the overall environmental performance
Location in
P. 721 – Section 5.1.1 – BAT 2
D1:
BAT 2. In order to improve the overall environmental performance, BAT is to
establish, maintain and regularly review (including when a significant change
occurs) an inventory of inputs and outputs, as part of the environmental
management system (see BAT 1), that incorporates all of the following features:
(i) information about the production process(es), including:
(a) simplified process flow sheets that show the origin of the emissions;
(b) descriptions of process-integrated techniques and waste water/waste gas
treatment techniques to prevent or reduce emissions, including their
performance (e.g. abatement efficiency);
(ii) information about the quantity and characteristics of materials used, including
textile materials and process chemicals (see BAT 14);
(iii) information about water consumption;
(iv) information about energy consumption;
(v) information about the quantity and characteristics of the waste water streams, such
as:
(a) average values and variability of flow, pH, temperature, and conductivity;
Current
(b) average concentration and mass flow values of relevant substances/parameters
text in D1:
and their variability (e.g. COD/TOC, nitrogen species, phosphorus, metals,
priority substances, microplastics);
(c) data on toxicity and bioeliminability (e.g. BOD
n, BOD
n to COD ratio, Zahn-
Wellens test, biological inhibition potential (e.g. inhibition of activated
sludge));
(vi) information about the characteristics of the waste gas streams, such as:
(a) average values and variability of flow and temperature;
(b) average concentration and mass flow values of relevant substances/parameters
and their variability (e.g. dust, organic compounds);
(c) flammability, lower and higher explosive limits, reactivity;
(d) presence of other substances that may affect the waste gas treatment system or
plant safety (e.g. water vapour, dust);
(vii) information about the quantity and characteristics of waste generated.
Applicability
The scope (e.g. level of detail) and nature of the inventory will generally be related to the
nature, scale and complexity of the installation, and the range of environmental impacts it
may have.
General comments
Add a yearly based frequency for reviewing the inventory of inputs and outputs
(DE 335).
Define the term "significant change" so that it could be implemented by Member
States in a homogeneous way (DE 387).
Express units per year, e.g. m3/year, kg/year (DE 335).
Add at the end of the BAT statement that the inventory incorporates all of the
Summary
following features, only if they are relevant (EURATEX 142).
of
Streamline and harmonise text (both wording and consecutive numbering) on
comments:
inventory of inputs and outputs with the respective text in the FDM BREF or other
BREFs (AT 33).
Add a reference to BAT 16, “Techniques for preventing or reducing emissions to
water of poorly biodegradable substances”, as they are very closely aligned (UK 6).
Clarify the use of "such as" in points (v) and (vi). If operators are expected to conduct
several tests on toxicity, bioeliminability. it could be expensive and time-consuming
(UK 6).
24
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Waste water streams
Add clarification on the differences of the measurement methods (BOD5, RODTOX
(biological inhibition test) and Zahn Wellens test), to help choose the appropriate
method or combination of methods (BE 32).
Microplastics
Add that testing for microplastics is done according "to an agreed test method or
standard" to avoid further uncertainty when trying to compare test results from
different sites in the future (UK 6).
Delete "microplastics" since there is still no valid measurement standard for
microplastics (currently under development within CEN TC248), so there is no
possiblity to be compliant or at least for comparing results. Furthermore, relevance is
presently
not
scientifically
confirmed
(CEFIC 20,
EURATEX 28
and
EURATEX 143).
Keep microplastics monitoring in the proposed BAT (EEB 99).
Waste gas streams
Delete the term "average" in points (vi) a) and (vi) b), since having information on
highest emissions levels and their context (e.g. recipes, hazardous substances used) is
as useful as information on average levels to prevent and reduce emissions (DE 63).
Add a bullet point on the identification of hazardous pollutants and the related
emissions to air of each applied recipe for textile finishing processes, based on the
emission factor concept (DE 64 and DE 413).
General comments
It may be necessary to review the inventory more than once per year if the process
conditions vary very frequently, for example in the case of companies working on
commission. In contrast, if the process conditions are stable, there may be not merit in
reviewing this inventory every year. The proposed wording reflects this variety of
cases, offers flexibility and is in line with recently published BAT conclusions such
as FDM.
The units used for the inventory are an operational detail which can be addressed at
the implementation stage.
Concerning the relevance of the proposed features, it is not clear in which cases one
of those features would not be relevant. Of course, if no water is used in the
processes, obviously point (iii) about water consumption would indicate that no water
is consumed but this case seems very specific.
The text in BAT 2 has been used in recent documents such as FMP, and presents the
principles of the inventory of inputs and outputs as part of the environmental
management system. The text has been adapted for the textile industry and the
applicability clarifies the interpretation of this BAT, giving flexibility at local scale. It
seems possible to harmonise wording and numbering with the recent text used for the
EIPPCB
FDM industry.
assessment:
Otherwise, the link with the specific BAT 16 is unclear, as the scope of BAT 2 is the
overall environmental performance.
Waste water streams
More information for choosing a relevant measurement method can be found in
Chapter 4 of D1 or in the Reference Document for monitoring of emissions to air and
water from IED installations. Moreover, the choice of an appropriate method to refer
to in order to obtain data on toxicity and bioeliminability may depend on the local
situation or process parameters.
Following the assessment of comment DE 340 on BAT 8 (on biodegradability) on the
usefulness of information on the biodegradability of individual waste water streams,
to handle them appropriately, it seems relevant to add biodegradability to point (v)(c)
as relevant information on waste water streams.
Microplastics
As mentioned in Section 3.4.19, microplastics have been measured in several studies
involving the textile industry, and a standardised European measurement method for
microplastics is currently under development (see CEN/TC 248/WG 37 -
Microplastics from textile sources).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
25
Background paper – Final meeting for the review of the TXT BREF
Microplastics is only one example of relevant substances/parameters mentioned in
point (v).
Waste gas streams
The text in BAT 2 is used in many conclusions from the CWW BAT conclusions
onward and includes average values and variability for the parameters listed, which
includes data on highest emissions levels.
The variability of the characteristics of the waste gas streams may indeed be
estimated by the use of emission factors, which could be reflected in BAT 2.
To make minor text adjustments on wording and numbering.
EIPPCB
To add a reference to emission factors.
proposal:
To add the biodegradability in point (v)(c).
BAT 2bis. In order to reduce the frequency of the occurrence of OTNOC and to
reduce emissions during OTNOC, BAT is to set up and implement a risk-based
OTNOC management plan as part of the EMS (see BAT 1) that includes all of the
following elements:
i.
identification of potential OTNOC (e.g. failure of equipment critical to the
protection of the environment (‘critical equipment’)), of their root causes
and of their potential consequences, and regular review and update of the
list of identified OTNOC following the periodic assessment below;
New
ii.
appropriate design of critical equipment (e.g. waste water treatment);
proposal
iii.
set-up and implementation of an inspection and preventive maintenance
plan for critical equipment (see BAT 1 xii);
iv.
monitoring (i.e. estimating or, where possible, measuring) and recording of
emissions during OTNOC and of associated circumstances;
v.
periodic assessment of the emissions occurring during OTNOC (e.g.
frequency of events, duration, amount of pollutants emitted) and
implementation of corrective actions if necessary;
vi.
regular review and update of the list of identified OTNOC under point i.
following the periodic assessment of point v;
vii.
regular testing of back-up systems.
Summary
of
Not applicable
comments:
Based on the data collection there are substantial fluctuations in the reported values of
emissions to air and water from some plants. The cause of these fluctuations is not
EIPPCB
known, however it seems that one of the possible reasons could be a poor operational
assessment:
management of the abatement techniques, resulting in other than normal operating
conditions. These could be prevented by appropriate management practice.
EIPPCB
To add BAT 2bis.
proposal:
26
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 83
Background paper – Final meeting for the review of the TXT BREF
1.4.2
Monitoring
1.4.2.1
Monitoring emissions to water
Location
P. 724 – Section 5.1.2– BAT 7
in D1:
BAT 7. BAT is to monitor emissions to water with at least the frequency given below
and in accordance with EN standards. If EN standards are not available, BAT is to use
ISO, national or other international standards that ensure the provision of data of an
equivalent scientific quality.
Activities
Minimum
Monitoring
Substance(s) /
Standard(s)
/
monitoring
associate
parameter
processes
frequency
d with
Adsorbable
Once
every
organically
bound EN ISO 9562
month
halogens (AOX) (1)
EN
standards
available for some
alkylphenols
and All
Alkylphenols
and alkylphenol
activities / Once
every
alkylphenol
ethoxylates
processes
3 months
ethoxylates (1)
(i.e. EN ISO 18857
-1
and
EN ISO 18857-2)
Biochemical
oxygen
Once
every
EN 1899-1
demand (BOD
n) (2)
month
To be decided,
All
after effluent
Biodegradability
EN ISO 9888
activities / characterisatio
Current
processes
n (5)
text in D1:
EN
standard Finishing
available for some
Brominated
flame
with
Once
every
polybrominated
retardants (1)
flame
3 months
diphenyl
ethers retardants
0
(i.e. EN 16694)
All
Chemical
oxygen No EN standard
Once
every
activities /
demand (COD) (2)(3)
available
month
processes
Once
every
Colour
EN ISO 7887
Dyeing
month
All
Hydrocarbon oil index
Once
every
EN ISO 9377-2
activities /
(HOI)
3 months
processes
Pre-
treatment
and/or
dyeing of
Various EN
polyester
standards available
Metals
Antimony
Finishing
Once
every
(e.g. EN ISO 1188
/
(Sb)
with
month
5, EN ISO 17294-2
metalloids
flame
or EN ISO 15586)
retardants
using
antimony
trioxide
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
27
Background paper – Final meeting for the review of the TXT BREF
Dyeing
with
Chromium
chromium
(Cr)
-
containing
dyes
Copper
All
(Cu)
activities /
Nickel (Ni)
processes
Zinc (Zn)
Dyeing
with dyes
Hexavalent
EN ISO 10304-3
containing Once
every
chromium
or EN ISO 23913
hexavalen
month
(Cr(VI))
t
chromium
EN
standards Pre-
available for some treatment
pesticides
(e.g. of
raw Once
every
Pesticides (1)
EN 12918,
EN wool
3 months
16693 or EN ISO fibres by
27108)
scouring
All
Perfluorinated
No EN standard
Once
every
activities /
compounds (1)
available
3 months
processes
Dyeing
Sulphide,
easily No EN standard with
Once
every
released (S2-)
available
sulphur
3 months
dyes
EN
standard
available
for
Once
every
Surfactants
anionic surfactants
3 months
(i.e. EN 903)
EN 12260 or
Once
every
Total nitrogen (TN) (2) EN ISO 11905-1
month
Total organic carbon
Once
every
EN 1484
(TOC) (2) (3)
month
EN ISO 6878,
EN ISO 15681-1,
Once
every
Total phosphorus (TP)
EN ISO 15681-2
month
or EN ISO 11885
Total suspended solids
Once
every
EN 872
(TSS) (2)
month
Fish
eggs
All
(
Danio
EN ISO 15088
activities /
rerio)
processes
Daphnia
(
Daphnia
EN ISO 6341
magna
To be decided
Straus)
based on a risk
Luminescen
EN ISO 11348-1,
Toxicit
assessment,
t bacteria
EN ISO 11348-2
y (4)
after effluent
(
Vibrio
or EN ISO 11348-
characterisatio
fischeri)
3
n (5)
Duckweed
EN ISO 20079 or
(
Lemna
EN ISO 20227
minor)
EN ISO 8692,
Algae
EN ISO 10253 or
EN ISO 10710
28
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
(1) The monitoring only applies when the substance(s)/parameter, including groups of
substances or individual substances in a group of substances, concerned is identified
as relevant in the waste water stream based on the inventory of inputs and outputs
mentioned in BAT 2.
(2) The monitoring only applies in the case of a direct discharge to a receiving water
body.
(3) TOC monitoring and COD monitoring are alternatives. TOC monitoring is the
preferred option because it does not rely on the use of very toxic compounds.
(4) An appropriate combination of the toxicity parameters can be used.
(5) The effluent characterisation is carried out before starting operation of the plant or
before a permit for the plant is updated for the first time after the publication of these
BAT conclusions, and after each significant change in the plant.
BAT statement
Amend the BAT statement as follows: “BAT is to monitor relevant emissions to water
with at least …”, as only pollutants at detectable concentrations should be monitored,
not all the pollutants listed in the table (CZ_A 7, CZ_B 84).
Allow the possibility for self-monitoring by the operator (DE 253).
Clarify that the measurement is done at the point of release (DE 286, EURATEX 32).
Add monitoring/measurement points in raw waste water or after intermediate treatment
steps to determine treatment efficiencies of WWTP (DE 142).
Standard(s)
Allow the possibility to use the standards set in "Standard Methods for the examination
of water and wastewater", when no EN or ISO standard is available (ES 35).
Allow equivalent standards to EN standards when self-monitoring (DE 254).
Activities / processes
Modify the heading of the table as follows: “Activities / processes if relevant”
(EURATEX 32).
Monitoring frequency
Change for all parameters the minimum monitoring frequency to once every three
months (EURATEX 32, EURATEX 36, EURATEX 145) to avoid additional testing
costs.
Change the monitoring frequency based on a risk-based sampling frequency dependent
Summary
on the amount and nature of the emission (UK 9).
of
comments:
Adsorbable organically bound halogens (AOX)
Change relevant processes to “pre-treatment of synthetic knitwear” (DE 351).
Support the proposed monitoring frequency once every month. (DE 127).
Reduce the monitoring frequency from once every month to once every three months
(EURATEX 146), as in most European countries the monitoring frequency is not lower
than every three months.
Alkylphenols and alkylphenol ethoxylates
Clarify which specific alkylphenol ethoxylates (mono, di or poly) are monitored and
with which method(s) (BE 4).
Support the proposed monitoring frequency once every 3 months (DE 127).
Change relevant processes to “pre-treatment of synthetic knitwear” (DE 351).
Biochemical oxygen demand (BODn)
Replace EN 1899-1 by EN ISO 5815-1, which is the applied standard since 2019
(BE 5, FR_A 29).
Increase monitoring frequency from once every month to once every week, as these
measurements are necessary for the operation of waste water treatment plants (DE 127,
SE 10).
Change relevant processes to “pre-treatment of synthetic knitwear” (DE 351).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
29
Background paper – Final meeting for the review of the TXT BREF
Biodegradability
Clarify that monitoring only applies for indirect discharges. It is not useful to monitor
biodegradability of effluents that have already passed a biological treatment (BE 23).
Include that the monitoring can apply to other monitoring points, e.g. partial
streams/concentrates from relevant processes. Measurements at the point of release are
not sufficient as hardly biodegradable substances might be diluted (DE 340).
Brominated flame retardants
Support the proposed monitoring frequency of once every 3 months (DE 127).
Chemical oxygen demand (COD)
Increase the monitoring frequency from once every month to once every week (SE 10),
or to daily (DE 127), as these measurements are necessary for the operation of waste
water treatment plants.
Colour
Increase the monitoring frequency from once every month to daily, as these
measurements are necessary for the operation of waste water treatment plants
(DE 127).
Replace EN ISO 7887 by SCA blue book 103 ISBN 0117519533 Absorbance Scan -
determined by scanning UV/ visible spectrometry (measured in absorbance units), as
EN 7887 is suitable for colours of drinking water, not so much for the textile effluents
(UK 48).
Hydrocarbon oil index (HOI)
Increase the monitoring frequency from once every 3 months to once every month
(DE 127).
Change relevant processes to “Processing of man-made fibres and its mixtures of goods
and knitwear good” (CZ_A 4, CZ_B 85).
Change relevant processes to “pre-treatment of synthetic knitwear” (DE 351).
Metals / metalloids: Chromium (Cr)
Change relevant processes to “Dyeing / printing” (CZ_A 5, CZ_B 86), as Cr is only
present when using metal-complex dyes containing such metal.
Support the proposed monitoring frequency of once every month (DE 127).
Metals / metalloids: Copper (Cu)
Change relevant processes to “Dyeing” (DE 344, EURATEX 32).
Change relevant processes to “Dyeing / printing” (CZ_A 5, CZ_B 86), as Cu is only
present when using metal-complex dyes containing such metal.
Support the proposed monitoring frequency of once every month. (DE 127).
Metals / metalloids: Nickel (Ni)
Change relevant processes to “Dyeing” (DE 344, EURATEX 32).
Change relevant processes to “Dyeing / printing” (CZ_A 5, CZ_B 86), as Ni is only
present when using metal-complex dyes containing such metal.
Support the proposed monitoring frequency of once every month (DE 127).
Metals / metalloids: Hexavalent chromium (Cr(VI)
EN ISO 10304-3 is preferred as EN ISO 23913: 2009 does not allow the elimination
of potential interference unless a pre-treatment step is performed (BE 6).
Support the proposed monitoring frequency of once every month (DE 127).
Metals / metalloids: Zinc (Zn)
Change relevant processes to “Dyeing” (EURATEX 32).
Change relevant processes to “Dyeing / printing” (CZ_A 5, CZ_B 86), as Zn is only
present when using metal-complex dyes containing such metal.
Support the proposed monitoring frequency of once every month (DE 127).
30
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Pesticides
Reduce the monitoring frequency from once every three months to once every six
months. In pre-treatment of raw wool fibres by scouring, pesticides might be only
indirect occurrences (i.e. impurities) (IT 9).
Support the proposed monitoring frequency of once every 3 months (DE 127).
Perfluorinated compounds
Add the following monitoring methods: ISO 25101 (PFOA and PFOS) and ISO 21675
(extensive range of PFAS) (BE 7).
Change the name of the parameter to Per- and Polyfluorinated compounds (DE 352).
Change relevant processes to “Finishing” (DE 352, EURATEX 32).
Sulphide, easily released (S2-)
Increase the monitoring frequency from once every 3 months to once every month
(DE 127).
Add in relevant processes “wool scouring” (UK 11).
Add the following monitoring method: methylene blue (UK 11).
Surfactants
Clarify that the 3 groups of surfactants (anionic, cationic and non-ionic) must be
monitored (BE 25).
Clarify which standard to use for monitoring non-anionic surfactants (FR_A 25).
Delete monitoring of hardly biodegradable surfactants, and address this issue in BAT
16, as hardly biodegradable surfactants should not be used (DE 143).
Delete the monitoring of surfactants. Surfactants are regulated by “EU detergents
directive” (EURATEX 32), and the measurement standards are not available
(EURATEX 147).
Total nitrogen (TN)
Increase the monitoring frequency from once every month to once every week, as these
measurements are necessary for the operation of waste water treatment plants (DE 127,
SE 10).
Reduce the monitoring frequency from once every month to once every three months.
Monthly frequency does not add value for the company or the authorities, so additional
testing costs should be avoided (EURATEX 37).
Total organic carbon (TOC)
Increase the monitoring frequency from once every month to once every week (SE 10),
or to daily (DE 127), as these measurements are necessary for the operation of waste
water treatment plants.
Total phosphorus (TP)
Replace EN ISO 6878 with ICP-AES or ICP-MS techniques, as spectrophotometric
methods can lead to an underestimation of the actual value (BE 8).
Increase the monitoring frequency from once every month to once every week, as these
measurements are necessary for the operation of waste water treatment plants (DE 127,
SE 10).
Reduce the monitoring frequency from once every month to once every three months.
Monthly frequency does not add value for the company or the authorities, so additional
testing costs should be avoided (EURATEX 38).
Total suspended solids (TSS)
Increase the monitoring frequency from once every month to once every week (SE 10),
or to daily (DE 127), as these measurements are necessary for the operation of waste
water treatment plants.
Toxicity
Modify the monitoring frequency to once every month. Different hazardous chemicals
can be used in the textile industry (DE 127).
Modify the monitoring frequency as follows: “To be decided, after effluent
characterisation” (AT 37).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
31
Background paper – Final meeting for the review of the TXT BREF
Additional parameters
Add the following parameters: NH4-N, pH and temperature. NH4-N has a negative
impact on water bodies (toxic for fish), while pH and temperature contribute to follow
the impact on water bodies (DE 148).
Footnote (1)
Add HOI (EURATEX 32, EURATEX 147), as HOI is only present in pretreatment of
synthetic knitwear (DE 163).
Add all metalloids (EURATEX 32, EURATEX 147), except for zinc, as they are
present in specific processes only (DE 164).
Add sulphides as they are not relevant in all processes (DE 390).
Add surfactants (EURATEX 147).
Footnote (2)
Add the following parameters: biodegradability (EURATEX 32, EURATEX 147),
colour
(DE 161,
EURATEX 32,
EURATEX 33,
EURATEX 147),
HOI
(EURATEX 32, EURATEX 35, EURATEX 147), TP (CZ_A 6, CZ_B 88, DE 128,
EURATEX 32, EURATEX 147,) and toxicity (BE 24, DE 168, EURATEX 32,
EURATEX 147).
Modify the footnote to include monitoring when waste water is treated by a
downstream WWTP (FR_A 64).
Delete Footnote (2). It is important to monitor these parameters as they affect the
downstream WWTP (SE 45).
Footnote (4)
Amend the footnote to: “One or an appropriate combination of the toxicity parameters
can be used”, as one test might be sufficient (DE 353).
Add a risk assessment as a criteria to determine which combination of the toxicity
parameters is appropriate (AT 37).
Amend the footnote to require monitoring toxicity only when other parameters or tests
indicate that it will be useful (e.g. biodegradability), and add one flora and one fauna
test as a minimum to provide more consistent and comparable results (UK 12).
Footnote (5)
Clarify what a significant change is (DE 388, DE 389).
Maintain the footnote but amend the wording as follows: “the effluent characterisation
is carried out before starting operation of the plant or for existing plants, within 1 year
after the publication of these BAT conclusions, and after each change that may
negatively affect the quantity and qualitative characteristics of the waste water streams
pursuant to BAT 2”. This would clarify what “significant changes” mean (EEB 173,
EEB 174).
Additional footnote
Add a minimum monitoring frequency of yearly for periodical measurements, if
emission levels are significantly stable (EURATEX 39).
Apply monitoring for metals only when the metal is identified as relevant in the
integrated permit (in case of direct discharge) or in the agreement with the WWTP (in
case of indirect discharge) (CZ_A 5, CZ_B 86).
Reduce or remove monitoring of AOX, COD and biodegradability, if toxicity tests are
carried out, in order to avoid the risk of duplication or overlap of the monitoring
parameters with the same degree of information (UK 10).
Amend the footnote to increase the monitoring frequency to daily when synthetic
textiles or UV-treatment activities are carried out (EEB 172).
BAT statement
Footnote (1) gives the flexibility to monitor only those parameters that have been
EIPPCB
identified in the inventory of inputs and outputs. It does not seem necessary to repeat
assessment
this in the BAT statement, which is a standard text used in all recently published BAT
:
conclusions.
Determining which laboratory (internal or external) carries out the monitoring is an
implementation issue.
32
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
According to IED Article 15, “the emission limit values shall apply at the point where
the emissions leaves the installation”, which implies that the monitoring is carried out at
the same location. This could be clarified by recalling this provision of IED Article 15
in the “General considerations”.
According to the “Monitoring associated with” column of the table included in BAT 7,
the aim of BAT 7 is to propose a monitoring frequency when a BAT-AEL is proposed,
and for parameters considered KEIs. Therefore, the aim of BAT 7 is not to determine
the treatment efficiencies of the techniques applied.
Standard(s)
When there is no EN standard available, it is possible to use ISO standards or any other
standards (e.g. “Standard Methods for the examination of water and wastewater”) if
they ensure the provision of data of an equivalent scientific quality. This is already
mentioned in the BAT statement.
Activities / processes
The specific processes relevant to emissions to water of each parameter have already
been identified in the KoM conclusions and the data analysis and are listed in the table
of BAT 7. Therefore, a general statement such as “if relevant” is not needed.
Monitoring frequency
BAT 7 aims at setting the minimum monitoring frequency and is based on the TXT
data collection and the environmental risk and performance achievable by using BAT.
The data collection encompasses real cases and therefore accounts for specific
conditions on the amount and nature of the emissions, and the costs of measurements.
Information on 207 monitoring frequencies were reported for 115 emission points.
Because different monitoring parameters require different monitoring frequencies, on
average 2 different frequencies were reported per emission point. Out of these 207
monitoring frequencies, 31 emission points reported yearly, 41 twice per year, 35 four
times per year, 31 monthly, 8 weekly, 6 daily and the rest Other or No information. The
most commonly set frequencies for direct discharge were monthly (14 out of 25
emission points), and for indirect discharge twice per year (36 out of 91 emission
points).
The type of discharge (i.e. direct) has a strong influence on the requirement for a
monthly or quarterly monitoring frequency (e.g. used 2-3 times more often for direct
compared to indirect discharge). This could be reflected for the parameters with a
monthly frequency ( AOX, BOD, COD, colour, metals (Sb, Cr, Cu, Ni, Zn), TN, TOC,
TP and TSS ) or quarterly frequency (HOI, sulphide, other surfactants) in the flexibility
to increase the minimum monitoring frequency for indirect discharge providing the
downstream waste water treatment plant abates the pollutants concerned.
Adsorbable organically bound halogens (AOX)
According to data collected, AOX is monitored in plants carrying out many different
processes. Apart from washing the synthetic fibre or knitwear, AOX may originate
from bleaching (e.g. if using sodium hypochlorite or sodium chlorite), from finishing
(e.g. if using brominated flame retardants or shrink-proofing (Hercosett)) or dyeing
(e.g. dyeing with some vat dyes). Therefore, limiting it only to "pre-treatment of
synthetic knitwear" would potentially increase the environmental risk and impact of
those plants/treatments.
Out of 60 emission points reporting AOX emissions to water, 13 are connected to
direct discharge and 47 to indirect discharge.. The most common frequency reported
for direct discharge is monthly (5 emission points) and for indirect discharge four times
per year (15 emission points).
The monthly monitoring frequency seems reasonable due to wide fluctuations (min.-
max. range) in the emissions profile. However, a footnote indicating the reduction of
monitoring frequencies in the case of indirect discharge could be added.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
33
Background paper – Final meeting for the review of the TXT BREF
Alkylphenols and alkylphenol ethoxylates
The alkylphenol ethoxylates that can be monitored under this parameter are those listed
in standards EN ISO 18857-1 (e.g. mixture of 4-nonylphenol isomers) and 18857-2
(OP, OP1EO, OP2EO, NP, NP1EO, NP2EO)5.
Regarding setting "pre-treatment of knitwear" as the only relevant process, see the
assessment in AOX above.
As alkylphenols and alkylphenol ethoxylates are non-ionic surfactants, they could be
moved to the section on surfactants.
Biochemical oxygen demand (BODn)
There is indeed a new standard, EN ISO 5815-1, for monitoring BODn which could be
mentioned.
According to the data collection, out of 85 reported BODn data sets, 4 reported weekly
and 1 daily monitoring frequency. According to the ROM and the existing TXT BREF,
BOD5, COD/TOC, Colour, TN, TP or TSS are common parameters measured for
controlling the operation of the biological waste water treatment in the textile sector.
Regarding setting "pre-treatment of knitwear" as the only relevant process, see the
assessment in AOX above.
Biodegradability
The monitoring of biodegradability of the effluent could be a valuable parameter to
control the environmental impact of both direct and indirect discharges. Only two data
sets for indirect discharge (SE119 and SE120) were reported in the data collection.
The characteristics of individual waste water streams are addressed in BAT 2,
including their bioeliminability. Biodegradability could be another factor to consider in
BAT 6.
Chemical oxygen demand (COD)
BAT 7 aims to set the minimum monitoring frequency which can be increased in the
implementation. According to the data collection, out of 97 COD data sets, 6 reported
weekly monitoring and 5 a daily monitoring frequency. Therefore, the proposal does
not seem to be supported by the data collection.
Colour
BAT 7 aims to set the minimum monitoring frequency, which can be increased in the
implementation. In the data collection, out of 22 plants reported data sets, only 2
reported a daily monitoring frequency. Therefore, the proposal does not seem to be
supported by the data collection.
In the scope of EN ISO 7887, it is indicated that Method B (use of
(spectro)photometer) is appropriate for industrial water with little colour. Methods C
and D (based on hexachloroplatinate concentration) are suitable for assessment of
water colour in water treatment plants. The method in the SCA blue book seems to be
similar to Method B from EN ISO 7887.
Hydrocarbon oil index (HOI)
Based on the data collection, only 2 out of the 34 emission points that reported HOI
emissions to water measure HOI monthly. Therefore, the proposal does not seem to be
supported by the data collection.
20 plants out of the 30 plants that reported HOI emissions to water do not treat
knitwear or wash synthetic fibres.
It seems reasonable to add Footnote (1) to HOI, as indeed it may be relevant only for
certain preparations, auxiliaries or incoming fibres.
Metals / metalloids: Chromium (Cr)
Metal-complex dyes may contain chromium. This could be clarified by adding metal
oxide dyes as an example of chromium-containing dyes in activity/process.
5 4-(1,1,3,3-tetramethylbutyl)phenol (OP), and its mono- (OP1EO) and diethoxylate (OP2EO), 4-nonylphenol (mixture of isomers)
(NP), and its mono- (NP1EO) and diethoxylate (NP2EO)
34
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Metals / metalloids: Copper (Cu)
According to the data collection, 82 plants report 89 data sets for emissions of copper;
of these, 70 data sets are for dyeing and 15 data sets for printing processes. 13 plants do
both processes (e.g. BE008, DE025, DE049, ES058, FR131) and Plant BE009 only
does printing. The relevant processes to monitor this parameter seem to be “Dyeing”
and “Printing with dyes”, due to use of dyes containing this metal.
Metals / metalloids: Nickel (Ni)
According to the data collection, 60 plants report 65 data sets for emissions of nickel;
of these, 53 data sets are for dyeing and 14 data sets for printing process. 11 plants do
both processes (e.g. BE008, DE025, DE032, DE049, ES058, FR131) and Plant BE009
only does printing. The relevant processes to monitor this parameter seem to be
“Dyeing” and “Printing with dyes”, due to use of dyes containing this metal.
Metals / metalloids: Hexavalent chromium (Cr(VI)
In EN ISO 23913:2009 in Section “4 Interferences”, it is hinted that reducing agents,
oxidising agents (like peroxacetic acid, or permanganate), strong alkalinity, colours or
turbidity in the sample may lead to biases and interfere with chromium (VI)
determination. The procedures (either analytic, interpretative or calculations) to
accommodate for these interferences are explained in the standard. For strong alkaline
samples, pretreatment with acids (HCl, H2SO4) may be needed. EN ISO 23913 is
preferred over EN ISO 10304-3 because it is more specific for this pollutant, more
precise (LoD), and has less uncertainty.
The same standards are used in other BAT conclusions (e.g. WT, STS).
Metals / metalloids: Zinc (Zn)
According to the data collection, 80 plants report 88 data sets for emissions of zinc to
water; of these, 71 plants report carrying out dyeing and 9 plants do not report dyeing,
but other pre-treatment processes, printing (15 data sets) and coating (AT004, BE009,
BE013, FR135, IT061, IT069, IT074, IT076, IT079). The relevant processes seem to
be “All processes” because the source can be also raw material (viscose fibres),
cationic dyes and bleaching (Zn added to start chemical reaction).
Pesticides
BAT 4a requires the operator to control the level of ectoparasiticides on the incoming
textile material (e.g. raw wool), because they can be the source of these pollutants in
the effluent.
A total of 13 data sets were provided, with 5 emission points/plants (IT076, IT092,
IT097, UK128, UK129). 2 plants from UK (6 data sets) measure every 3 months; IT
plants report ‘Other’ frequency.
Perfluorinated compounds
The list of standards is given in a similar way as in all other BAT conclusions. The use
of EN standards guarantees the scientific quality and comparability of the
measurements.
In addition, Table 3.2 of D1 includes the monitoring standards reported in the data
collection for PFOA, PFOS and PFAS.
To provide more information about the monitoring standards for PFOA, PFOS and
PFAS, ISO 25101 and ISO 21675 can be mentioned in Section 3 of the review of the
TXT BREF.
Regarding the name to identify perfluorinated compounds (PFCs), the OECD refers to
PFCs using the abbreviation PFASs (per and polyfluoroalkyl substances). According to
the document published by the OECD6 in 2013 named: ‘Synthesis paper on Per- and
Polyfluorinated Chemicals (PFCS)’, in the past, PFASs (chemicals that contain one or
more perfluoroalkyl moieties, –CnF2n+1) were often referred to as “PFCs” (per- and
6 https://www.oecd.org/chemicalsafety/risk-management/synthesis-paper-on-per-and-polyfluorinated-chemicals.htm
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
35
Background paper – Final meeting for the review of the TXT BREF
polyfluorinated chemicals), but this term can also be understood as perfluorocarbons.
The Stockholm Convention7 only includes perfluorooctanoic acid (PFOA), its salts and
PFOA-related compounds.
Table 3.2 of D1 of the TXT BREF shows all the compounds reported as
perfluorocarbons in the questionnaires, where more than 8 different compounds were
identified, e.g. per- and polyfluoroalkyl substances, perfluorobutanoic acid,
perfluorodecanoic acid.
Taking into account the above bullet points related to the different names to identify
perfluorocarbons compounds, it seems appropriate to use the internationally accepted
name, proposed by the OECD and which includes a wide range of chemical compounds
consisting of carbon and fluorine.
Not only are finishing processes identified as a source of emissions to water of PFCs.
According to the data collection, there are different associated processes where PFCs
have been reported, e.g. dyeing, shrink-proof finishing, printing, washing synthetic
fibre, desizing, bleaching, coating. It is not clear if they are already present in the
incoming material.
In addition, footnote (1) gives the flexibility to monitor only when PFCs are identified
as relevant in the inventory of inputs and outputs in BAT 2.
Sulphide, easily released (S2-)
According to the data collection, 3 out of 19 emission points reported a monthly
monitoring frequency. Therefore, the proposal does not seem to be supported by the
data collection.
According to the KoM conclusions, it was decided that sulphides were to be considered
a KEI for dyeing with sulphide dyes.
Currently there is no EN standard for monitoring sulphide in emissions to water. The
ISO 10530:1992 or ISO 13358:1997 standards using methylene blue could be
mentioned in the BREF.
Surfactants
The wording of the parameter (‘Surfactants’) is generic and enables the competent
authority to specify the monitoring of the group or individual surfactants, based on the
inventory and relevance as related to BAT 2.
The only available EN standard at the time of drafting the document was EN 903 for
anionic surfactants. The national standards reported to be used for various surfactants
are given in Table 3.5 of D1.
No specific surfactants (e.g. like hardly biodegradable) are singled out in BAT 7.
BAT 16a is not related to monitoring, but deals with substitution of surfactants like
AP/APEO with biodegradable ones.
A total of 36 emission points reported 96 data sets, proving that monitoring of
surfactants in the effluents is important in the textile sector. If EN standards are not
available, BAT is to use ISO, national or other international standards that ensure the
provision of data of an equivalent scientific quality. The national standards reported to
be used for various surfactants are given in Table 3.5 of D1.
Total nitrogen (TN)
BAT 7 aims at setting the minimum monitoring frequency and is based on the data
collection, which encompasses real cases.
A total of 8 out of 18 emission points with direct discharge to water are monitored once
every month. On the other hand, no emission points are monitored either once every
week or once every three months. This shows that the data collection does not support
the proposed changes.
The aim of BAT 7 is not to set a monitoring frequency to check the maintenance
operations of waste water treatment plants.
Total organic carbon (TOC)
BAT 7 aims to set the minimum monitoring frequency, which can be increased in the
implementation phase.
7 http://www.pops.int/TheConvention/ThePOPs/AllPOPs/tabid/2509/Default.aspx
36
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
According to the data collection, none of the 21 TOC data sets reported a weekly
monitoring frequency. This shows that the data collection does not support the
proposed changes.
Total phosphorus (TP)
EN ISO 6878 is included in Annex 2 “Standards for the measurement of emissions to
water” of the ROM as a Standard Method for total phosphorus (TP).
The interferences affecting the accuracy of measurements for each standard are usually
described in its annexes or in a specific section. As these interferences are clearly
identified in each standard, there is no reason to exclude the standard.
Among the standards in BAT 7 is included EN ISO 11885:2009 by ICP-OES.
A monitoring frequency of once every week fulfils the minimum monitoring frequency
proposed of once every month. It is in the domain of the competent authority to set a
stricter monitoring frequency.
The aim of BAT 7 is not to set a monitoring frequency to check the maintenance
operations of waste water treatment plants.
According to the TXT data collection, the most common monitoring frequency, for
direct and indirect discharges, is monthly (14 out of 58 emission points to water),
followed by four times per year (10 out of 58 emission points to water each of them)
and twice a year (9 out of 58 emission points to water each of them).
Total suspended solids (TSS)
BAT 7 aims to set the minimum monitoring frequency, which can be increased in the
implementation phase.
According to the data collection, out of 87 TSS data sets, 4 reported daily monitoring
and 4 a weekly monitoring frequency. Therefore, the proposal does not seem to be
supported by the data collection.
Toxicity
According to the data collection, toxicity was reported from 3 indirect discharge
emission points (10 data sets) and 10 direct discharge emission points (35 data sets).
Footnote (5) requires the competent authority to decide on the monitoring frequency
(relevance) based on a risk assessment, after effluent characterisation, including in this
assessment the ability of the downstream waste water treatment to abate toxic
compounds.
The frequency of toxicity monitoring may be based on the information on the specific
toxic chemicals whose relevance is determined in the inventory of inputs and outputs
from BAT 2.
It is not clear why the wording “based on a risk assessment” should be omitted.
Additional parameters
The monitoring of pH and temperature as key parameters of the waste water streams is
set in BAT 6. According to the ROM, NH4-N is usually measured to control the
nitrification step of a biological waste water treatment plant or to control the effluent
toxicity and is therefore an important parameter for the good operation of the waste
water treatment plant.
However, the TWG did not conclude at the Kick-off Meeting to consider NH4-N as a
KEI. In recent BAT conclusions, there is a tendency not to define monitoring and BAT-
AELs for NH4-N, but rather to use it to assess the performance of a biological waste
water treatment plant. Instead, BAT-AELs and monitoring for total nitrogen (TN) were
proposed, as this parameter better reflects the eutrophication potential.
Footnote (1)
The HOI parameter can be present in the effluents of pretreatment of synthetic knitwear
or washing of synthetic fibres.
Footnote (1) is not deemed necessary for metalloids or sulphides since the processes
relevant for their monitoring are already indicated in BAT 7.
Because surfactants are widely used in many pretreatment and washing processes or
because they are added as a component to many other preparations used in textile wet
treatments, adding Footnote (1) to surfactants seems unnecessary.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
37
Background paper – Final meeting for the review of the TXT BREF
Footnote (2)
It is not clear why biodegradability would be monitored only for direct discharges,
since (only) 2 data sets were reported and they were for indirect discharge. In addition,
the monitoring frequency for biodegradability and toxicity will be decided based on
effluent characterisation, according to Footnote (5). Similarly, for colour (15 plants
reported data, 5 of them with indirect discharge), HOI (90 plants reported data, 68
reported indirect discharge), Total P (59 plants reported data, 38 reported indirect
discharge) and toxicity (13 plants reported data, 3 reported indirect discharge), plants
that report indirect discharge reported monitoring these parameters. According to the
data collection, these parameters (biodegradability, colour, HOI, Total P and toxicity)
are monitored for indirect discharges as well.
For the issue of toxicity monitoring for indirect discharge only, see the assessment
under Toxicity above.
A BAT-AEL for HOI is proposed for indirect discharge.
It is important to know whether the effluent discharged indirectly, to be treated in a
downstream waste water treatment plant, contains non-biodegradable and toxic
compounds (e.g. the qualitative parameter colour is often used where dyes are present
in the effluent, as they can be non-biodegradable and/or toxic). It is not clear why
plants discharging indirectly would not need to monitor these parameters.
Footnote (2) could be replaced by footnote (6), since it is important to monitor these
parameters before they are abated in the downstream WWTP (e.g. COD/TOC, BOD,
TSS and Total N) to protect its performance/operation.
Footnote (4)
Indeed, the competent authority may conclude that one test could be sufficient and
Footnote (4) could be amended accordingly.
The decision on a combination of toxicity tests is in the domain of the competent
authority due to local circumstances and national and EU legislation pertaining to the
environmental quality standards of the particular water body.
The competent authority is free to decide on the method or combination of methods to
be used, taking into account various aspects (e.g. the biodegradability, and flora and
fauna tests). Keeping the text generic, without making a combination of flora and fauna
methods compulsory, seems to give more flexibility and accommodate more possible
outcomes.
Footnote (5)
Significant change is any change that can significantly affect the characteristics of the
waste water and that would therefore require a new assessment of these characteristics.
The wording “significant change” used in the footnote may be clarified by replacing it
with a description, e.g. “change that may negatively affect the quantity and qualitative
characteristics of the waste water streams pursuant to BAT 2”.
Additional footnote
Effluents of the textile sector can fluctuate and change a lot, based on the production
demands. This is particularly true for plants working on commission. Therefore, a
footnote on decreasing the minimum monitoring frequency in the case where emission
levels are stable does not seem relevant..
Monitoring of emissions of metals to water is carried out for the processes where they
have the potential to occur (e.g. dyeing), as specified in the “Activities/processes”
column of the table.
Although toxicity provides similar information to AOX, COD and biodegradability,
these parameters on their own give more specific information on the presence and
characteristics of certain hazardous compounds or groups of compounds that are
available from the toxicity test of the effluent. The information provided may ‘overlap’
in the sense that the parameters mentioned would all detect the same effect of the
pollutants/compounds (e.g. the toxicity), but the identity and concentration of specific
compounds or groups of compounds causing the toxicity (important for their
abatement) would be missing.
Only one plant (CZ015) reported adding UV stabilisers in dyeing. No additional
information regarding UV treatments was received in the data collection via
questionnaires, to support the comment and assess the influence of UV treatment on the
monitoring frequency.
38
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
According to the data collected, there is no significant difference in the monitoring
frequency between plants treating synthetic fibres versus plants treating other fibres.
The type of discharge (i.e. direct) has a much bigger influence on the requirement for a
monthly monitoring frequency (e.g. used 2-3 times more often compared to indirect
discharge).
BAT statement
To add in General considerations a provision that the emission levels associated with
the BAT-AELs for emissions to water apply at the point where the emission leaves the
installation.
Activities / processes
To change activities/processes for copper, nickel and zinc to “Dyeing” and “Printing
with dyes”.
Monitoring frequency
To add new footnotes to clarify the adaptation of monthly monitoring frequency (for
the parameters AOX, BOD, COD, colour, metals (Sb, Cr, Cu, Ni, Zn), TN, TOC, TP
and TSS), and quarterly monitoring frequency (for the parameters HOI, sulphide, other
surfactants) in the case of indirect discharge.
Adsorbable organically bound halogens (AOX)
To clarify the adaptation of monitoring frequencies in the case of indirect discharge.
Biodegradability
To add biodegradability as a factor to be considered for individual waste water streams
in BAT 2.
Biochemical oxygen demand (BODn)
To add a new standard, EN ISO 5815-1.
Hydrocarbon oil index (HOI)
To add Footnote (1).
EIPPCB
proposal:
Metals / metalloids:
Chromium (Cr)
To add metal oxide dyes as an example of chromium-containing dyes in
activity/process.
Copper (Cu)
To specify dyeing/printing as concerned processes
Nickel (Ni)
To specify dyeing/printing as concerned processes
Pesticides
To change the frequency to be decided after effluent characterisation (same as
biodegradability).
Perfluorinated compounds
To change the name of perfluorinated compounds.
Surfactants
To group the three different types of surfactants (anionic, cationic and non-ionic).
Footnote (2)
To delete the footnote.
Footnote (4)
To change it to accommodate for the option to have “one or a combination of
monitoring standards/methods”.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
39
link to page 118 link to page 110 link to page 121 link to page 110
Background paper – Final meeting for the review of the TXT BREF
Footnote (5)
To clarify the text by describing the meaning of significant change.
New Footnote (6) and Footnote (7)
To clarify the adaptation of monitoring frequencies in the case of indirect discharge.
1.4.2.2
Monitoring channelled emissions to air
Location
P. 726 – Section 5.1.2– BAT 8
in D1:
BAT 8. BAT is to monitor channelled emissions to air with at least the frequency given
below and in accordance with EN standards. If EN standards are not available, BAT is
to use ISO, national or other international standards that ensure the provision of data
of an equivalent scientific quality.
Minimum
Monitoring
Activities /
Substance/parameter
Standard(s)
monitoring
associated
processes
frequency
with
Singeing
Once every
CO
EN 15058
Combustion
—
3 years
plants
Fabric
production
Once every
Dust
EN 13284-1
Singeing
0
year (1) (2)
Thermal
treatment
Coating (3)
Flame lamination
Printing (3)
No
EN
Current
Singeing
Once every
Formaldehyde
standard
0
text in
Thermal
year (1) (4)
available
D1:
treatment
after
finishing
and
after printing (3)
Coating (3)
Printing (3)
No
EN
Once every
NH
Thermal
3
standard
0
year (1) (5)
available
treatment
after
finishing
and
after printing (3)
Singeing
Once every
NO
Combustion
—
X
EN 14792
3 years
plants
Combustion
Once every
SO
—
X (6)
EN 14791
plants
3 years
Coating
Lamination
Printing
Once every
TVOC
EN 12619
0
Singeing
year (1) (7)
Thermal
treatment
40
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
(1) The measurements are carried out at the highest expected emission state under normal
operating conditions.
(2) In the case of a dust mass flow of less than 50 g/h, the minimum monitoring frequency
may be reduced to once every 3 years.
(3) The monitoring only applies when the substance concerned is identified as relevant in
the waste gas stream based on the inventory of inputs and outputs mentioned in BAT
2.
(4) In the case of a formaldehyde mass flow of less than 2.5 g/h, the minimum monitoring
frequency may be reduced to once every 3 years.
(5) In the case of a NH3 mass flow of less than 50 g/h, the minimum monitoring frequency
may be reduced to once every 3 years.
(6) The monitoring does not apply if natural gas only is used as fuel.
(7) In the case of a TVOC mass flow of less than 100 g/h, the minimum monitoring
frequency may be reduced to once every 3 years.
BAT statement
Amend the BAT statement as follows: “BAT is to monitor relevant channelled emissions
to air with at least…”, as only pollutants at detectable concentrations should be
monitored, not all the pollutants listed in the table (CZ_A 8, CZ_B 90).
Activities / processes
Delete for several parameters “Singeing” from the relevant processes, as those
parameters are only relevant for combustion plants (EURATEX 112).
CO
Delete “Singeing” from the relevant processes, as CO is not relevant for “Singeing”
(DE 342, EURATEX 133); CO is only relevant for combustion plants (EURATEX 148).
Dust
Delete “Fabric production and Thermal treatment” from the relevant processes, as dust is
only relevant for “Singeing” (DE 170, EURATEX 149).
Delete “Fabric production and Thermal treatment” from the relevant processes, as the
channelled emissions from these processes are not relevant (EURATEX 112).
Delete “Singeing” and replace “Thermal treatment” with “Finishing”. Dust is only
relevant for combustion plants and not for emissions to air from drying
(EURATEX 133).
Summary
Add in relevant processes “Carpet cropping” or ensure that carpet cropping is included
of
within the definition for fabric production. Carpet cropping is an inherently dusty
comment
process (UK 13).
s:
Add a footnote to reduce the monitoring frequency from once every year to once every
three years (DE 354), for thermal treatment, when there is an alternative control of
emissions or stability of the process (EURATEX 40).
Formaldehyde
Replace “Thermal treatment after finishing and after printing” with “Thermal treatment”,
as formaldehyde can also be formed under incomplete burning conditions. Expand the
monitoring to directly heated thermal apparatus (DE 65).
Delete “Singeing” from the relevant processes and replace “Thermal treatment” with
“Finishing”. Formaldehyde is only relevant for combustion plants, not for emissions
from drying (EURATEX 133).
Replace “Thermal treatment after finishing and after printing” with “Thermal treatment
after finishing”, as the source of formaldehyde emissions to air is drying
(EURATEX 112).
Add a definition for coating which covers carpet back-coating with latex, or clarify that
emissions of formaldehyde from carpet back-coating with latex are covered under
BAT 8. This parameter is a concern from a human health and environmental perspective
when there is a significant risk of it being emitted in significant quantities (UK 14).
Reduce the monitoring frequency from once every year to once every three years, when
the emissions factor concept is applied every year for all recipes (DE 348).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
41
Background paper – Final meeting for the review of the TXT BREF
NH3
Reduce the monitoring frequency from once every year to once every three years, when
the emissions factor concept is applied every year for all recipes (DE 348).
NOX
Delete “Singeing” from the relevant processes as NOx is not relevant for “Singeing”
(DE 343). NOx is only relevant for combustion plants (EURATEX 112,
EURATEX 133).
TVOC
Delete “Singeing” from the relevant processes and replace “Thermal treatment” with
“Finishing”. TVOC is only relevant for combustion plants, not for emissions from
drying. A source of TVOC emissions to air is the use of chemical products
(EURATEX 112, EURATEX 133).
Add a definition for coating which covers carpet back-coating with latex, or clarify that
emissions of TVOC from carpet back-coating with latex are covered under BAT 8. This
parameter is a concern from a human health and environmental perspective when there is
a significant risk of it being emitted in significant quantities (UK 14).
Reduce the monitoring frequency from once every year to once every three years, when
the emissions factor concept is applied every year for all recipes (DE 348).
Mass flow thresholds
Clarify that mass flow threshold refers to the total emission mass flow of the installation,
not to a single stack (DE 70).
Footnote (1)
Add that the emission factor concept described in Section 4.1.2.4 of D1 is used to
determine the highest expected emission. A reliable method is needed to predict the
highest expected emission, as substances change quite often with a wide range of
different recipes (DE 125).
Footnote (3)
Apply Footnote (3) to dust, as monitoring should be carried out only if relevant
emissions are expected (DE 69).
Apply Footnote (3) to formaldehyde for the relevant processes “Singeing”, according to
information included in Sections 2.6.1.1 and 3.5.4 of D1 (IT 11).
Apply Footnote (3) to TVOC as monitoring for coating, lamination, printing and thermal
treatment is only relevant when solvents are used (EURATEX 41).
Footnote (6)
Add LPG, as the sulphur content of LPG is similar to natural gas (IT 10), so SOx
emissions are not relevant for liquid gas in heating units (DE 68).
Apply Footnote (6) to dust for relevant processes “Thermal treatment”, as dust emissions
to air are not relevant when natural gas is used as fuel (EURATEX 40).
Footnote (7)
Clarify that the mass flow threshold refers to the total emission mass flow of the
installation, not to a single stack (DE 67).
Add the three following points, to clarify that the footnote does not contradict
requirements in Article 62, and special provisions reported in Chapter V of the IED:
- organic solvent consumption for coating exceeds 5 tonnes per year;
- organic solvent consumption of lamination exceeds 15 tonnes per year;
- organic solvent consumption for rotary screen printing exceeds 30 tonnes per year
(IT 12).
Additional footnotes
Add a similar footnote to Footnote (1) in BAT 7, to monitor pollutants only when
relevant emissions of these pollutants are expected. For example, ammonia is not a
general pollutant for each finishing process (DE 66, DE 173, EURATEX 151) or
formaldehyde emissions are only relevant when formaldehyde is used in specific
processes or chemicals (DE 171, EURATEX 151).
42
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Add a new footnote to allow for all parameters a monitoring frequency of once every
three years if the technique described in Section 4.1.2.4 of D1 (emission factor concept)
is applied or measurements with low and stable values are achieved (EURATEX 150).
Add a new footnote to increase the monitoring frequency for larger emitters and to
provide more proportionate risk-based monitoring for smaller emitters, as monitoring
once every three years does not provide meaningful data to assess the potential impact of
the emissions to air (UK 15).
BAT statement
Footnote (3) gives the flexibility to monitor only those parameters identified as relevant
in the inventory of inputs and outputs mentioned in BAT 2.
For the other cases where Footnote (3) does not apply, the comment is not clear as to
why the monitored parameters may not always be relevant for the processes concerned.
Activities / processes
According to the data collection, singeing is a widespread process within the textile
industry. Singeing is included under the scope of the BAT conclusions and was also
included in the data collection (see Section 8.5 of the KoM report). It is not clear for
which parameters singeing is not relevant or the reason why.
CO
According to the KoM conclusions, data for CO emissions from singeing should be
collected. The technical justification for the changes proposed in the comment submitted
is not entirely clear. As stated in the scope of the BAT conclusions, when the generated
hot gases are used for direct contact heating, then these processes are included in the
scope of these BAT conclusions.
A total of 3 out of 31 emission points to air associated with the singeing process (i.e.
ES058_{15}, ES058_{35} and SE120_{1}) have reported data for CO. The values
reported for the 3 emission points were: ES058_{15} reported 74.82 mg/Nm3 and 416
g/h, ES058_{35} reported 137.42 mg/Nm3 and 657 g/h, and SE120_{1} reported a
yearly average of 151,246 kg/year.
Singeing is a burning process where CO emissions can be generated by an incomplete
combustion process when using fossil fuels. It is not clear why CO emissions to air are
not relevant for singeing.
EIPPCB
assessme
Dust
nt:
The data collection shows that 13 emission points reported dust measurements for fabric
production in a concentration range from 1 mg/Nm3 up to 23 mg/Nm3 and a mass load
range from 8 g/h to 270 g/h. 20 emission points reported dust measurements for singeing
in a concentration range from 0.2 mg/Nm3 up to 20 mg/Nm3 and a mass load range from
0.8 g/h to 125 g/h. 67 emission points reported dust measurements for thermal treatment
in a concentration range from 0.02 mg/Nm3 up to 112 mg/Nm3 and a mass load range
from 0.03 g/h to 461 g/h.
Based on this data, it is not clear why singeing and thermal treatment are not relevant for
dust emissions.
Dust is expected to be generated in combustion processes, either due to the type of fuel
or the textile materials which are in contact with the gaseous products of combustion.
This can be clarified in the
Regarding fabric production, it seems that the 13 EPs are connected to thermal treatment
and not to the fabric production itself (see also the assessment done for Table 5.6).
Monitoring activities were harmonized with activities in table 5.6 (with BAT-AELs) and
are proposed for emissions from singeing and from thermal treatments as steps
associated with pre-treatment, dyeing, printing and finishing. This has been clarified in
the wording of activities/processes column.
The proposed monitoring is based on the data collection and no data were collected
about emissions to air from carpet cropping.
According to the data collection, more than half of the emission points that have
measured dust emissions from thermal treatment have done so with a monitoring
frequency of once every 3 years. This could be reflected by applying Footnote (2) to
thermal treatment.
Regarding the use of an emission factor to reduce the monitoring frequency, no data
have been reported on applying an emission factor for dust.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
43
Background paper – Final meeting for the review of the TXT BREF
Formaldehyde
The processes it is proposed in BAT 8 to monitor are coating, flame lamination, printing,
singeing, and thermal processes after finishing or printing, all of them related to the use
of chemical substances and high temperatures. According to the data collection, the
concentration ranges for each of these processes are: coating and flame lamination from
0.3 to 20 mg/Nm3 and a mass load range from 1.1 g/h to 328 g/h, printing from
0.05 mg/Nm3 to 1.9 mg/Nm3 and a mass load range from 0.3 g/h to 36.5 g/h, singeing
from 1.8 mg/Nm3 up to 4.1 mg/Nm3 and a mass load range from 5 g/h to 20 g/h, and
thermal treatment after finishing and after printing from 0.02 mg/Nm3 up to 20 mg/Nm3.
and a mass load range from 0.1 g/h to 328 g/h. Based on these data, it is not clear why
the processes proposed in BAT 8 are not relevant for emissions of formaldehyde to air.
These emissions could originate either from a combustion process where formaldehyde
is formed (e.g. singeing or flame lamination) or from thermal treatment without a
combustion process (e.g. drying) where formaldehyde or formaldehyde-prone substances
are contained in process chemicals (see BAT 46 and BAT 47). In the latter situation,
Footnote (3) accounts for the cases where process chemicals do not contain
formaldehyde or formaldehyde-prone substances.
More generally, monitoring activities were harmonized with activities in BAT 23 and
table 5.5. BAT-AELs are proposed for emissions from processes and from thermal
treatments as steps associated with them. This has been clarified in the wording of
activities/processes column.
The proposed monitoring is based on the data collection and no data were collected
about emissions to air from carpet cropping.
Emission factors can be one tool to identify that formaldehyde emissions are low.
Whether or not the emission factor concept ensures provision of data of an equivalent
scientific quality than a monitoring standard method is in the remit of the competent
authorities. More generally speaking, there is no EN standard available for
formaldehyde. As stated in the WBP and ROM reference documents, periodic sampling
of formaldehyde can be performed using two different methods with a potential for
difference in the measurement results. High volume isokinetic sampling in an impinging
solution tends to give higher results than low volume non-isokinetic sampling on
adsorption tubes. According to the BAT statement, BAT is to use ISO, national or other
internal standards that ensure provision of data of an equivalent scientific quality.
NH3
Regarding the comment related to the use of emission factors, see the assessment done
for formaldehyde.
Add the new monitoring standard for channeled emissions of NH3 to air, which was
published on 30.04.2020: EN ISO 21877:2019.
Monitoring activities were harmonized with activities in table 5.7 (with BAT-AELs) and
are proposed for emissions from coating, printing and finishing, and from thermal
treatments associated with them. This has been clarified in the wording of
activities/processes column.
NOX
A total of 5 out of 31 emission points to air associated with the singeing process (i.e.
PT115_{10}, ES058_{35}, ES058_{15}, PT109_{3} and SE120_{1}) have reported
data for NOx. The values reported for the 5 emission points were: PT115_{10} reported
8.2 mg/Nm3 and 28 g/h, ES058_{35} reported 18.8 mg/Nm3 and 90 g/h, ES058_{15}
reported 18.8 mg/Nm3 and 105 g/h, PT109_{3} reported 27.1 mg/Nm3 and 26 g/h and
SE120_{1} reported a yearly average of 135.53 kg/year.
Singeing is a burning process where NOx emissions can be generated in the combustion
process when using fossil fuels. It is not clear why NOx emissions to air are not relevant
for singeing.
TVOC
A total of 20 out of 31 emission points to air associated with the singeing process have
reported data for TVOC in a concentration range from 0.5 mg/Nm3 to 64 mg/Nm3, and a
mass load range from 4 g/h to 353 g/h. According to the data collection, it is not clear
why TVOC emissions to air are not relevant for singeing
Drying is included in the definition of thermal treatment. According to the data
collection, 162 emission points reported data for TVOC in a concentration range from
44
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 109 link to page 18 link to page 109
Background paper – Final meeting for the review of the TXT BREF
0.2 mg/Nm3 to 223 mg/Nm3, and a mass load range from 0.04 g/h to 3 380 g/h.
According to the data collection, it is not clear why TVOC emissions to air should only
be relevant for combustion plants.
The proposed monitoring is based on the data collection and no data were collected
about emissions to air from carpet cropping.
Regarding the comment related to the use of emission factors, see the assessment done
for formaldehyde.
Monitoring activities were harmonized with activities in table 5.5 (with BAT-AELs) and
are proposed for emissions from coating, dyeing, finishing, lamination, printing and
singeing, and from thermal treatments as steps associated with them. This has been
clarified in the wording of activities/processes column.
TVOC as a parameter may include CMR substances other than formaldehyde (see Kick-
off meeting report), therefore it is proposed to monitor such substances with the same
frequency as formaldehyde
Mass flow thresholds
See the assessment for each parameter in Section
1.4.8 of this BP.
Footnote (1)
How to determine the highest expected emission state under normal operating conditions
is an implementation issue. Indeed, the technique described in Section 4.1.2.4 of D1 is
an option. There are, however, other alternatives such as techniques described in
Sections 4.1.1.2 and 4.1.2.3 of D1. Therefore, prioritising one technique over the others
does not seem necessary.
Footnote (1) is meant to ensure that the emissions are monitored even at the highest
emission state, even if this might not have been the case for some plants in the data
collection. Such a footnote was used in the latest adopted BAT conclusions (e.g. FDM,
STS) and a provision to apply the measurements to the extent possible could be added
also in these BAT conclusions.
Footnote (3)
According to the data collected, fabric production, singeing and thermal treatment are
processes where relevant dust emissions have been reported (see assessment above
related to dust). It is not clear in which circumstances dust may not be relevant.
Formaldehyde emissions can be generated in a combustion process (e.g. singeing).
Clarification in Sections 2.6.1.1 and 3.5.4 of D1 can be included.
Footnote (7) gives the flexibility to monitor every 3 years, taking into account the use of
a relevant quantity of solvents. Nevertheless, it could be possible to have coating,
lamination, printing or thermal treatment without the use of organic substances. This
could be reflected by applying Footnote (3) to the parameter TVOC.
For consistency with tables 5.5 and 5.7, footnote (3) has been specified for Finishing
processes for formaldehyde and ammonia.
Footnote (6)
The use of LPG is expected to be related to insignificant SOX emissions to air and this
can be further specified.
Dust is not expected from combustion of natural gas; however, when using natural gas
the source of dust is not in the fuel but in the product itself. For example, emission points
PT109_{30}, PT109_{31}, FR135_{1}, PT109_{30}, PT114_{34} and PT109_{29}
reported a dust concentration range from 17.6 mg/Nm3 to 45.9 mg/Nm3 and a mass load
range from 14.4 g/h to 411 g/h, for processes associated with thermal treatment and
using natural gas as fuel.
Footnote (7)
Regarding the comment about the mass flow, see the assessment in Section
1.3.1 and
Section
1.4.8 of this BP.
The monitoring frequency proposed in Footnote (7) does not contradict the requirements
of Article 62 of the IED, i.e. measuring once every year fulfils the minimum monitoring
frequency of once every 3 years proposed in Footnote (7).
On the other hand, according to the provisions of Part 6 of Annex VII to the IED,
channels to which abatement equipment is connected, and which at the final point of
discharge emit more than an average of 10 kg/h of total organic carbon, shall be
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
45
Background paper – Final meeting for the review of the TXT BREF
monitored continuously. According to the data collections, no plant reported a TVOC
load over 10 kg/h. The maximum mass load reported in the data collection for TVOC
was 3.4 kg/h (IT059_{3}).
Additional footnotes
Adding a general footnote on all parameters that the monitoring requirement may not
apply when the substance is not present in the waste would undermine the usefulness of
the BAT for the permit writers. Guidance is given by the "Activities / processes"
column, which already considers the expected relevance of each substance for each
process.
All the parameters (except ammonia and formaldehyde) may be monitored once every 3
years, if the emissions are below a specific mass flow threshold, which could be
estimated by using the emission factor concept.
In the case of higher emissions, however, it is not clear how emission factors could
substitute actual measurements especially in the cases where EN standards are available.
In all recently published BAT conclusions (WI, FDM, etc.), TVOC is monitored as per
EN 12619. Introducing another type of monitoring would not be consistent with the
other BAT conclusions and would lead to distortions in terms of a level playing field and
in terms of data comparability.
The principle of proportionality is encompassed in the proposed BAT 8 as, for some
parameters, the monitoring frequency is higher for larger emission sources and lower for
smaller emission sources.
BAT statement
No change.
Activities / processes
For the proposal of comments regarding activities/processes, see the following
parameter-specific points.
CO
No change.
Dust
To delete fabric production in the column of Activities / processes.
To add combustion in the column of Activities / processes
To clarify in the column of Activities / processes to which processes the thermal
treatments are associated.
Formaldehyde
To add Finishing Activity/Process and clarity to which processes the thermal treatments
EIPPCB
are associated.
proposal:
NH3
To add a new EN monitoring standard.
To add Finishing Activity/Process and clarity to which processes the thermal treatments
are associated.
NOX
No change.
SO2
To implement a minor editorial change in the name of the parameter, as combustion
plants are the main source of emissions to air.
TVOC
To add Finishing Activity/Process and clarity wo which processes the thermal treatments
are associated.
To add monitoring of CMR compounds.
46
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Mass flow thresholds
To delete footnotes (4) and (5).
Footnote (1)
To add ‘to the extent possible’.
Footnote (3)
Add Footnote (3) for emissions to air for TVOC.
To add footnote (3) to Finishing for formaldehyde and ammonia.
Footnote (6)
To amend the footnote to include LPG as fuel with insignificant SO2 emissions to air.
Footnote (7)
No change.
Additional footnotes
Not to add additional footnotes.
1.4.3
Water use and waste water generation
1.4.3.1
Techniques for reducing water consumption and waste water
generation
Location in
P. 727 – Section 5.1.3 – BAT 9
D1:
BAT 9. In order to reduce water consumption and waste water generation, BAT is to
use all of the techniques given below.
Technique
Description
Applicability
Management techniques
A water management plan is part of
the EMS (see BAT 1) and includes:
flow diagrams and a water mass
balance as part of the inventory
Current
of inputs and outputs mentioned The level of detail of
text in D1:
in BAT 2;
the water management
Water
establishment of water efficiency plan and water audits
a
management plan
objectives;
will
generally
be
and water audits
implementation
of
water related to the nature,
optimisation
techniques
(e.g. scale and complexity of
control
of
water
usage, the plant
reuse/recycling, detection and
repair of leaks).
Water audits are carried out at least
annually to ensure the objectives of
the water management plan are met.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
47
Background paper – Final meeting for the review of the TXT BREF
This includes:
optimised
combination
of
processes
(e.g.
pretreatment
processes
are
combined,
bleaching of textile materials is
Production
avoided before dyeing in dark
b
Generally applicable
optimisation
shades);
optimised scheduling of batch
processes (e.g. dyeing of the
textile materials in dark shades is
carried out after dyeing in light
shades in the same dyeing
equipment).
Design and operation techniques
Only applicable to new
plants or major plant
upgrades.
Processes that do not use water
Water-free
The applicability may
c
include plasma, laser or ozone
processes
be restricted by the
treatments.
characteristics of the
textile materials and/or
product specifications
Batch processes are carried out with
Optimisation of low-liquor-ratio
systems
(see
the amount of Section 5.9.4).
d
process
liquor Continuous processes are carried out
used
with low-volume application systems
(see Section 5.9.4).
This includes:
water-free cleaning (e.g. by
wiping or brushing the tanksʼ
Optimised
inner surfaces);
e
cleaning of the
multiple cleaning steps with low
equipment
amounts of water; the water of
the last cleaning step may be
reused to clean another part of
equipment.
This includes:
use of auxiliary tanks for
Optimised batch
temporary storage of:
processing,
o spent washing or rinsing Generally applicable
f
washing
and
water;
rinsing of textile
o fresh or spent process
materials
liquor;
multiple drain and fill steps for
rinsing and washing with low
amounts of water.
This includes:
timely process liquor preparation
based
on
online
pick-up
Optimised
measurements;
continuous
automatic closure of the washing
processing,
water inflow when the washing
g
washing
and
machine stops;
rinsing of textile
countercurrent
rinsing
and
materials
washing;
intermediary
mechanical
dewatering of textile materials
(see BAT 12 b) to reduce the
carry-over of process chemicals.
48
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Reuse and recycling techniques
Reuse and/or recycling of water
streams (preceded or not by water
treatment), e.g. for cleaning, rinsing,
Water
reuse cooling or in the processing of textile
h
and/or recycling
materials. The degree of water
reuse/recycling is limited by the
content of impurities in the water
streams.
Generally applicable
Process liquor, including the process
liquor extracted from textile materials
by
mechanical
dewatering
(see
Reuse of process BAT 12 b), is reused after analysis
i
liquor
and make-up if needed.
The degree of reuse of process liquor
is limited by
the content of
impurities.
Whole BAT
For increased clarity and simplicity, restructure the BAT conclusion into two BAT
conclusions: one on water management and the other on techniques to reduce water
consumption and pollutants in the effluents. Make separate techniques of the
techniques not grouped under the title “optimisation/optimised” not to lose relevance
(DE 418). See also the general comment (DE 396) on Chapter 5.
BAT statement
Adjust the applicability or change the BAT statement to use "all" of the techniques
because some techniques are not applicable to all installations. For example, it is not
consistent to have both techniques c and d (DE 175, FR_B 6).
Management techniques
Technique a
Specify whether the inventory of water inputs and outputs (BAT 2) is also covered by
the water management plan (BAT 9) (AT 40).
Set BAT 9a as a "stand-alone" BAT conclusion because a water management plan is
a prerequisite for all techniques for the reduction of water consumption. It should be
implemented in all installations (DE 355). See the proposal, attached to the comment,
regarding prioritising this technique in a separate BAT conclusion (DE 418).
Summary
Add a reference to BAT 5 in technique a because the monitoring results (of water
of
consumed and waste water generated) shall be taken into account when optimising
comments:
water consumption and releases (FR_A 4).
Decrease the frequency of water audits (e.g. every 3 years), provided that the
measures to be implemented between audits are monitored and controlled at least
annually to ensure that the objectives are met (PT 12).
Amend the applicability to also provide for a lower frequency of auditing for smaller
less complex sites (e.g. single process) to once every 4 years (UK 16).
Technique b
Specify distinct combinations of pretreatment processes in the description, e.g.
washing and bleaching or washing and desizing (DE 384). Explain in the description
what "optimised processes" are in Europe (DE 418).
Specify that not all combinations of processes are possible, especially if the chemicals
used are incompatible. Also, scheduling may be limited by demands of processes, e.g.
if the process needs a subsequent step within a defined time (EURATEX 152).
Design and operation techniques
Technique c
Delete the technique as laser, plasma and ozone techniques are emerging techniques
and not BAT. There is no information available about the implementation of the
laser/plasma technique in the questionnaire of Plant DE042. As regards the ozone
technique, there is only one plant mentioned which is located in Tunisia (FR_B 5).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
49
Background paper – Final meeting for the review of the TXT BREF
Change the applicability: laser and ozone treatment are only applicable for garment
treatment, and plasma only applicable for pretreatment, e.g. of wool (DE 345,
EURATEX 153).
Specify the applicability restrictions for different treatments in line with the
descriptions of techniques in Chapter 4 or delete them. For example, the description
for laser and plasma treatment in Section 4.7.1.1 of D1 does not justify any restriction
but states broad applicability. Similarly, ozone treatment is referred to in
Section 4.4.7.3 of D1, which states general applicability to cellulose, keratin and
synthetic fibre (see also EEB 100 and EEB 105) (EEB 106, EEB 120).
Technique d
Mention water-free processes under technique d, with the same structure as technique
e: with water-free processes as a first bullet and the second bullet the remaining
current description because technique c and technique d cannot be applied at the same
time (FR_B 6).
Split this technique into two separate techniques: i) Exhaust processing at low liquor
ratio (LR 1:3–1:6) for discontinuous pretreatment and exhaust dyeing of all fibres
except wool and silk; and ii) minimisation of the volume of padders and segregation
of spent padding liquors for dyeing, finishing, laminating or coating for reuse or
disposal and minimisation of the system volume from rotary printing and recycling of
residual printing pastes (DE 418).
Change the applicability to “only applicable to new plants or major plant upgrades”
because the 'liquor ratio' depends on the type of dyeing machines; existing machinery
is not always equipped or adjustable for low-water processes and would therefore be
reduced only by replacing the existing machines with new ones (IT 13,
EURATEX 92).
Technique e
Change the applicability to "only applicable to new plants or major plant upgrades"
because water-free cleaning (wiping, brushing the tanks' inner surface) cannot be
carried out in a safe way (safety restrictions) in an existing tank park and screen
cleaning system (EURATEX 92).
Add techniques for rotary printing, i.e. mechanical pre-cleaning of squeegees and
rotary screen and of drums containing printing pastes, segregation of high
concentrated spent liquors (padding liquors) before washing the padder (proposal
attached to the comment) (DE 418).
Technique f
Change the applicability to “only applicable to new plants or major plant upgrades”
because the implementation of auxiliary tanks for temporary storage requires the new
piping to collect and transport the exhausted washing and rinsing waters (IT 41). The
piping/tanks may also be restricted by the space available (EURATEX 92).
Technique g
Delete the bullet “intermediary mechanical dewatering of textile materials” because
its relevance for reducing water consumption (the purpose of BAT 9) is not clear. The
technique is more relevant to reduce energy consumption and is already listed in BAT
12 (FR_A 43).
Add techniques: counter-current rinsing and washing and intermediary mechanical or
vacuum dewatering of textile materials to reduce carry-over of process chemicals
(proposal attached to the comment) (DE 418).
Replace “online pick-up measurements” with "the pick-up rates pre-programmed
depending on the raw materials used" (FR_A 44).
Change the introductory sentence of the description to "This may include" because
these are only some examples of techniques (FR_B 1).
Change the applicability to: “The applicability may be restricted by the characteristics
of the textile materials and/or product specifications”. Technique g is not generally
applicable because the listed technologies (online pick-up, automatic closure,
countercurrent rinsing, etc.) are not used simultaneously in the same equipment. The
washing of textiles can be done at many stages during the production (EURATEX 7).
Reuse and recycling techniques
Technique h
50
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Change the applicability to: “only applicable to new plants and major plant upgrades”
because the technique requires additional piping, which can only be done during a
major upgrade. Also, reduction of water consumption by recycling of process water
can include high costs, energy, storage and area/spatial demands. It depends on
ecological and economic efficiency (EURATEX 93, EURATEX 154).
In the description, add “On site or off site centralised” to reuse and/or recycling of
water streams. Centralised waste water management/recycling systems, adopted on
site or off site, proved to be highly effective, compared to (single) internal waste
water treatment system, allowing all companies, even the smallest ones, to contribute
in saving water resources (e.g. the Italian textile district of Prato in Tuscany) (IT 15).
Add specific examples of reuse: i) reusing the washing water from continuous
bleaching of cotton woven fabric for scouring and ii) reusing the last rinsing water
from mercerisation for washing after bleaching (DE 418).
Technique i
Change the applicability to: “Applicability may be restricted by impurities, colour and
storage life”. Colour and impurities may hamper reuse. Storage life may also be a
constraint, e.g. it is limited by the use of natural thickeners (CEFIC 28,
EURATEX 94).
Whole BAT
The structure of this BAT conclusion is similar to some recent BAT conclusions (e.g.
STS, FMP).
BAT statement
Several of the techniques listed are not generally applicable and consideration of the
applicability restrictions could be better reflected in the statement. Furthermore,
technique a as a management tool would have merit in all cases where water is
consumed and/or waste water is generated.
According to the data collection on BAT used at the plant level, ‘Water management’
and ‘Optimisation of water consumption’ are used by 86 and 69 out of 106 plants,
respectively, which is much more (4-5 times) than is reported for other techniques,
like ‘Recycling/reuse’ 16 or ‘Reduction of water consumption for cleaning’ (17
plants). This seems to support the argument on generic use of techniques a and b,
with the combination of other techniques.
Management techniques
Technique a
The inventory of water inputs and outputs (BAT 2) could indeed be implemented as
an integral part of the water management plan (BAT 9a) and/or environmental
EIPPCB
management system (BAT 1). This is indicated by the cross references in the
assessment:
description of the technique.
Technique a could be a stand-alone conclusion. However, embedding it in the same
conclusion might strengthen the link between a customised water management plan
and audits and selection and implementation of the appropriate other techniques listed
in the same conclusion. Finally, this structure (i.e. management technique embedded
with other techniques) has already been used in BAT conclusions (e.g. WT, STS).
The reference to BAT 5 is placed after Table 5.1 which is an integral part of BAT 9
and therefore does not seem to be necessary in the description of the individual
techniques. Should Table 5.1 be removed, it would be appropriate to include the
reference in BAT 9a.
The yearly frequency of water audits is harmonised with the one used in other BAT
conclusions (e.g. STS). According to the data collection, 80 % of plants discharge
more than 180 m3 of effluent per day (i.e. at least 18 m3/t of textile treated), which
demonstrates the importance of water consumption for textile plants. Regular auditing
ensures compliance with water consumption objectives; therefore, yearly frequency
of auditing seems reasonable. On the other hand, the level of detail of the audit is
already included in the applicability clause which refers to the nature, scale and
complexity of the plant.
Technique b
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
51
Background paper – Final meeting for the review of the TXT BREF
The examples of combinations of processes given in brackets are not exhaustive but
illustrative. Since BAT 35a refers to more specific combinations of processes for
cotton fibres, it seems more prudent to add these examples there.
Production optimisation would be carried out on a case-by-case basis in each plant for
its specific products and process demands. It is considered that this is a dynamic and
ongoing decision-making process, reflecting the utilisation of the plant’s production
capacity. This technique lays out the principles of production optimisation and these
principles seem to be always applicable. However, parameters to be considered when
optimising the production could be added in the description in Chapter 4.
Technique b1
To better reflect the technical considerations important for recovery/recycling
operations a new technique on segregation of polluted/non-polluted water streams
could be added. This technique is considered management technique and could be
used always. This could be reflected in BAT statement.
Design and operation techniques
Technique c
Section 2.3.7.2.9 “Example plants” of COM Decision 2012/119/EU (BREF
Guidance) states: "Reference(s) to a plant(s) where the technique has been
implemented and from which information has been collected and used to draft the
section of the BREF concerning that technique will be listed, including an indication
of the degree to which the technique is in use in the Union or worldwide.” The
“Example plants” sections of ozone (Section 4.4.7.3 of D1 of the TXT BREF) and
laser/plasma techniques (Section 4.7.1.1 of D1 of the TXT BREF) follow this rule.
Article 3(10) of the IED states that a technique is available if “developed on a scale
which allows implementation in the relevant industrial sector, under economically
and technically viable conditions, taking into consideration the costs and advantages,
whether or not the techniques are used or produced inside the Member State in
question, as long as they are reasonably accessible to the operator”. According to the
references listed in Sections 4.4.7.3 and 4.7.1.1 of D1 of the TXT BREF, the
techniques mentioned are commercially available and implemented on the industrial
scale; therefore, they are not considered emerging.
The use of these techniques is versatile and under intensive development; therefore, it
seems better to keep the description very generic and brief. Moreover, the specific
uses in regard to the form of the textile substrates do not seem to be the (technical)
applicability restrictions but currently the most common modes of use. However, this
information could be added in the descriptions of techniques in Chapter 4.
These technologies are related to the instalment of new treatment lines/machinery and
the corresponding utilities, which correspond to the definition of major plant upgrade.
Additionally, the currently commercialised techniques cannot universally (for all
types of fibre, product, quality) replace the performance of conventional wet
processing treatments. All these issues are reflected in the proposed applicability
restrictions and could be further detailed in Chapter 4.
Laser and plasma treatment do not use water, while ozone treatment is typically
conducted in small amounts of water (as carrying medium).
Technique d
Technique c and technique d are not mutually exclusive: one plant could have a
water-free production line and a second line based on wet processes. Merging both
techniques could be an option but would make the understanding more difficult
considering the applicability restrictions of technique c.
It is not clear why these techniques would need to be separated. The proposed more
detailed descriptions are already included in BAT conclusions with other
environmental objectives (e.g. BAT 28 on disposal of spent process liquors or
BAT 44 for recovery of printing paste).
Existing machinery can hardly be upgraded with low-liquor-ratio or low-volume
application systems and therefore needs to be replaced (i.e. major plant upgrade).
This could be reflected in the applicability.
Technique e
The examples of water-free cleaning given in the description are illustrative and not
exhaustive. It is not clear why safety restrictions are a limitation for the use of this
52
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
technique. The applicability of water-free cleaning may be limited by accessibility.
This could be reflected in the applicability statement.
The cross-reference to BAT 43 and example of mechanical cleaning in rotary printing
could be added to the description. Handling of highly concentrated spent liquors is
already addressed in BAT 43.
Technique f
The addition of auxiliary tanks and piping in the existing plants may require
substantial redesign of the plant layout due to possible space restrictions, which
would be undertaken as major plant upgrades. This could be reflected in the
applicability.
Technique g
To avoid the contamination of the following rinsing/washing bath, the intermediary
mechanical dewatering may be relevant to enable water reuse. The same technique
can fulfil multiple environmental objectives.
Vacuum dewatering is one of the mechanical dewatering techniques used in the
textiles sector. This is specified in the description of BAT 12b cross-referenced in the
description.
Use of pre-programmed pick-up for liquor preparation is static and not responsive or
customised to momentary changes. Modern machinery with automatic online pick-up
measurement feedback loops may reduce water consumption.
The list of measures given in the technique’s description is neither prescriptive nor
exhaustive as mentioned in the General considerations.
The list of measures given in the technique’s description is illustrative and is not
intended to prioritise the measures nor to stipulate that they are used on the same
equipment simultaneously. In addition, it is not clear which textile materials or which
product specifications limit the applicability of these techniques.
Reuse and recycling techniques
Technique h
The technological factors (like additional piping) and lack of space (e.g. for storage
tanks) could be the limiting factors in implementation of this technique. These factors
could be acknowledged in the applicability of this technique or related techniques
(e.g. see applicability of new technique b1 on segregation of water streams, or
technique f).
The textile plants may be located within bigger industrial sites (with many plants)
where water management may be shared and carried out through a centralised utility,
affecting the plant’s reuse/recycling. The description could be amended to reflect this.
The examples of water reuse would prolong the description and add unnecessary
detail. They may be added to the technique description in Chapter 4.
Technique i
The issue of impurity content is already mentioned in the description as it is an
important part of the use of this technique. The perishability of the process liquor
could also be mentioned as an influencing factor (as in BAT 28c).
BAT statement
To change the BAT statement to require the use of techniques (a), (b) and (b1) and an
appropriate combination of the rest of the techniques to reflect the applicability
restrictions of several techniques.
Technique a
The water audits are added to description of the technique to mirror the applicability.
To add the integrated water management of plants on large sites to the description.
EIPPCB
Technique b1
proposal:
Add technique on the segregation of the water streams to promote their
reuse/recycling.
Technique c
Modify the name and description to reflect that some processes use no and other little
water
Technique d
To change the applicability of the technique to “only applicable to new plants or
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
53
Background paper – Final meeting for the review of the TXT BREF
major plant upgrades”.
Technique e
To add examples for rotary printing (i.e. mechanical pre-cleaning of squeegees and
rotary screen and of drums containing printing pastes) and a cross reference to
BAT 43.
To add the accessibility of equipment as an applicability restriction for water-free
cleaning.
Technique f
To change the applicability of the technique to reflect lack of space as a limiting
factor for existing plants.
Technique h
To reflect in the description that textile plants on the same site can have common
water management (reuse/recycling/waste water treatment).
To move high degree of reuse and/or recycling (>80%) to the description.
To change the applicability to refer to the content of impurities and/or characteristics
of the water streams.
Technique i
To add in the description the perishability as an influencing factor for reuse of the
process liquor.
BAT 35a
In the description of technique a, add ‘washing’ to the treatments listed in brackets.
1.4.3.2
BAT-AEPLs for specific water consumption
Location in
P. 727 – Section 5.1.3 – BAT 9 – Table 5.1
D1:
Table 5.1: BAT-associated environmental performance levels (BAT-AEPLs) for
specific water consumption
BAT-AEPL
Specific process(es)
(Yearly average)
(m3/t)
Batch
3–48 (2)
Bleaching (1)
Continuous
3–8
Scouring of cellulosic
Batch
2–43 (3)
materials (1)
Continuous
2–20
Desizing of cellulosic materials (1)
2–20
Mercerisation
2–13 (4)
Washing of synthetic material
5–20
Fabric
10–175 (5)
Batch dyeing
Yarn
3–140 (6)
Current
Loose fibre
13–62
text in D1:
Continuous dyeing
2–16
(1) The BAT-AEPL for the combined pre-treatment of cotton textiles by bleaching, scouring and
desizing is 9–20 m3/t. The lower end of the range is typically achieved for continuous
treatment.
(2) The lower end of the range is typically achieved with a high level of water recycling (e.g.
above XX).
(3) The lower end of the range is typically achieved with a high level of water recycling (e.g.
above XX).
(4) The lower end of the range is typically achieved with a high level of water recycling (e.g.
above 85 %).
(5) The lower end of the range is typically achieved with a high level of water recycling (e.g.
above 85 %).
(6) The lower end of the range is typically achieved with a high level of water recycling (e.g.
above 95 %).
The associated monitoring is given in BAT 5.
Summary
Whole table
54
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
of
Develop a new table with different ranges for processes depending on parameters like
comments:
product quality, textile substrate etc. in a sub-working group with several sector
experts. The process-specific consumption of water depends mostly on the product
type (e.g. some products need 3-4 process baths, others 15), material (cotton vs. PES),
fabric weight (40-3500 g/m², lightweight curtains or nightdresses vs. heavy
nonwovens for sound protection or in buildings) or purpose (highly cleaned medical
or food contact textiles vs. textiles for dike stabilisation). The current presentation of
BAT-AEPLs is not useful, non-transparent and misleading. If appropriate and
transparent levels for water consumption could not be achieved, delete Table 5.1
(DE 356).
Replace the BAT-AEPLs by indicative values due to the high diversity in product
specification in the textile industry (DE 356, EURATEX 155).
Set BAT-AEPLs in minimum recycling rates for specific processes because it would
be more relevant to better environmental performance than specific water
consumption ranges. Based on the analysis of the recycling levels/rates and
identification of BAT to recycle water in different processes: i) narrow down the
BAT-AEPL ranges and ii) set BAT on recycling levels/rates (EEB 186).
Increase the upper end of the BAT-AEPL range for specific water consumption levels
of batch dyeing, i.e. for fabric to 250 m3/t, yarn to 200 m3/t and loose fibre to
100 m3/t; due to the following factors: i) type of dye used (i.e. dyeing with reactive
dyes) can affect the total required rinsing steps (e.g. up to six); and similarly ii) the
higher quality of textile products manufactured. See the Italian questionnaires IT067,
IT082, IT096, IT097 (IT 14).
Narrow down the BAT-AEPL ranges as much as possible. For example, the ranges
for batch bleaching (3-48 m3/t), scouring (2-43 m3/t) and dyeing of fabric (10-
175 m3/t) yarn (3-140 m3/t) are very large and do not seem to be based on
comparable data sets. One way of amending this would be to remove from the
analysis the data sets for specific water consumption at process level where the
figures are the same as for total water consumption at the plant level (and more than
one process is in use on site). Examples are data sets from UK123 and UK124 where
it was found that the data for both are the same because there is no submetering on
site and the operator submitted data for both based on one total water consumption
figure (UK 17).
Footnote (1)
Change the upper limit for combined processes in Footnote (1) to 45 m3/t because it is
not logical compared to values of individual processes (EURATEX 95).
Whole table
The BAT-AEPLs are derived from the process-level consumption data collected via
the questionnaires. Due to KoM decisions, these data were considered confidential,
meaning that only the EIPPCB could see the related contextual information (e.g. main
plant’s products, fibre treated, form of textile material, etc.).
The BAT-AEPL proposals in D1 are based on comparable processes. Further
detailing and classification based on type of product or treated textile material was
attempted. However, due to the high variability in processes, textile materials and
forms, layouts/configurations of plants, affecting the reliability of data reported, it is
deemed most practical to propose indicative values instead of BAT-AEPLs.
The proportions of recycled/reused water from the data collection exercise were
EIPPCB
presented in figures and tables together with water consumption levels at plant and
assessment:
process level in Section 3.6.3 of D1. This information is considered when evaluating
data sets to be considered for setting the BAT-AEPLs; however, there is not enough
comparable data, due to various different local and technical circumstances, to
propose BAT-AEPL recycling levels at the plant or process level.
Based on the data reported in the questionnaires for Plants IT067, IT082, IT096,
IT097, it was established that IT082 does batch dyeing of fabric, IT082 and IT097 do
batch dyeing of yarn, and they all do batch dyeing of loose wool fibre. The specific
water consumption of these plants is typically within the proposed range, except for
one of them, which exceeds the proposed upper ends of the corresponding BAT-
AEPL levels. Therefore, only one IT plant could be considered for increasing the
proposed BAT-AEPL range for batch dyeing of loose fibres or yarns.
Regarding the argument on dyeing with reactive dyes (requiring more rinsing steps),
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
55
Background paper – Final meeting for the review of the TXT BREF
there are five plants, dyeing loose wool fibres or yarns with reactive dyes apart from
the one IT plant mentioned, reporting water consumption below the upper end of the
BAT-AEPL for batch dyeing of loose fibres or yarns. The information on the higher
quality of textile products manufactured was not collected through the questionnaires,
and, apart from the IT plants mentioned in the comments, it was not possible for the
EIPPCB to identify other such plants. Therefore, the data and information available
do not support increasing the upper ends of BAT-AEPL range for batch dyeing of
loose fibres or yarns.
The data sets where the water consumption at the plant level exceeded the sum of the
consumption reported at the process level were indeed excluded from the data sets
used for setting the BAT-AEPL ranges.
Footnote (1)
The BAT-AEPL range for combined (one-step) processes is derived based on the
values reported in the questionnaires. It was derived as the sums of the values
reported for the individual processes in those plants that indicated using the technique
of combined (one-step) pretreatment. The lower/upper ends of the water consumption
levels for individual continuous processes are based on all plants, those that use one-
step pretreatment and those that do not. Therefore, addition of the values of
lower/upper ends does not give the performances achievable with the technique
mentioned.
To propose indicative values instead of BAT-AEPLs.
EIPPCB
To adapt ranges based on the new assessment considering TWG comments,
proposal:
additional explanations and information provided.
1.4.4
Energy efficiency
Location in
P. 729 – Section 5.1.4
D1:
Current
Entire Section 5.1.4.
text in D1:
Change the applicability in the BAT conclusions of this section to "only applicable to
Summary
new plants or major plant upgrades and if economically feasible" because the
of
statements of BAT 10 to 12 say 'use all of the techniques' and not all techniques are
comments:
always and in every case applicable, or feasible (e.g. cogeneration is only useful when
there a constant and sufficient demand of heat) (CEFIC 30).
The selection and implementation of some of the techniques in BAT 10, BAT 11 and
BAT 12 may be restricted by the substrate type, product quality requirements, type of
EIPPCB
processes (e.g. batch/continuous), thermal equipment (dryers, stenters), off-gas
assessment:
treatment systems are their mutual compatibility. This could be reflected in the BAT
statements of the conclusions in this section.
EIPPCB
To change the wording of the BAT statements in this section (5.1.4) to reflect that a
proposal:
combination of techniques is considered BAT.
1.4.4.1
Techniques for using energy efficiently
Location in
P. 729 – Section 5.1.4 – BAT 10
D1:
BAT 10. In order to use energy efficiently, BAT is to use all of the techniques given
below.
Current
text in D1:
Technique
Description
Applicability
Management techniques
56
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
An energy efficiency plan is part of the
EMS (see BAT 1) and includes:
energy flow diagrams as part of the
inventory of inputs and outputs (see The level of detail
BAT 2);
of
the
energy
Energy
setting objectives in terms of energy efficiency
plan
efficiency plan
will generally be
a.
efficiency
(e.g. MWh/t
of
textile
and
energy
materials processed);
related
to
the
audits
nature, scale and
implementing actions to achieve these complexity of the
objectives.
plant
Energy audits are carried out at least
annually to ensure that the objectives of
energy efficiency plan are met.
Optimised scheduling of fabric batches to
Production
Generally
b.
undergo thermal treatment in order to
optimisation
applicable
minimise the idling time of the equipment.
Common techniques
This includes:
burner maintenance and control;
cogeneration;
energy-efficient motors;
energy-efficient lighting;
optimising steam distribution systems,
e.g. by using point-of-use boilers;
regular inspection and maintenance of
the steam distribution systems to
prevent or reduce steam leaks;
Use of common
Generally
c.
process control systems;
techniques
applicable
reducing heat losses by insulating
equipment components and by covering
tanks or bowls containing warm
process liquor;
optimising the temperature of the
rinsing water;
avoiding overheating of the process
liquors;
variable speed drives;
optimising air conditioning and
building heating.
Heat recovery techniques
Recycling
of See BAT 9 h. This avoids the need for
d.
warm
cooling heating cold water.
water
Reuse of warm See BAT 9 i. This avoids the need for
e.
process liquor
heating cold process liquor.
Heat
recovery Heat from waste water is recovered by heat
f. fr om
waste exchangers, e.g. to warm up process liquor.
water
Generally
Reuse
and/or Warm cooling air (e.g. from air-cooled air applicable
g. r
ecycling
of compressors) is reused and/or recycled (e.g.
warm air
for drying, after dedusting if needed).
Heat from waste gases (e.g. from thermal
Heat
recovery treatment of textile materials, steam boilers)
h. fr om
waste is recovered by heat exchangers and used
gases
(e.g. to warm up process water or to preheat
combustion air).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
57
Background paper – Final meeting for the review of the TXT BREF
Heat
recovery Heat, e.g. from hot condensate and boiler
i.
from steam use
blowdown, is recovered.
Management techniques
Technique a.
Make BAT 10a a "stand-alone-BAT". An energy management plan is indeed a
prerequisite for all techniques for the reduction of energy consumption and should be
implemented in all installations (DE 357).
Replace "energy audits" with "monitoring" because an energy efficiency plan is based
on an energy audit, which is performed periodically (e.g. every 4 years). The follow-
up of the energy plan is done via monitoring (EURATEX 96, CEFIC 29).
Add the following footnote in the table: “EN ISO 50001:2018 is an example of a
management system compliant with BAT 10a” for easier implementation
(ES 37).
Include the possibility to carry out periodic energy audits in longer periods (for
instance every 6 years), as long as the measures are controlled annually (PT 13).
Amend the applicability to provide for a lesser frequency of auditing at smaller
single-process sites and that demonstration of compliance with the technique may be
obtained by providing the audit findings and summaries from other similar energy
efficiency schemes such as ISO 50001 (UK 18).
Common techniques
Technique c.
Change the applicability for cogeneration which is applicable for all new plants and
for major refurbishments of existing plants where it may additionally be limited due
to the layout and available space (ES 18).
Replace "This includes" with "This includes techniques such as" because
cogeneration is not generally applicable (FR_A 45).
Summary
of
Cogeneration is not applicable in every situation. Therefore, either delete
cogeneration from the list of techniques, or move it to “Heat recovery techniques” to
comments:
be applicable in combination with other techniques listed there, or change the
applicability for cogeneration to “Applicable for major plant upgrades”
(EURATEX 8).
Replace the applicability with "only applicable to new plants or major plant upgrades
and if economically feasible". The applicability is also related to the economic
feasibility and specific on-site situation (e.g. constant and sufficient heat demand for
cogeneration, similarly for energy-efficient motors, energy-efficient lighting and
variable-speed drives) (EURATEX 97).
Heat recovery techniques
The techniques listed cannot be used simultaneously in the same equipment, or they
require additional area (layout restrictions), or there is no process in which the warm
liquor could be reused. Therefore, either change the statement to “use one or a
combination of the listed techniques” (EURATEX 9) or change the applicability
restriction for heat recovery techniques to “Only applicable to new plants or major
plant upgrades” (IT 16, EURATEX 9).
Techniques f. and h.
Change the applicability of the techniques to: "Only applicable to new plants or major
plant upgrades" because the implementation of these techniques is closely linked to
the configuration of the installation (spatial layout) and sufficient high thermal energy
level suitable for recovery (operational conditions) (FR_A 46, IT 17, EURATEX 98,
EURATEX 99). Economic feasibility should also be reflected in applicability
(EURATEX 98, EURATEX 99).
BAT statement
Several of the techniques listed are not generally applicable and consideration of the
applicability restrictions could be better reflected in the statement. Furthermore,
EIPPCB
technique (a) as a management tool would have a merit in all cases where energy is
assessment:
consumed.
Management techniques
Technique a.
58
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Technique a. is a management tool and would have merit in all processes where
energy is consumed. A total of 45 plants from the data collection apply an energy-
saving plan (Section 4.1.4.1 of D1). According to the data collection on BAT used at
the plant level, ‘Management’ is used by 66 out of 106 plants, which is much more
than is reported for other techniques, like ‘Minimising the energy consumption of
stenters’ (30) or ‘Combined Heat and Power’ (9 plants). This seems to support the
argument on generic use of technique a. and only a combination of other techniques.
Technique a. could be a stand-alone conclusion. However, embedding it in the same
conclusion might strengthen the link betweena customised energy efficiency plan
and audits on one side, and selection and implementation of the appropriate other
techniques listed in the same conclusion on the other side. Finally, this structure (i.e.
management technique embedded with other techniques) has already been used in
BAT conclusions (e.g. STS).
Energy efficiency plans and regular energy audits are important tools to tap the
energy-savings potential of textile installations. Relevant European or International
Standards, such as EN ISO 50001 (Energy Management Systems), ISO 50002:2014
(Energy audits — Requirements with guidance for use) or the EN 16247 series
(Energy Audits: e.g. Part 1 and Part 3), can be considered when establishing an
energy efficiency plan and audits as part of an environmental management system
(e.g. certified according to EMAS or ISO 14000). Apart from the note in BAT 1, no
additional footnotes on implementation of management systems are deemed
necessary.
Monitoring is usually considered as checking the change (e.g. measuring, calculating)
of a variable over time so that a certain set threshold value is not exceeded. Auditing
is considered a more comprehensive and structured analysis of different variables,
measures and processes with the aim of acquiring the comprehensive knowledge of
different aspects of a plant’s operation, to discover the improvement potential and
report on it.
The energy audits in the scope of these BAT conclusions can be internal or external,
and it is left to the implementation stage to decide if the energy audits resulting from
other regulatory requirements or conducted as part of requirements of the certified
energy management systems are considered an appropriate demonstration of
compliance. However, it could be reflected in the applicability that the level of detail
of the energy audits will generally be related to the nature, scale and complexity of
the plant.
The consumption of energy in textile plants is substantial. The monitoring of energy
consumption is important information, which is checked as part of the energy audit,
whose findings are used for verifying that the objectives of the energy efficiency plan
are met. The yearly frequency of energy audits is harmonised with the one used in
other BAT conclusions (e.g. FMP). According to EMAS Regulation (EC) No
1221/2009, Annex III, Part A, point 4, for complex activities (the IED activities could
be considered as such) the audit frequency should be yearly. Finally, according to
ISO 19011 or the EMAS Regulation (e.g. Article 9), internal or external audits are
possible. Since the level of detail of energy audits can be relatively simple in textile
plants, it is not clear why the frequency of energy audits would need to be less
frequent.
46 out of 106 plants reported using Energy saving plan within their management
system, 14 reported having established certified energy management system
according to ISO 50001.
Technique b.
Production optimisation is management technique that could be used generally like
technique a. This could be reflected in BAT statement.
Common techniques
.Technique c.
Implementation of cogeneration would require investment (e.g. CAPEX) in technical
infrastructure (e.g. adaptation of piping and installation of new equipment (e.g. gas
turbine)) and substantial operating costs (e.g. OPEX). Both could be justified if there
is sufficient heat demand, making it economically feasible. This could be specified in
the applicability.
Concerning the applicability of other techniques such as energy-efficient motors,
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
59
link to page 60
Background paper – Final meeting for the review of the TXT BREF
energy-efficient lighting or variable-speed drives, these pieces of equipment can be
installed during regular maintenance activities when the existing ones need to be
replaced and it is not clear why the applicability may be restricted to new plants or
major plant upgrades.
The name of the technique could be made more technically relevant by referring to
energy-saving.
Technique c1.
There is a merit to join bullets related to heating demand in a dedicated technique.
Especially insulation of equipment, optimising the temperature of rinsing water and
avoiding overheating process liquors.
Heat recovery techniques
The techniques listed in this conclusion cover the whole plant and not just one piece
of equipment/process. Therefore, in plants with multiple processes or equipment, it
would be possible to implement all of the techniques in the same plant. However, the
BAT statement gives flexibility to implement the combination of techniques which
would make it possible to implement some of them despite spatial (layout)
restrictions or a lack of processes with heat demands.
Techniques f. and h.
According to the data collection, heat recovery from waste water and waste gases is
relatively widely used in the sector (see Section 3.6.3 of D1, Figures 3.79 and 3.71).
Specifically, 40 plants reported recovering heat from waste water, 27 from process
waters, and 25 from waste gases. This indicates that these techniques are widely
implemented in the sector. The layout of the plant and the heat demand affect the heat
recovery, but many of the heat recovery loops could be implemented without a major
plant upgrade. Moreover, the BAT statement gives flexibility to implement the
combination of techniques, which would make it possible to implement some of them
despite spatial (layout) restrictions and/or the lack of processes with heat demands.
Technique g.
Technique g. would be better placed in BAT 11 which addresses specific issues
related to the energy efficiency of air compressors.
Technique b1.
For the assessment, see Section
1.4.4.2.
BAT statement
To change the wording “to use all of the techniques” in the BAT statement to require
the use of techniques a. and b. and appropriate combination of the rest of the
techniques to reflect the applicability restrictions of several techniques.
Technique a.
To add the applicability restrictions regarding the level of detail of energy audits.
Technique b1.
To be moved from BAT 12 a.
EIPPCB
Technique c.
proposal:
To reflect in the applicability that cogeneration in existing plants may be restricted by
a suitable heat demand.
To amend the name of technique to reflect the energy saving objective.
Technique c1.
To make new technique on heating demand from some of the examples in technique
c.
Technique g.
To delete in the technique from this BAT conclusion and to move it to BAT 11d.
1.4.4.2
Techniques for increasing energy efficiency of thermal treatment
Location in
P. 731 – Section 5.1.4 – BAT 12
60
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
D1:
BAT 12. In order to increase the energy efficiency of thermal treatment, BAT is to
use all of the techniques given below.
Technique
Description
Applicability
Techniques for reducing the use of heating
Wet-on-wet
Dyeing or finishing liquors are applied
dyeing
or
a.
directly to the wet fabric, thus avoiding an
finishing
of intermediate drying step.
fabric
The water content of textile materials is
Mechanical
Generally
reduced by mechanical techniques (e.g.
b. d ewatering
of
applicable
centrifugal extraction, squeezing and/or
textile materials
vacuum extraction).
Avoiding
The textile materials are not dried below
c. o verdrying
of their natural moisture level.
textile materials
Design and operation techniques
This includes:
the number of air injection nozzles is
adapted to the width of the fabric;
Only applicable to
Optimising air
the distance between the nozzles and new plants or
d.
circulation
in
the fabric is as short as possible;
major
plant
stenters
the pressure drop caused by the upgrades
Current
stentersʼ internal components is as
text in D1:
small as possible.
The following drying parameters are
monitored and controlled (see BAT 3):
humidity content and temperature of
the inlet air;
temperature of textile materials and air
Advanced
within the dryer;
process
Generally
e.
monitoring and
humidity content and temperature of
applicable
control
of
the exhaust air; drying efficiency is
drying
optimised by a high humidity content
(e.g. above 0.1 kg water/kg dry air);
residual moisture content of the fabric.
The exhaust airflow is adjusted to optimise
drying efficiency and is reduced during
idling time of drying equipment.
Only applicable to
Microwave
or Drying of textile materials with high-
new
plants
or
f. r
adio-frequency
efficiency microwave or radio frequency major
plant
dryers
dryers.
upgrades
Heat recovery techniques
Heat
recovery
Generally
g. fr om
waste See BAT 10 h.
applicable
gases
Whole BAT
Clarify the scope of the BAT and possibly split the techniques between several types
of thermal treatments. For example, it is not clear why the techniques listed are
specific only to the thermal treatment. Some techniques could be implemented even if
Summary
there is no thermal treatment. It is also not clear what thermal treatments it covers
of
(FR_B 3).
comments:
BAT statement
Change the statement to: “BAT is to use one or more of the techniques given below”,
because all of the listed techniques cannot be used simultaneously (EURATEX 10).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
61
Background paper – Final meeting for the review of the TXT BREF
Techniques for reducing the use of heating
Technique a.
Change the applicability to: "Not applicable to continuous processes or when the pre-
treated fabric need to be stored before being dyed or finished because of operational
constraints." Production scheduling (especially in commission firms) and operational
restrictions may demand different sequencing and hence intermediate drying to avoid
moulds. Moreover, continuous dyeing/finishing on wet fabric may require higher
chemicals consumption (dosing) to ensure a homogeneous treatment and the required
product specifications (e.g. up to 3 times higher use of optical brighteners, softeners
or water-repellent resins) (CZ_B 5, CZ_A 9, CZ_A 12, FR_A 47, EURATEX 10).
Add that the applicability may be restricted by potential reactions between unfixed
chemicals on the wet fabric (EURATEX 113).
Technique b.
Add that the applicability of mechanical drying may be restricted by the textile
characteristics (i.e. it can withstand it) (EURATEX 113).
Modify the applicability to: “The applicability may be restricted by the characteristics
of the textile materials and/or product specifications.” (IT 19).
Design and operation techniques
Technique e.
Not all parameters need to be monitored, so add “such as” after “(See BAT 3)”
(FR_A 48).
The residual moisture of the fabric is more often monitored compared to the other
parameters listed. Moreover, a high humidity content in the exhaust air can lead to
deposits within the stack and the risk of fire and in addition it may result in
condensation that causes spots on the fabric (FR_A 48).
Change technique e. as follows: delete the first bullet point and change the third bullet
point to "humidity content and temperature of the exhaust air; drying efficiency is
optimised". Also, change the applicability to “only applicable to new plants or major
plant upgrades” (EURATEX 10).
Add that the applicability of input temperature and humidity control may be restricted
by other parameters. For example, high exit air humidity is only possible if other
parameters allow (EURATEX 113).
Technique f.
Modify the applicability as it may be restricted by product specifications, e.g. textiles
containing metallic fibres (especially in ATEX/explosive areas) (ES 16,
EURATEX 12) or change it to “only applicable to new plants or major upgrades”
(EURATEX 12).
Delete the technique as it is an emerging technique and not BAT, or change the
applicability to "not applicable to fabric containing metallic fibres." Also, there are no
example plants which apply this technique mentioned in the BREF and no data in the
questionnaires (FR_A 49).
Heat recovery techniques
Technique g.
Change the applicability to reflect that the technique is generally applicable to new
plants and major upgrades of plants because, depending on the configuration of
existing plants, it may not be easy to install, and that it depends on heat needs and the
calorific value of the off-gases (FR_A 62).
Whole BAT
The scope of the technique is energy efficiency of thermal treatment. Splitting the
techniques according to the type of thermal treatment could prove repetitive and
complex. The generic table seems a very clear and understandable way of presenting
EIPPCB
the techniques.
assessment:
A definition of thermal treatment is given in the Definitions.
Technique b. “Mechanical dewatering of textile materials” is not specific only to
energy efficiency of thermal treatment but also to other environmental objectives, i.e.
water consumption/waste water generation (see BAT 9g and BAT 9i). It is not clear
62
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 56
Background paper – Final meeting for the review of the TXT BREF
how other techniques in this conclusion could be implemented if no thermal treatment
was carried out in the plant.
BAT statement
The techniques of this BAT conclusion cover the whole plant and not just one piece
of equipment/process. Therefore, in plants with multiple processes or pieces of
equipment, it would be possible to implement all of the techniques in the same plant.
However, in line with the general approach adopted for BAT conclusions in this
section (see Section
1.4.4 of this document), the BAT statement could reflect that a
combination of techniques could be implemented to achieve its objective.
Techniques for reducing the use of heating
Technique a.
Technique a. does not increase the energy efficiency of thermal treatment, but reduces
the need for a thermal treatment step, and thereby increases the energy efficiency of
the plant. Therefore, it would be more appropriate to include it in BAT 10 on general
(plant-level) energy efficiency techniques.
It is not clear why wet-on-wet dyeing is not applicable to continuous processes since
it can be carried out on continuous ranges with the padding machines (e.g. Foulard) in
various combinations (e.g. pad-pad-steam), but also with spray and foam application.
It is suitable for fabrics which have the ability to retain substantial amounts of liquids
(e.g. terry cloth, corduroy), e.g. with density typically above 140 g/m2.
Production scheduling in relation to energy efficiency is addressed by technique
BAT 10b. It does not seem to limit or contradict the implementation of wet-on-wet
dyeing or finishing.
The note on the potential higher finishing agent consumption (up to three times more)
to ensure product quality could be added in Chapter 4, but there was no specific
information on which finishing processes (agents) this refers to.
No specific information on potential reactions between unfixed chemicals and textiles
was provided (e.g. for which type of dyes or which fibre combinations).
Technique b.
No information on potential restrictions related to mechanical drying and the textile
properties (e.g. withstanding mechanical pressure from harming the substrate) was
provided.
Design and operation techniques
Technique e.
The drying parameters described are indicative. This could be reflected in the
description.
It is not clear why this technique is only applicable to new plants and major upgrades.
It is not clear which other parameters would limit the high humidity content of
exhaust air exiting the dryer.
Technique f.
Microwave or radio-frequency drying of textile materials with metallic fibres or other
metallic parts (e.g. buttons) may not be possible. This could be mentioned as a
technical applicability restriction of this technique.
High-frequency drying has been reported to be used by Plants BE010, IT082 and
PT105 and is largely described in the existing TXT BREF as an applied process. See
also the site visit reports dated 05/03/2019 and 11/04/2019.
Heat recovery techniques
Technique g.
It is not clear how installation difficulties or the calorific value of the waste gases
would change with a major plant upgrade. It is hard to imagine a lack of heat
demands in the textile sector, where a lot of processes require heat. Moreover, the
BAT statement gives flexibility to use a combination of techniques to achieve the
objective of heat efficiency in thermal treatment, so indeed satisfactory energy
efficiency may be achieved without implementing this technique.
EIPPCB
BAT statement
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
63
Background paper – Final meeting for the review of the TXT BREF
proposal:
To rephrase the statement to “use a combination of the techniques”.
Technique a.
To move the technique to BAT 10 on energy efficiency.
Technique e.
To modify the introductory sentence of the description to reflect the indicative nature
of the parameters listed.
Technique f.
To add the applicability restriction for textile materials containing metallic parts.
64
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.4.4.3
BAT-AEPLs for specific energy consumption
Location in
P. 727 – Section 5.1.3 – BAT 12 – Table 5.2
D1:
Table 5.2: BAT-associated environmental performance levels (BAT-AEPLs) for
specific energy consumption
Current
BAT-AEPL
text in D1:
Process
Unit
(Yearly average)
Thermal treatment
MWh/t
0.5–4.4
The associated monitoring is given in BAT 5.
Whole table
As for Table 5.1, develop a new table with different ranges for processes depending
on parameters like product quality, textile substrate etc. in a sub-working group with
several sector experts. The process-specific consumption of water depends mostly on
the product type (e.g. some products need 3-4 process baths, others 15), material
(cotton vs. PES), fabric weight (40-3500 g/m², lightweight curtains or nightdresses vs.
Summary
heavy nonwovens for sound protection or in buildings) or purpose (highly cleaned
of
medical or food contact textiles vs. textiles for dike stabilisation). The proposed range
comments:
is not useful to be used as a BAT-AEPL (DE 262).
Remove from the analysis the data sets for specific energy consumption at process
level where the figures are the same as for total energy consumption at the plant level
(and more than one process is in use on site). Examples are data sets from UK124
where due to lack of sub-metering the same figure was reported for both (UK 19).
Whole table
Because it was not clear whether the values reported for the wet processes include the
energy needed for drying or only the energy needed for heating liquors (water), the
specific energy consumption was proposed for thermal treatments only. Limiting the
water consumption of wet processes through indicative values for specific water
consumption would indirectly limit their energy consumption.
EIPPCB
Due to the high variability in processes, textile materials and forms,
assessment:
layouts/configurations of plants, affecting the reliability of data reported, and the
limited extent of TWG participation in the data analysis (e.g. due to the CBI nature of
data), it is deemed more practical to propose indicative values instead of BAT-
AEPLs.
The data sets where the energy consumption at the plant level exceeded the sum of
the consumption reported at the process level were indeed excluded from the data sets
used for setting the BAT-AEPL ranges
EIPPCB
To propose indicative values instead of BAT-AEPLs.
proposal:
1.4.5
Chemicals
1.4.5.1
Techniques for improving the overall environmental performance
Location in
P. 732 – Section 5.1.5 – BAT 13
D1:
BAT 13. In order to improve the overall environmental performance, BAT is to
elaborate and implement a chemicals management system (CMS) as part of the EMS
(see BAT 1) that incorporates all of the following features:
I. process chemicals procurement policy to select process chemicals and their suppliers
Current
with the aim to minimise the use of hazardous chemicals such as substances of very high
text in D1:
concern and to avoid the procurement of excess amount of process chemicals. In order to
reduce emissions to air, the selection of process chemicals may be based on emission
factors (see Section 5.9.1);
II. anticipatory monitoring of regulatory changes related to hazardous chemicals and
safeguarding compliance with applicable legal requirements;
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
65
Background paper – Final meeting for the review of the TXT BREF
chemicals inventory (see BAT 14);
III. identification of the process chemicals pathways through the plant (from procured
process chemicals to products, waste and emissions);
IV. assessment of the risks associated to the chemicals, based on the chemicals’ hazards,
concentrations and amounts. This may include an estimation of their emissions to the
environment;
V. regular (e.g. annual) check aiming at identifying potentially new available and safer
alternatives to the use of hazardous chemicals (e.g. changes of process(es) or use of other
chemicals with no or lower environmental impacts such as enzymes);
VI. goals and action plans to avoid or reduce the use of hazardous chemicals;
VII. development and implementation of procedures for the handling, storage, use and
return of process chemicals (see BAT 20).
The criteria for selecting process chemicals and their suppliers may be based on
certification schemes or standards. In that case, the compliance of the process chemicals
and their suppliers with these schemes or standards is regularly verified.
Applicability
The level of detail of the CMS will generally be related to the nature, scale and
complexity of the plant.
Point I
Replace “the use of hazardous chemicals” with “the emissions of hazardous
chemicals” as the amount of hazardous chemicals used depends on the plant
throughput (CEFIC 5).
Clarify what is meant by "substances of very high concern" and if relevant make a
reference to the candidate list of REACH (FR_A 6).
Replace "such as substances of very high concern" with "in the meaning of IED
Article 3(18)” as SVHC are only a small fraction of the hazardous substances
(EEB 86).
Delete the reference to “substances of very high concern” as it is already regulated by
REACH (CEFIC 6).
Point II
Put the chemical inventory in a separate bullet point, maybe the first one as it is the
starting point for the management of chemicals (FR_A 10).
Point IV
Merge Points IV and VII as the risks associated with chemicals are the basis to
identify risk management measures (FR_A 8).
Summary
Replace the word “risk” with “hazard x exposure” to ensure coherence with the
of
REACH and CLP Regulations. How to perform a risk assessment for chemicals is
comments:
described in the ECHA Guidance on Information Requirements and Chemical Safety
Assessment (CEFIC 7).
Point V
Specify that “hazardous chemicals” are “chemicals which are restricted by EU or
international regulations (e.g. CMR substances in CLP-Regulation, SVHC in article
57a-f of the REACH Regulation, POPs listed in the Stockholm Convention)”
(AT 43).
Remove the mention of “safer chemicals” and refer instead to alternative processes
and chemicals with no or lower environmental impacts, which is the final aim
(CEFIC 8).
Delete the reference to enzymes as the impact on the environment is also a question
of emission, exposure and concentration and not only a property of a substance
(CEFIC 9).
Point VI
Delete Point VI as it is redundant with Point I (FR_A 7).
Replace “avoid or reduce the use of hazardous chemicals” with “avoid or reduce the
emissions of hazardous chemicals”, which is the real target (CEFIC 10).
66
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Point VII
Add procedures to collect spent bath and pastes for reuse or disposal as waste, as they
contain high concentrations of chemicals (SE 13).
Clarify the return of chemicals as follows: “return of unused process chemicals to
suppliers” (FR_A 9).
Criteria for selecting process chemicals and their suppliers
Add examples of certification schemes or standards (e.g. ECO PASSPORT by
OEKO-TEX®, STeP by OEKO-TEX®, DETOX TO ZERO by OEKO-TEX®)
(ES 14, EURATEX 101).
Add that the selection of chemicals may be done via “positive” lists of chemicals (i.e.
list of preferred chemicals that are assessed/screened and validated by neutral third
parties for their toxicological and ecological profile) (DE 215).
General comment
Restructure the BAT according to the following order of priority:
o management techniques to avoid or (if not possible) minimise the use of
hazardous chemicals (like SVHC);
o techniques for selection of chemicals with the aim to reduce emissions (including
anticipatory survey of alternatives for used substances);
o identification of emission pathways of substances used;
o techniques for handling, storage.
The proposed wording is the following: (DE 358)
BAT 13. In order to improve the overall environmental performance, BAT is to elaborate
and implement a chemicals management system (CMS) that incorporates the following
features:
I.
process chemicals procurement policy to select process chemicals and their
suppliers with the aim to minimise the use of hazardous chemicals such as
substances of very high concern as described in Article 57 REACH as substances
with CMR-properties (Category 1A and 1B), PBT or vPvB substances, or
substances with an equivalent level of concern, such as endocrine disrupting
chemicals;
II.
goals and action plans to avoid or reduce the use of hazardous chemicals and
substances that may pass existing barriers in concentrations that may raise
concern;
III.
Selection of recipes for textile finishing based on the application of the emission
factor concept (see Section 5.9.1) as a tool that allows for assessing and
predicting air emission released from chemical auxiliaries, e.g. during thermal
treatment.
IV.
Selection of process chemicals considering their eliminability to minimize the
release into water as well as their effect to the aquatic compartment (eco-
toxicity).
V.
anticipatory monitoring of regulatory changes related to hazardous chemicals
and safeguarding compliance with applicable legal requirements;
VI.
regular survey whether new and safer alternatives to the use of hazardous
chemicals are available
VII.
identification of the process chemicals pathways through the plant (from
procured process chemicals to products, waste and emissions)
VIII.
assessment of the risks associated to the chemicals based on the chemicals’
hazards, concentrations and amounts. This should include an estimation of their
emissions to the environment;
IX.
development and implementation of procedures for the handling, storage, use
and return of process chemicals.
Point I
Point I is about the procurement policy, which can contribute to the reduction of
emissions of hazardous chemicals by minimising the procurement and therefore the
EIPPCB
use of hazardous chemicals. This does not contradict the fact that the amount of
assessment:
chemicals used also depends on the plant throughput.
The criteria for determining BAT do not concern only emissions to the environment.
The reduced use of hazardous chemicals also addresses the following aspects, which
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
67
Background paper – Final meeting for the review of the TXT BREF
are listed in Annex III to the IED as criteria for determining BAT:
o the use of less hazardous substances;
o the consumption of raw materials used in the process.
It would therefore be limiting to mention only the reduction of emissions as the
objective of point I.
The term “hazardous chemicals” may be unnecessary as it is the term “hazardous
substances” which is defined in Article 3(18) of the IED (which refers to Article 3 of
the CLP Regulation) and mentioned in Annex III to the IED.
The term “substances of very high concern” would need a definition in Definitions.
Point II
The chemical inventory not being in a separate point is due to a formatting issue.
It is not necessarily the first point of the CMS as a management system would
normally start by setting an overall objective and an associated action plan.
BAT 14 is dedicated to the chemical inventory, but its role in the CMS could be
specified.
Point IV
Procedures mentioned in point VII of the CMS consider the risks associated with the
chemicals and identified in point IV but not exclusively. It can also consider for
example the shelf life of the chemicals or the return of unused chemicals. It seems
therefore clearer to have two separate points. This being said, the connection between
both points could be clearer by having the point about risk assessment immediately
before the point about the development of procedures.
Article 14 of the REACH Regulation lays out the provisions for the realisation of the
chemical safety assessment. This safety assessment is based on the assessment of the
hazards induced by the substance or mixture concerned and, depending on the
outcomes of this assessment, is complemented by an exposure assessment and a risk
characterisation8. The risk characterisation in turn allows the identification of risk
reduction measures. A better alignment of the wording of point IV with the
terminology used in the REACH regulation would improve clarity.
Point V
The term “hazardous chemicals” is not defined in the IED or in other relevant
regulations (REACH or CLP). On the other hand, the term “hazardous substances” is
defined in the IED and the use of the same term in the BAT conclusions would ensure
consistency, clarity and avoid possible conflicts.
The word “safer” in the expression “safer alternative to hazardous chemicals” seems
redundant and it is not clear what it compares to.
The use of enzymes as substitutes for other chemicals is mentioned in a number of
other BAT (BAT 15, BAT 37, BAT 39 and BAT 48) and it is therefore not necessary
to repeat it here.
Point VI
Point VI is about goals and action plans to reduce the use of hazardous chemicals
whereas point I is specific to the procurement policy; these points are therefore not
equivalent. This being said, both points are indeed connected as point I would be one
way to reduce the use of hazardous substances (another way could be for example to
change processes or process liquor) and it would bring clarity to bring both points
together.
The aim of the CMS is to reduce the use of hazardous substances, which in turn
reduces the emissions of hazardous substances. The use of less hazardous substances
is one of the criteria listed in Annex III to the IED for determining BAT.
Point VII
The reuse of process liquor is already mentioned in BAT 15. The disposal of spent
process liquor chemicals as waste is covered by BAT 28 as is the disposal of any
8 Guidance on Information Requirements and Chemical Safety Assessment, Part D: Framework for exposure assessment, ECHA
2016
68
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
other waste. A cross-reference in BAT 28 could be helpful to highlight the
relationship between both BAT.
Concerning the return of process chemicals, this does indeed refer to the unused
process chemicals mentioned in BAT 20.
Criteria for selecting process chemicals and their suppliers
While examples of certification schemes and standards could helpfully complement
the description of BAT 13, it seems difficult to promote commercial tools in a legal
text such as BAT conclusions. However, such examples are given in Chapter 4 of D1.
A ‘positive list’ of chemicals is indeed a tool used by some certification bodies but it
does not seem necessary to detail those tools in the BAT conclusions. This being said,
Chapter 4 of D1 could usefully be complemented with this information.
General comment
Concerning the restructuration of the CMS, the proposed order brings improved logic
to the order of the CMS features as these features go from management techniques to
the selection of chemicals, identification of emission pathways of substances used and
finally techniques for handling and storage of chemicals. The setting of goals and
action plans to reduce the use of hazardous substances seems however to precede the
procurement policy, which is one action for achieving the objective.
Concerning the proposed BAT statement, the deletion of the words “all of” may
undermine the fact that all features are to be used and is not in line with the wording
of the EMS (BAT 1).
Concerning the proposed additional point about the emission factor concept, this
element is already mentioned in D1 as one possible selection criteria for process
chemicals which will have reduced emissions to air. Making a separate point for this
method could give the impression that only this method may be used.
Concerning the proposed additional point about the eliminability and ecotoxicity of
process chemicals, these are indeed important characteristics to consider for the
selection of chemicals and could be added in point I as examples of selection criteria
in addition to the emission factor concept for emissions to air. Making a separate
point for this could give the impression that only those characteristics are to be
considered.
Concerning the proposed wording of points I, V, VI, VIII and IX, see the assessment
of the corresponding points above.
To replace “hazardous chemicals” with “hazardous substances” throughout the
document and to add this term in Definitions.
To define the term “substances of very high concern” in Definitions and to use this
term throughout the document (e.g. in BAT 4 and BAT 13).
To restructure the bullet points indicating the main CMS elements (bullet points I, VII
and VIII) and the elements of the selection of process chemicals (bullet points II, III,
EIPPCB
IV and V).
proposal:
To complement the wording of points I, VI and VII.
To reformulate point IV and point V.
To add the reuse and recovery of chemicals to elements considered in selection of
chemicals.
To specify the role of the chemical inventory.
To complement Chapter 4 of D1 with information about positive lists of chemicals.
Location in
P. 732 – Section 5.1.5 – BAT 14
D1:
BAT 14. In order to improve the overall environmental performance, BAT is to
elaborate and implement a chemicals inventory and tracking system as part of the
CMS (see BAT 13).
Current
text in D1:
Description The chemicals inventory and tracking system is computer-based and contains information
about:
the identity of the process chemicals;
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
69
Background paper – Final meeting for the review of the TXT BREF
the quantities and location of the process chemicals procured, recovered (see
BAT 15 f), stored, used and returned to suppliers;
the characteristics of process chemicals including properties with adverse effects on
the environment and/or human health.
BAT statement
Delete “tracking system” as the meaning is unclear and replace it with “electronic
tool for the chemical inventory lists” (DE 185).
Delete “tracking system” as the meaning is unclear and replace it with “assess the
partitioning of process chemicals in the environmental compartments (air, water,
waste, product)” (DE 385).
Delete “ tracking system” as a chemical tracking system provides no improvement of
environmental performance. The chemical inventory and knowledge of chemicals that
Summary
are waste-water- or air-relevant is sufficient (EURATEX 114).
of
comments:
Description
Clarify the characteristics of the process chemicals by “the physical and chemical
data of process chemicals (e.g. solubility, vapour pressure, log Kow), data on
ecotoxicity, fate and behaviour in the environment (e.g. biodegradation,
adsorption/desorption coefficient, mobility) as well as adverse effects on human
health” (DE 385).
Mention that the main source of information for the process chemicals and their
characteristics is the Safety Data Sheet (SDS) (ES 15, FR_A 11, CEFIC 11,
EURATEX 102), in particular Section 2 and Section 9 of the SDS (CEFIC 11).
BAT statement
The wording “tracking system” refers to the locations and quantities of process
chemicals mentioned in the second bullet point. As this wording seems unclear and is
in any case covered in a bullet point, it is not necessary.
The tracking of chemicals is more efficient when an electronic tool is used but the use
of a computer-based system is already mentioned in the BAT description and it does
not seem necessary to repeat it in the BAT statement.
The assessment of the fate of process chemicals in various environmental
compartments is based on the chemicals inventory but is not part of the inventory
EIPPCB
itself. This assessment is part of BAT 13.
assessment:
Description
According to D1, information mentioned in the first and third bullet points of the
BAT description is indeed to be found in the Safety Data Sheet (SDS) but also in the
Technical Instruction Sheets and it could be useful for the reader to add a reference to
these documents.
Concerning the proposed wording for the BAT description, some additional examples
of characteristics of the process chemicals could indeed bring further guidance to the
users of the BAT conclusions.
To remove “tracking system” from the BAT statement.
EIPPCB
To add a reference to SDS and to Technical Instruction Sheets in the BAT description
proposal:
as well as additional examples of characteristics of the process chemicals.
To add some examples of physico-chemical and environmental properties.
1.4.5.2
Techniques for reducing the consumption of chemicals
Location in
P. 733 – Section 5.1.5 – BAT 15
D1:
BAT 15. In order to reduce the consumption of chemicals, BAT is to use all of the
Current
techniques given below.
text in D1:
Technique
Description
Applicability
70
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
This includes:
regularly reviewing the formulation of
Reduction of the
process chemicals and liquors;
Generally
a. n
eed for process
using demineralised water in the applicable
chemicals
processes to reduce the need for
complexing agents;
production optimisation (see BAT 9 b).
The applicability
Enzymes are selected (see BAT 13) and may be restricted
Treatment
of used to catalyse the reactions with textile by
product
b.
textile materials materials to lower the consumption of specifications or
with enzymes
process chemicals (e.g. in desizing, the availability of
bleaching and/or washing).
suitable enzymes
Automatic
Automatic systems for weighing, dosing,
systems
for dissolving, measuring and dispensing
preparation and which ensures precise delivery of process
c. d osing
of chemicals and process liquors to the
process
production machines.
chemicals
and See BAT 3.
process liquors
Optimisation of
Generally
the quantity of
d.
See BAT 9 d.
applicable
process
chemicals used
Reuse
of
e.
See BAT 9 i.
process liquor
Recovery and
Residual process chemicals are recovered
use of leftover
(e.g. by thoroughly purging pipes or
f.
process
completely emptying packaging) and used
chemicals
in the process.
General comment about BAT 15
Delete BAT 15 as it is a repetition of BAT 3, BAT 9 and BAT 28 or it should be
contained in the Chemicals Management System (CMS) (DE 415).
BAT statement
Change the environmental objective of the BAT from the reduction of use of
hazardous chemicals to the reduction of emissions of hazardous chemicals as the
reduction of use does not have necessarily an environmental impact (CEFIC 12).
Technique a.
Change the name of technique a. to reduction of chemicals consumption per tonne of
textiles (CEFIC 12).
Delete technique a. because the first and third points are very generic and already
Summary
covered. Moreover, concerning the second point, demineralised water is not widely
of
used but instead softened water (FR_A 50).
comments:
Delete the second point as the use of demineralised water is not needed when the
incoming water is already very soft (IT 42).
Replace the use of demineralised water with the use of water softened with an ion
exchanger. Softened water is sufficient to reduce the need for complexing agents.
Demineralisation produces double the amount of waste baths from the regeneration of
the ion exchanger (DE 313, CZ_B 6, EURATEX 103).
Delete the reference to demineralised water as the washing capacity of demineralised
or softened water is worse than that of "hard" water due to lack of calcium and
manganese (EURATEX 156).
Change the applicability of technique a. to reflect that, depending on technical
feasibility and contamination of liquors, complexing agents might still be needed (i.e.
if the use of ion exchangers is not possible) (DE 313).
Technique b.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
71
link to page 65
Background paper – Final meeting for the review of the TXT BREF
Specify the applicability restriction related to the product specifications by referring
to Section 4.1.6.4 of D1 (EEB 107).
Technique c.
Change the applicability to standardised processes (e.g. pretreatment processes) in
new plants or major upgrades of plants because the technique is not feasible in
existing plants and it is not feasible for companies using hundreds of different liquors
(FR_A 51).
Change the applicability to new plants and major plant upgrades as the technique
implies a new piping system from the new preparation system to every machine that
uses the liquor (IT 20).
Change the applicability because the use of this technique may be restricted by the
size of the company or of the process (EURATEX 104).
Technique f.
Change the applicability because the recovery and use of leftover chemicals may be
restricted by the storage life and the presence of impurities (CEFIC 32,
EURATEX 105).
Add at the end of the description “whenever possible” as the collected chemicals may
need to be treated as waste (SE 23).
General comment about BAT 15
The objective of BAT 15 is to give in one place an overview of the techniques to
reduce the quantity of chemicals used. BAT 15 contains cross-references to other
BAT when these BAT have multiple benefits. For example, BAT 9b, BAT 9d and
BAT 9i allow the reduction of water consumption and waste water generation but
also the reduction of the consumption of chemicals.
Deleting BAT 15 would lead to a loss of information about the reduced use of
complexing agents and about the use of enzymes which is proposed to be removed
from BAT 13 (see Section
1.4.5.1 about BAT 13).
BAT statement
The criteria for determining BAT do not concern only emissions to the environment.
The reduced consumption of chemicals also addresses the following aspects, which
are listed in Annex III to the IED as criteria for determining BAT:
o the use of less hazardous substances;
o the consumption of raw materials used in the process.
It would therefore be limiting to change the environmental objective of the BAT to
the reduction of emissions only.
Technique a.
EIPPCB
Technique a. aims to reduce the need for process chemicals, which in turn will reduce
assessment:
the consumption of chemicals, be it specific consumption or overall consumption. A
reference to specific consumption does not seem necessary.
It could be clarified that not only is it necessary to review the formulation of process
chemicals and liquors, but also to optimise the formulation of process chemicals and
liquors.
BAT 15 is structured in such a way that technique a.sets general techniques to reduce
the need for process chemicals while the other techniques are more specific; this is
why the first and third bullet points of technique a. are generic. In this context, the
second bullet point seems too specific and could be moved into a separate technique.
The description of the technique in Section 4.4.7.2 in Chapter 4 of D1 refers to
softened water and not demineralised water as a way to reduce the use of complexing
agent.
No information has been made available about the lower washability of softened
water.
It is not clear in which cases the use of an ion exchanger would not be possible.
Technique b.
Section 4.1.6.4 of D1 is not explicit as to which product specifications may limit the
use of enzymes. Rather than the product specifications, it seems that the limiting
factor is the availability of the enzymes for the given treatment and textile material.
During the 2nd Data Assessment Workshop held on 21-23 October 2020, EURATEX
72
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
clarified that enzymes do not bleach, they are used in pretreatment to improve the
bleaching.
Technique c.
According to Section 4.1.6.7 of D1, the size and the age of the plant do not seem to
represent a limitation to the applicability of automated dosing and dispensing systems
in general. However, the following limitations are listed and could be reflected in the
BAT conclusions:
o space availability in existing plants, especially for the automation of dyes;
o dosing systems based on the colour-on-demand principle and automated
laboratories are still very expensive and as a consequence more suitable for
large installations;
o high number of dyes due to lack of space and the higher investment costs
required, where the plant may decide to automatise the dyes with higher
consumption and leave the others for manual dosing and dispensing;
o long piping length may be uneconomical and environmentally controversial
for small batches (because the amount of process liquor in the pipes may be
higher than the amount actually needed).
Technique f.
The residual process chemicals contained in process pipes may indeed be
contaminated, which could limit the degree to which they are used, as for water reuse
(see BAT 9). In that case, the contaminated process chemicals may need to be treated
by waste.
Concerning the shelf life of the process chemicals, this could indeed limit the degree
of reuse of the chemicals, as mentioned in BAT 44.
To move the use of demineralised water from technique a. into a dedicated technique
a1.
EIPPCB
To refer to softened water instead of demineralised water.
proposal:
To change the applicability restriction of technique (c).
To add a reference to the contaminated process chemicals and their perishability in
technique (f).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
73
Background paper – Final meeting for the review of the TXT BREF
1.4.5.3
Techniques for preventing or reducing emissions to water of poorly
biodegradable substances
Location in
P. 733 – Section 5.1.5 – BAT 16
D1:
BAT 16. In order to prevent or reduce emissions to water of poorly biodegradable
substances, BAT is to use all of the techniques given below.
Technique
Description
Applicability
Substitution of Alkylphenols and alkylphenol ethoxylates
alkylphenols
(AP/APEO)
are
substituted
by Generally
a.
and alkylphenol biodegradable surfactants, e.g. alcohol applicable
ethoxylates
ethoxylates (AE).
Complexing agents containing phosphorus
(e.g. triphosphates) or nitrogen (e.g.
polycarboxylic acids such as EDTA, DTPA
Substitution of or NTA) are substituted by biodegradable
substances, e.g:
Current
phosphorus- or
The applicability
text in D1:
nitrogen-
may be restricted
b.
polycarboxylates (e.g. polyacrylates
containing
and copolymers of acrylic and maleic by
product
complexing
acids);
specifications
agents
hydroxy
carboxylic
acids
(e.g.
gluconates, citrates);
sugar-based acrylic acid copolymers.
Substitution of
The applicability
mineral-oil-
Mineral-oil-based antifoaming agents are may be restricted
c. b ased
substituted by biodegradable substances, by
product
antifoaming
e.g. silicone-based antifoaming agents.
specifications
agents
General comment about BAT 16
Add techniques on chemicals with poor biodegradability and update the information
on the substitutes. Include techniques from other BATs for the selection of chemicals
with lower risks or chemicals which are biodegradable/bioeliminable (DE 391).
Technique a.
Mention in the technique description that the use of AP/APEO is restricted by
REACH (DE 391).
Technique b.
Change the applicability to generally applicable as the restriction proposed in D1 does
not seem justified (DE 391, EEB 108).
Add in the technique description the following substitutes (DE 391):
Summary
o methylglycinediacetic acid (MGDA), L-glutamic acid N,N-diacetic acid
of
(GLDA) and (N-(1,2-dicarboxyethyl)-D,L-aspartic acid (IDS) which are
comments:
biodegradable;
o phosphonates proven to be highly eliminable (e.g. ATMP, DTPMP and
HEDP).
Technique c.
Add in the technique description that silicone-based antifoaming agents have a
minimised content of silicone cyclic substances (D4, D5 and D6) (DE 391).
Add compounds based on synthetic ester oils as possible substitutes (DE 391).
Specify the applicability clause as follows: “For instance, silicone-based antifoaming
agents cannot be applied for all kind of coating processes. The use of silicone can be
restricted due to depositions in the textile finishing equipment such as dyeing
machines.” (DE 391).
Delete the reference to silicone because silicone contaminates the machines and the
74
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
textile and can have a negative effect on subsequent processes (EURATEX 115).
Change the applicability to generally applicable as the restriction proposed in D1 does
not seem justified (EEB 109).
Additional techniques
Add the following techniques (DE 391):
Waiving of brominated flame
Prevention of use
retardants as restricted by EU
Generally
d. of brominated
REACH Annex XVII and EU POP
applicable
flame retardants
Regulation.
Not applicable for
personal protection
equipment where
the highest levels of
Prevention of use
Finishing without PFAS for durable
repellency are
of per- and
water repellency for ordinary apparel
required to
e.
polyfluorinated
textiles and outdoor textiles except
safeguard the user.
alkylated
for anticipated derogations under EU
and for certain
substances (PFAS)
law.
technical textiles
(e.g. temperature-
resistant bag filter
fabrics)
Generally
applicable. There
are alternative
Waiving of use of chromium VI
Prevention of use
techniques and
f.
compounds for dyeing of wool (after
of Chromium VI
alternative dyes
chroming process).
available to reach
the required deep
shades.
Use of sizing
agents and
mixtures of sizing
Mixtures of starch, starch
agents fulfilling an
derivatives, polyvinyl alcohol,
Generally
g. elimination rate
polyacrylates, carboxymethyl
applicable
80 % within 28
cellulose and other sizing agents can
days according to
fulfil the elimination rate of 80 %
OECD 302B (EN-
ISO 9888)
Use of detergents
and mixtures of
detergents
fulfilling a
Generally
h.
biodegradation rate
applicable
of 70 % within 28
days according to
OECD 301A-F ()
Waiving of the use of all esters of
orthophthalic acid (phthalates), e.g.
as additive to plastics to increase
Prevention of use
flexibility, to facilitate moulding of
Generally
i.
of phthalates
plastic by decreasing its melting
applicable
temperature. In flexible plastic
components (e.g. PVC), print pastes,
adhesives and polymeric coatings
Prevention of use
Waiving of the use of UV absorbers
Generally
j.
of specific UV
UV 320, UV 327, UV 328, UV 350.
applicable
absorbers
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
75
Background paper – Final meeting for the review of the TXT BREF
General comment about BAT 16
Concerning the content of the proposed additional techniques, see the assessment
below.
Concerning the grouping of all BAT related to the selection of chemicals in BAT 16,
this concerns in particular the proposed technique d. which is related to BAT 49b, the
proposed technique e. which is related to BAT 50, the proposed technique f. which is
related to BAT 41c and the proposed technique g. which is related to BAT 32a. As
BAT 16 concerns the biodegradability of the substances used, this option would
narrow down the focus of BAT 49b, BAT 50 and BAT 32a which also address other
aspects (toxicity, washability, etc.). Concerning the proposed technique f., the hazards
related to chromium VI are not limited to its biodegradability but also concern its
(eco)toxicity and its CMR properties.
Technique a.
The scope of the proposed BAT conclusions states that the BAT conclusions apply
without prejudice to other relevant legislation such as REACH, CLP and BPR. It does
not seem necessary to indicate the status of the substances cited in the BAT
conclusions according to this legislation. In addition, this status may evolve over the
lifetime of the BAT conclusions.
Technique b.
Concerning the applicability of this technique, indeed there is no particular limitation
mentioned in Chapter 4 of D1.
Technique b. focuses on substitutes which are biodegradable and, according to
Section 8.5 of D1, phosphonates are bioeliminable but not biodegradable. This can be
clarified in the title of the technique.
MGDA, GLDA and IDS are readily biodegradable9. It is not clear if the
EIPPCB
compounds used in the TXT sector are in the form of acid or salt.
assessment:
The compounds EDTA, DTPA or NTA can be classified under the group of amino
polycarboxylic acids.
Gluconates and citrates are salts generated from the hydroxy carboxylic acids.
Technique c.
In March 2020, SEAC (Committee for Socio-economic Analysis) adopted its final
opinion10 supporting ECHA’s proposal to restrict the placing on the market of D4, D5
and D6 as substances, as constituents of other substances, or in mixtures in a
concentration equal to or greater than 0.1 % weight by weight of each substance.
Therefore, it does not seem necessary to mention D4, D5 and D6 in the BAT
conclusions as the use of these substances will be regulated in the coming months.
This could be added in the body of D1 though for information purposes.
Synthetic ester oils are mentioned in BAT 33 as a possible substitute for mineral oil
used for spinning and knitting and it would be consistent to mention them here also.
According to Section 4.1.6.8.3 of D1, the use of silicone leads to a risk of silicone
spots on the textile and silicone precipitates in the machinery, which could be
reflected in the applicability of this technique.
No information has been made available about the impact of silicone on some coating
processes.
The product specifications mentioned in the applicability restriction refer, for
example, to the automotive industry where silicone cannot be used, as mentioned in
Section 4.1.6.8.3 of D1. However, after verification with the automotive industry, it is
not clear what the automotive-specific restrictions are.
Additional techniques
Proposed technique d.
The proposal consists of banning the use of brominated flame retardants whose use is
restricted by the REACH Regulation and/or banned by the POPs Regulation. The
9 Green Processes: Designing Safer Chemicals, John Wiley & Sons, 2014
10 https://echa.europa.eu/fr/registry-of-restriction-intentions/-/dislist/details/0b0236e181a55ade
76
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 80
Background paper – Final meeting for the review of the TXT BREF
added value of this technique would therefore be very limited and may not be entirely
in line with the REACH Regulation as the REACH restrictions may contain
exemptions.
Proposed technique e.
Per- and polyfluorinated alkylated substances (PFAS) include a wide variety of more
than 3 000 compounds11.
Perfluorooctanoic acid (PFOA) and its salts are listed in Annex XVII to the REACH
Regulation and from 4 July 2020 shall not be manufactured, or placed on the market
as substances on their own or be used in the production of, or placed on the market in
another substance, as a constituent, a mixture, an article, in a concentration equal to or
above 25 ppb by weight of PFOA including its salts or 1 000 ppb by weight of one or
a combination of PFOA-related substances.
Perfluorooctane sulphonic acid and its derivatives (PFOS) are prohibited by the POPs
Regulation. Some exemptions are:
o concentrations of PFOS equal to or below 0.001 % by weight when it occurs
in substances or in preparations;
o concentrations of PFOS in semi-finished products or articles, or parts
thereof, if the concentration of PFOS is lower than 0.1 % by weight
calculated with reference to the mass of structurally or micro-structurally
distinct parts that contain PFOS or, for textiles or other coated materials, if
the amount of PFOS is lower than 1 μg/m2 of the coated material.
Adding a technique to ban the use of substances already subject to restrictions or to
prohibition does not seem necessary and may not be entirely in line with the REACH
Regulation.
Concerning the other PFAS, no information has been provided as to why they are not
to be used.
Proposed technique f.
Sodium and potassium dichromate are “substances of very high concern” listed in
Annex XIV to the REACH Regulation and the use of these substances is subject to
authorisation. Therefore, adding a technique to ban their use does not seem necessary
and would not be in line with the REACH Regulation.
Proposed technique g.
The proposed technique g. is based on BAT 32a in D1.
It is not clear why galactomannans are proposed to be removed from the examples of
sizing chemicals with improved environmental performance.
According to Section 8.3 of D1, carboxymethyl cellulose (CMC) is water-soluble.
CMC is mentioned as being very difficult to degrade as only 20 % of the initial
amount is eliminated after 7 days. However it can be reduced after longer periods of
adaptation (> 4 weeks) and in favourable conditions (especially higher temperatures).
CMC could therefore be added in the examples of sizing chemicals with improved
environmental performance.
Concerning the elimination rate of 80 % within 28 days according to EN ISO 9888,
see the assessment related to BAT 18 (Section
1.4.6.2).
Proposed technique h.
According to Table 8.8 of D1, nearly all the types of surfactants which are used in the
textiles industry have a biodegradability higher than 70 %12 except APEO.
The substitution of APEO by biodegradable surfactants is already addressed in
technique a.
Proposed technique i.
Phthalates include a wide variety of different compounds.
DEHP (bis- (2-ethylhexyl) phthalate), benzyl butyl phthalate (BBP), dibutyl phthalate
11
https://www.umweltbundesamt.de/themen/chemikalien/chemikalien-reach/stoffgruppen/per-polyfluorierte-chemikalien-pfc#was-
sind-pfc
12 According to test OECD 301E
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
77
Background paper – Final meeting for the review of the TXT BREF
(DBP), dihexyl phthalate and diisobutyl phthalate (DIBP) are listed in Annex XVII to
the REACH Regulation and shall not be used as substances or in mixtures, in
concentrations greater than 0.1 % by weight of the plasticised material, in toys and
childcare articles.
DEHP is also listed in Annex XIV to the REACH Regulation. One authorisation
granted to a manufacturer may possibly concern the textile industry (PVC-based
waterproof clothing and footwear).
Seven other phthalates are listed in Annex XIV to the REACH Regulation: benzyl
butyl phthalate (BBP), dibutyl phthalate (DBP), dihexyl phthalate, diisobutyl
phthalate (DIBP), diisopentyl phthalate, bis(2-methoxyethyl) phthalate, dipentyl
phthalate and N-pentyl-isopentylphthalate. No application for authorisation has been
submitted so far for uses in the textile sector.
Adding a technique to ban the use of substances already subject to authorisation does
not seem necessary and may not be entirely in line with the REACH Regulation.
D1 mentions that DEHP may be used as a dyeing auxiliary but does not mention
other phthalates.
No information has been provided about the use of other phthalates and their possible
substitutes.
Proposed technique j.
UV 320 (2-benzotriazol-2-yl-4,6-di-tert-butylphenol), UV 327 (2,4-di-tert-butyl-6-(5-
chlorobenzotriazol-2-yl)phenol),
UV 328
(2-(2H-benzotriazol-2-yl)-4,6-
ditertpentylphenol) and UV 350 (2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-
butyl)phenol) are “substances of very high concern” listed in Annex XIV to the
REACH Regulation and their use is subject to authorisation. Therefore, adding a
technique to ban their use does not seem necessary and would not be in line with the
REACH Regulation.
To amend the title of technique b.
To add examples of possible substitutes in technique b.
EIPPCB
To change the applicability restriction of technique b to generally applicable.
proposal:
To complement the description of technique c.
To modify and complement the applicability restriction of technique c.
To add a reference to carboxymethyl cellulose (CMC) in BAT 32a.
1.4.6
Emissions to water
1.4.6.1
Techniques for reducing the waste water volume, the pollutant
loads discharged to the waste water treatment plant and the
emissions to water
Location in
P. 734 – Section 5.1.6 – BAT 17
D1:
BAT 17. In order to reduce the waste water volume, the pollutant loads discharged
to the waste water treatment plant and the emissions to water, BAT is to use an
integrated waste water management and treatment strategy that includes an
appropriate combination of process-integrated techniques, techniques to recover and
Current
reuse process liquors, and treatment techniques (see BAT 18 and BAT 19).
text in D1:
Description
The integrated waste water management and treatment strategy is based on the
information provided by the inventory of inputs and outputs (see BAT 2).
Whole BAT
Integrate BAT 17 with BAT 2 and BAT 9 to avoid repetition, ease the
Summary
implementation and streamline general requirements for waste water management.
of
The relations of waste water management and treatment strategy in BAT 17, the
comments:
inventory of water inputs and outputs in BAT 2, and the water management plan in
BAT 9 need to be clarified. Since both BAT 2 and BAT 9 are part of the
environmental management system (BAT 1), it is unclear if the waste water
78
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
management and treatment strategy of BAT 17 is also part of the EMS. Also, it is
unclear whether the inventory of water inputs and outputs (BAT 2) is not already
covered by the water management plan (BAT 9) (AT 40).
Delete BAT 17 as it is part of BAT 18 (DE 267).
BAT statement
Change the statement to highlight the need for concentrated bath and pastes to be
collected, recovered/reused or handled (e.g. disposed) as waste containing hazardous
chemicals (SE 15).
Description
Clarify that external waste water treatment can be done by an external waste water
treatment plant (WWTP) (EURATEX 16).
Whole BAT
A technique can fulfil several environmental objectives in different BAT conclusions.
The environmental objective of BAT 2 is to improve the overall environmental
performance of the plant, of BAT 9 to reduce water consumption and waste water
generation and of BAT 17 to reduce the waste water volume, the pollutant loads
discharged to the waste water treatment plant and the emissions to water. These are
different aspects of the plant’s environmental performance.
The issues addressed by the three BAT may overlap but are approached from
different perspectives and with different goals: BAT 2 aims to ensure
data/information collection for all input/output streams; BAT 9 focuses mainly on
reuse/recovery/reduction of consumption of waters and process liquors (and
consequently on waste water reduction) and BAT 17 deals with strategy for reduction
or treatment of waste waters.
An integrated waste water management and treatment strategy can be a part of a
water management plan (BAT 9a). It is a decision-making tool for selection of the
optimal waste water treatment, used in an ongoing decision-making process (e.g. for
evaluation of the waste water treatment options and the efficiency of the techniques
used) of the environmental management system in an operating installation.
Recovery/reuse of process liquors is addressed in BAT 9i. The cross-reference could
be added.
BAT 2 already cross-references BAT 1 and BAT 9 to highlight its link to the
environmental management system – so an additional reference in BAT 17i is not
needed.
EIPPCB
BAT 17 is generic and BAT 18 is specific. BAT 17 aims at selection of techniques to
assessment:
either reduce/reuse process liquor, (pre)treat it as waste water or handle it as waste
(see assessment below). BAT 18 sets further criteria for the pretreatment of effluents
of spent process liquors (i.e. with pollutants that cannot be adequately treated by or
could harm the operation of a biological treatment). Deleting BAT 17 would reduce
the flexibility of using an appropriate combination of techniques and remove the
process of their selection as an important decision-making tool.
BAT statement
If process liquors cannot be i) reduced by process-integrated techniques, ii)
reused/recovered or iii) treated by a suitable waste water pretreatment, they can be
handled as waste (e.g. treated or disposed of off site). The concentrated process
liquors with recalcitrant and toxic pollutants are best removed, treated or disposed of
from the common waste water flow (not to be diluted by mixing with other waste
water streams), thereby reducing the pollutant loads to be treated and discharged. This
could be mentioned in the BAT statement.
Concentrated baths and pastes that contain recalcitrant pollutants are addressed in
BAT 18.
Description
The use of off-site contractors to control the environmental impacts of the plant is an
implementation decision that is not within the scope of the BAT conclusions but in
the hands of the operator and the competent authority. The alternative of off-site
treatment is mentioned in BAT 18.
EIPPCB
To restructure the text indicating the order of priority and listing the techniques on
proposal:
separate lines.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
79
Background paper – Final meeting for the review of the TXT BREF
To add cross references to other BAT to the techniques (e.g. BAT 9i, BAT 38 and
others).
To add as one of the techniques separation and pre-treatment or handling as waste of
concentrated waste water streams, which are the subject of BAT 18.
1.4.6.2
Techniques for reducing emissions to water
Location in
P. 734 – Section 5.1.6 – BAT 18
D1:
BAT 18. In order to reduce emissions to water, BAT is to (pre)treat waste water
containing pollutants that cannot be treated adequately by a biological treatment.
Description
The treatment is carried out as part of an integrated waste water management and
treatment strategy (see BAT 17) and is generally necessary to:
protect the (downstream) biological waste water treatment against inhibitory or toxic
compounds;
remove compounds that are insufficiently abated during biological waste water
treatment (e.g. toxic compounds, poorly biodegradable organic compounds, organic
compounds that are present in high concentrations, or metals);
remove compounds that could otherwise be stripped to air from the collection system
or during biological waste water treatment (e.g. sulphide);
Current
remove compounds that have other negative effects (e.g. corrosion of equipment;
text in D1:
unwanted reaction with other substances; contamination of waste water sludge).
The treatment is carried out on site or off site. On-site treatment is generally carried out as
close as possible to the source in order to avoid dilution.
The techniques used depend on the pollutants targeted and include adsorption, chemical
oxidation and chemical reduction (see BAT 19).
Waste water which may contain toxic or poorly biodegradable compounds includes:
spent liquors from sizing, dyeing and finishing;
spent printing pastes.
The biodegradability of the COD/TOC content of the waste water sent to biological
treatment is at least 80 %, monitored in accordance with the standard EN ISO 9888
BAT statement
Change the BAT statement to emphasise the minimisation of the amount of waste
water, and to focus on retaining and reusing waste waters containing pollutants that
cannot be adequately treated by biological treatment (DE 267).
Introduction
Change in the introductory sentence “generally necessary” to “aims at” to focus more
Summary
on technical features of the technique (FR_A 12).
of
comments:
First bullet point
Reword the first bullet point to keep only the technical feature of technique, which is
treating/removing inhibitory or toxic compounds (FR_A 13).
Second bullet point
In the second bullet add the reference to BAT 19 and list the treatment techniques
according to the pollutants they are relevant for: a) chemical oxidation, chemical
reduction, filtration, adsorption or evaporation for poorly biodegradable organic
80
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
compounds; b) adsorption, precipitation, chemical oxidation, chemical reduction for
organic compounds present in high concentrations; c) precipitation for soluble metals
or solid removal for metals bound to suspended solids (BE 17).
In the second bullet point indicate that the metals are present in high concentrations.
Metals come from dyes but pretreatment is needed only in the case of high
concentrations (EURATEX 17).
In the second bullet specify toxic/poorly biodegradable waste water streams’
concentrates such as desizing liquors, residual padding liquors from continuous or
cold pad-batch dyeing, residual printing pastes, residual padding liquors from final
finishing. In addition, specify that they need to be pretreated. A concrete wording
proposal is attached to the comment (DE 267).
On-site and off-site treatment
Remove the sentence stating that the treatment is carried out on site or off site,
because it is inconsistent, the purpose of this wording is not clear and has no added
value (FR_A 15).
Treatment techniques
Change the wording “chemical oxidation and chemical reduction” to “chemical
oxidation OR chemical reduction”, because they are opposite reactions
(EURATEX 18).
Waste water streams concerned
Move the paragraph listing poorly biodegradable compounds under the second bullet
as it deals with toxic or poorly biodegradable compounds (FR_A 14).
Add coating pastes next to printing pastes as they can also contain toxic or poorly
biodegradable compounds and are used in larger amounts then printing pastes
(SE 16).
Add that individual waste water streams listed here need to be collected separately
(segregated) (DE 267).
Add padding liquors from continuous or cold pad-batch dyeing and final finishing
(DE 267).
Level of biodegradability
Add bioelimination (DE 290) or elimination (EURATEX 116) to biodegradability in
the last sentence of the description (DE 290, EURATEX 116).
Clarify the regulatory status of the percentage, i.e. whether it is an indicative value,
BAT-AEPL or BAT-AEL, or delete it (FR_A 20).
The monitoring standard is not consistent with BAT 7 (FR_A 20).
Delete the last sentence because no information has been collected (i.e. within the
questionnaires) regarding the level of biodegradability of the COD/TOC content of
the waste water sent to biological treatment (IT 21).
Provide justification for how the figure of 80 % was derived (UK 20).
Additional proposals
Add that the technique is not applicable for commission working plants, or
alternatively that it is applicable only to new plants and major plant upgrades. The
reasons are high costs related to the investment in (pre)treatment techniques and
difficult identification and separation of polluting waste water streams in commission
working plants (EURATEX 15).
Add that for the applicability of this BAT the economical/technical feasibility should
be taken into account and demonstrated (EURATEX 19).
Add a BAT for on-site pretreatment of waste water streams containing
organophosphorus flame retardants (FR) for both direct and indirect discharges. D1
gives confusing information: that organophosphorus FR should be collected and not
discharged (p. 806), that urban WWTPs should be equipped with appropriate tertiary
treatment for organophosphorus FR (p. 171). In addition, there is a general overview
of techniques that can be used to remove soluble, non-biodegradable contaminants,
such as organophosphorus FR (p. 425) (BE 19).
EIPPCB
BAT statement
assessment:
BAT 9 and BAT 17 aim to reduce waste water generation or its volume by choice of
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
81
Background paper – Final meeting for the review of the TXT BREF
various techniques. The focus of this conclusion is reducing emissions to water either
by pre-treatment.
Introduction
The wording was used in BAT 11 of the CWW BAT conclusions. It is not clear why
rewording would be needed.
First bullet point
The bullet expresses the important goal of the removal of inhibitory or toxic
compounds. The wording was used in BAT 11 of the CWW BAT conclusions. It is
not clear why rewording would be needed.
Second bullet point
The individual waste water treatments that may abate the inhibitory or toxic
compounds are listed in BAT 19. This was referenced in the description in the
following paragraph (e.g. see Treatment techniques below).
The main source of metals in the spent process liquors are dyes. This is indicated by
mentioning spent liquors from dyeing in the listing of the individual waste water
streams in the description below the bullets (e.g. see Waste water streams concerned).
Repeating the individual waste water streams in bullets explaining the aim of the
pretreatment would complicate the text. The need to pretreat at source to avoid
dilution is explained in the description following the bullets. The alternative to
pretreatment is handling these waste water streams as waste.
On-site and off-site treatment
The off-site or on-site treatment are implementation options to be decided by the
operator and the competent authority on a case-by-case basis to comply with BAT-
AELs and local environmental constraints. Therefore, mention of these options can be
avoided in the description.
Treatment techniques
The wording should be changed to indicate that either chemical oxidation or chemical
reduction is possible.
Waste water streams concerned
The paragraph listing the waste water streams concerned could be moved to the
beginning of the description. It does not seem practical to merge it with the bullets
listing the aims of the treatment.
Spent coating baths could be added to the list of waste water streams similar like
finishing baths.
According to the data collection, out of 106 plants, only 6 (DE024, DE030, DE039,
DE049 FR130 and FR133) reported handling spent dyeing baths and padding liquors
as waste and 17 reported treating them as waste waters; 10 plants (DE022, DE024,
DE025, DE030, DE032, DE046, DE047, DE049, FR135 and SE119) reported
handling spent finishing baths or padding liquors as wastes and 8 reported treating
them as waste waters.
It could be highlighted that individual waste water streams considered in this
conclusion need to be collected separately (segregated).
Padding liquors from continuous or cold pad-batch dyeing and finishing could be
added to the list of waste water streams.
Level of biodegradability
Bioeliminability seems to be an appropriate parameter in relation to the treatment
techniques (adsorption, chemical oxidation and chemical reduction) proposed to
remove the pollutants. The percentage of bioeliminability of the treated waste waters
is part of the BAT description (efficiency of the removal) and does not have the status
of a BAT-AE(P)L. The BAT-AE(P)Ls in the conclusions are clearly indicated as such
according to Implementing Decision 2012/119/EU.
The monitoring standard for biodegradability and bioeliminability is EN ISO 9888 –
as also indicated in the table of BAT 7.
The fact that data/information on biodegradability was not collected via
questionnaires is not a reason for dismissing other sources available to the EIPPCB or
82
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
expert opinion.
The bioeliminability or biodegradability of more than 80 % (e.g. after 28 days in
relation to the Zahn-Wellens test (EN ISO 9888) according to the OECD 301 test) is
considered a criterion for biodegradable/bioeliminable substances in several places
within D1 (e.g. Figure 4.35 in Section 4.1.3.2.1. Selection of sizing agents).
Additional proposals
The only economic information on costs for waste water treatment techniques was
provided for a combination of techniques called Zero Liquid Discharge. No
information on high costs of separation or treatment of these waste water streams in
commission working plants was provided, which makes economic assessment
difficult.
The plants reporting using this technique demonstrate the technique’s
economic/technical feasibility. No other information enabling economic assessments
was provided.
Spent finishing liquors would include the waste water streams containing
organophosphorus flame retardants (FR). The waste water treatments mentioned in this
conclusion would remove organophosphorus FR from the waste waters. This conclusion
is valid irrespective of the type of discharge. The need to collect ant treat these waste
streams separately from others could be reflected in the statement and description of the
conclusion.
BAT statement
To modify the statement to highlight the high pollutant loads of poorly biodegradable
compounds.
Description section
To put the list of the waste water streams considered at the beginning of the
description.
EIPPCB
To complement the list with spent dyeing, coating and finishing liquors.
proposal:
To indicate that these streams include residual padding liquors from continuous
and/or cold pad-batch processes.
In the statement on treatment, to indicate chemical oxidation and chemical reduction
techniques as alternatives (linking them with ‘or), and to possibly add filtration and
precipitation.
To replace ‘Biodegradability of the COD/TOC content’ with ‘bioeliminability’ of
waste water streams sent to downstream biological treatment.
Location in
P. 735 – Section 5.1.6 – BAT 19
D1:
BAT 19. In order to reduce emissions to water, BAT is to use an appropriate
combination of the techniques given below.
Technique (1)
Typical pollutants targeted
Applicability
Preliminary and primary treatment, e.g.
a.
Equalisation
All pollutants
b.
Neutralisation
Acids, alkalis
Physical separation (e.g.
screens, sieves, grit
Generally
Current
separators, grease separators,
Gross solids, suspended solids,
applicable
c.
text in D1:
oil-water separation,
oil/grease
hydrocyclones or primary
settlement tanks)
Physico-chemical treatment, e.g.
Adsorbable dissolved non-
d.
Adsorption
biodegradable or inhibitory
pollutants, e.g. AOX
Generally
Precipitable dissolved non-
applicable
biodegradable or
e.
Precipitation
inhibitory pollutants, e.g. metals,
phosphorus
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
83
Background paper – Final meeting for the review of the TXT BREF
Oxidisable dissolved non-
f.
Chemical oxidation
biodegradable or inhibitory
pollutants, e.g. AOX, sulphide
Reducible dissolved non-
biodegradable
g.
Chemical reduction
or inhibitory pollutants, e.g.
hexavalent chromium (Cr(VI))
h.
Evaporation
Soluble contaminants
Biological treatment, e.g.
i.
Activated sludge process
Biodegradable organic
Generally
j.
Membrane bioreactor
compounds
applicable
k.
Anaerobic treatment
Nitrogen removal
Nitrification
may not be
applicable in
the case of
high chloride
concentrations
(e.g.
Nitrification/denitrification
above 10 g/l).
l.
(when the treatment includes
Total nitrogen, ammonia
Nitrification
a biological treatment)
may not be
applicable
when the
temperature
of the waste
water is low
(e.g. below 12
°C).
Solids removal, e.g.
m. Coagulation and flocculation
n.
Sedimentation
Filtration (e.g. sand
Suspended solids and
Generally
o.
filtration, or membrane
particulate-bound metals
applicable
filtration)
p.
Flotation
(1) The descriptions of the techniques are given in Section 5.9.3.
Whole BAT
Add technique 'boiling of effluent with caustic soda to destroy the permethrin' (used
in Plant UK123, see paragraph 4.1.7.3.4.1 of D1) because of its performance and
permethrin’s high toxicity to aquatic organisms (BE 29).
Restructure the BAT to reflect the common sequences for textile-specific waste water
treatment plants (primary, secondary, tertiary treatment etc.), including textile-
specific requirements and removal efficiency. Also, add examples of waste water
treatment sequences. Proposals are attached to the comment13 (DE 268).
Summary
Revise the table substantially because the currently proposed description can be
of
misleading (i.e. some of the techniques have been assigned a false function and
comments:
position in the sequence of downstream treatment operations). A proposal is attached
to the comment (CZ_B 19).
Add zero liquid discharge (ZLD) to the list, together with information on its severe
cross-media effects (see final report on EU project EColoRO) (DE 392).
Biological treatment, e.g.
Technique k.
Indicate that the applicability of anaerobic treatment may be restricted by the
13 Schönberger, H., Technique combinations to meet the ambitious ZDHC Wastewater Guidelines, Proceedings of the Colloquium
on Textile Wastewater Management 2018-09-18/Integrated Best Available Wastewater Management in the Textile Industry,
Vulkan-Verlag GmbH, Essen (2018) p.35 – 70
84
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
composition of waste water (EURATEX 20).
Solids removal, e.g.
Technique o.
Add the following specific membrane filtration techniques: nanofiltration, reverse
osmosis, ultrafiltration and microfiltration (BE 26).
Whole BAT
The technique 'boiling of effluent with caustic soda to destroy the permethrin' (used in
Plant UK123) is considered to be an example of chemical oxidation treatment and is
mentioned in Section 4.1.7.3.4.1 of D1. Pesticides could be mentioned as an example
of typical pollutants targeted by the chemical oxidation technique.
The removal efficiencies of individual techniques are given in Chapter 4 of D1; they
are indicative of potential environmental performance in any sector (not just textiles).
According to the data collection, only 16 out of 1 213 data sets for emissions to water
reported the actual removal efficiencies in the real plants (see Section 3.4.1 of D1).
The BAT-AELs are typically considered a sufficient regulatory tool to ensure
appropriate removal of pollutants. High removal efficiencies are exceptionally used
instead of BAT-AELs for regulating cases of high water recycling and consequently
high pollutant load build-up.
The BAT statement instructs the operator and competent authority that the
appropriate combination of techniques listed in the table is to be selected. The
groupings of techniques (e.g. primary, secondary, tertiary treatment etc.) as proposed
in the comments could be helpful for the implementation.
The textile-specific pollutants targeted related to specific waste water treatment
techniques could be amended.
The Zero Liquid Discharge approach to waste water treatment and recycling is a
EIPPCB
combination of techniques already presented in the table. Many approaches using
assessment:
different combinations and variations of techniques from the table are presented in
Section 4.1.7.4 of D1.
Biological treatment, e.g.
Technique k.
The typical pollutants removed from the effluents by the treatment techniques are
indicated in the table. The choice of appropriate techniques to remove certain
pollutants is not considered an applicability restriction.
As indicated in Section 4.1.7.3.5.2 of D1, the technique is typically used as a
(pre)treatment for waste water which is characterised by a high organic load (> 2 g/l)
and a more or less constant quality. It is therefore used mostly in the sectors with
effluents with consistently high BOD loads. In the textile sector, anaerobic
bioreactors are used in combination with activated sludge treatment to treat textile
effluents with a high COD concentration and dyestuff pollutants. According to the
data collection, Plants CZ019 and FR134 indicated using the technique.
Solids removal, e.g.
Technique o.
Specific membrane filtration techniques: nanofiltration, reverse osmosis,
ultrafiltration and microfiltration are already listed in the description of the membrane
filtration technique in Section 5.9.3.
To restructure the table to follow the steps (e.g. pre-treatment, primary, secondary,
EIPPCB
tertiary, advanced) in the waste water treatments typical for textile sector.
proposal:
To add examples of typical pollutants targeted by specific waste water treatment
techniques.
1.4.6.3
BAT-AELs for direct discharges to a receiving water body
Location in
P. 735 – Section 5.1.6 – BAT 19 – Table 5.3
D1:
Current
Table 5.3: BAT-associated emission levels (BAT-AELs) for direct discharges to a
text in D1:
receiving water body
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
85
link to page 24 link to page 27
Background paper – Final meeting for the review of the TXT BREF
BAT-AEL (1)
Substance/Parameter
Activities / processes
(mg/l)
Adsorbable organically bound halogens
0.1–0.5
(AOX) (2)
All activities /
Chemical oxygen demand (COD) (3)
processes
40–120 (4)
Hydrocarbon oil index (HOI)
1–10
Pre-treatment and/or
dyeing of polyester
Antimony (Sb)
Finishing with flame
0.1–0.4
retardants using
antimony trioxide
Metals /
Dyeing with
metalloids
Chromium (Cr)
chromium-containing
0.01–0.3
dyes
Copper (Cu)
0.03–0.4
All activities /
Nickel (Ni)
0.01–0.5
processes
Zinc (Zn)
0.04–0.5
Dyeing with sulphur
Sulphide, easily released (S2-)
0.3–1
dyes
Total nitrogen (TN)
5–20 (5)
Total organic carbon (TOC) (3)
All activities /
13–40 (6)
Total phosphorus (TP)
processes
0.4–5
Total suspended solids (TSS)
5–45
(1) The averaging periods are defined in the general considerations.
(2) The BAT-AELs only apply when the substance/parameter concerned is identified as
relevant in the waste water stream based on the inventory of inputs and outputs
mentioned in
0.
(3) Either the BAT-AEL for COD or the BAT-AEL for TOC applies. The BAT-AEL
for TOC is the preferred option because TOC monitoring does not rely on the use of
very toxic compounds.
(4) The upper end of the BAT-AEL range may be up to 150 mg/l when the amount of
waste water discharged is less than 25 m3/t of treated textile materials.
(5) The BAT-AEL may not apply when the temperature of the waste water is low (e.g.
below 12 °C) for prolonged periods.
(6) The upper end of the BAT-AEL range may be up to 50 mg/l when the amount of
waste water discharged is less than 25 m3/t of treated textile materials.
The associated monitoring is given in
0. General comments
Derive BAT-AELs for direct discharges to a receiving water body based on the
reported emission data of the direct discharges, because indirect discharges do not
implement an appropriate combination of the techniques to reduce emissions to water
for direct discharge (e.g. physico-chemical treatment, biological treatment, nitrogen
removal, solids removal); see also comments BE 21 and BE 22 (BE 3).
Express BAT-AELs as specific loads in kg/ton of treated textile or add an appropriate
expression/factor (× m3/t) for all BAT AELs. Many important BATs which reduce
water and energy consumption simultaneously increase the concentration of
pollutants (see also comment SE 40) (SE 26).
Summary
In the interest of transparency, explain the methodology of deriving BAT-AELs either
of
within the BREF or in a separate document (UK 21).
comments:
Additional parameters
Set a BAT-AEL range for BOD at 5-10 mg/l, because it shows the efficiency of the
WWTP. Also, the collected data indicate that the range is valid (SE 28).
Set an upper end of the BAT-AEL range for colour for dyeing activities as 1/30
dissolution (ES 38); or as spectral absorption coefficients at 436 nm (yellow range)
7 m-1; 525 nm (red range) 5 m-1; 620 nm (blue range) 3 m-1 (DE 273). Colour in
discharge could have a negative impact on water bodies and has a high public
response (ES 38, DE 273).
Set BAT-AEL ranges for the following:
o
NH4-N with the upper end of the range up to 10 mg/l, because it is toxic to
86
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
fish.
o
Toxicity with the option to use one or a combination of different
measurement methods. For EN ISO 15088 set the upper end of the range up
to 2 mg/l. It is important to control the toxicity for directly discharged waste
water (DE 273).
Set the BAT-AEL range for nonylphenol to 0.0002-0.005 mg/l (= 0.2-5 µg/l)
Nonylphenol is a substance of environmental concern. There are 17 data sets for the
value of NP and 13 data sets are in the proposed BAT-AEL range. Emission limit
values for this parameter are set in some national regulations (e.g. in France 0.025
mg/l and in Belgium 0.00008 mg/l) (AT 15).
Set a BAT-AEL range for DecaBDE to 0.001-0.02 mg/l because DecaBDE is a
substance of environmental concern. In addition, there are 5 data sets for DecaBDE.
Finally, the use and production of the substance have been prohibited by the EU POP
Regulation 2019/1021 since 2019 (AT 17).
Set a BAT-AEL range for Sum of PFOA and PFOS to 0.001-0.003 mg/l because
PFOA and PFOS are substances of environmental concern. There are 8 data sets for
PFOA and 7 data sets for PFOS. In 2019, PFOA and its salts were listed in category
A (Elimination) in the Stockholm Convention on Persistent Organic Pollutants (entry
into force: December 2020). In the EU, the production, placing on the market and use
of PFOA, its salts and polymers have been restricted in Annex XVII to REACH since
2017 (AT 19).
Adsorbable organically bound halogens (AOX)
Increase the upper end of BAT-AEL range for polyester and blends of
modacryl/cotton to 1 mg/l, and change the BAT-AEL range for other fibres to 0.1-
0.6 mg/l. Companies with specific processes, e.g. polyester dyeing and
modacryl/cotton dyeing, have an AOX discharge of 1.9 mg/l (90th percentile) and
1.46 mg/l (80th percentile) for indirect discharges. 1 mg/l is a reasonable limit based
on 10 times the environmental quality standard. A 90th percentile value for the upper
limit is more representative for the well-performing plants (EURATEX 21).
Increase the upper end of the BAT-AEL range to 0.8 mg/l for dyeing products with
high lightfastness, and high quality demands (EURATEX 136).
Lower the upper end of the BAT-AEL range to 0.3-0.4 mg/l. The upper end of the
BAT-AEL range of 0.5 mg/l is in line with limits of certification schemes. Although
collected data indicate that many plants are below or even consistently well below
this level, contextual information (e.g. on the set-up and process conditions of the
waste water treatment plants) for technically deriving a more ambitious BAT is
lacking (EEB 152, EEB 165).
Chemical oxygen demand (COD)
Lower the upper end of the BAT-AEL range to 100 mg/l because, according to the
collected data, the average concentration of only 3 plants is above 100 mg/l, there are
only 2 plants with a maximum concentration between 100 mg/l and 120 mg/l and 58
% of plants below 100 mg/l. With good physical, biological and chemical treatment,
less than 80 mg/l COD can be achieved (AT 3, SE 25).
Decrease the BAT-AEL range to 30-100 mg/l to align it with the CWW BAT
conclusions. Collected data show that plants achieve concentrations below 100 mg/l
and those above 120 mg/l are probably not applying BAT. Two plants achieve
concentrations lower than the proposed BAT-AEL range (IT082 and IT092),
indicating the best achievable level (EEB 153, EEB 165).
Increase the upper end of the BAT-AEL range to 160 mg/l (FR_A 52).
Increase the upper end of the BAT-AEL range to 160 mg/l because the 85th percentile
of collected data represents the performance of the majority of plants better
(EURATEX 22, EURATEX 158).
Footnote (4)
Decrease the upper end of the range in Footnote (4) to 130 mg/l if the removal
efficiency is at least 90 %. Indeed, the exemption should be rather linked to the
removal efficiency because Table 5.1 (BAT-AEPLs for specific water consumption)
shows that for batch processes the specific water consumption ranges are above 25
m3/t treated textile materials; and for continuous processes below 25 m3/t treated
textile materials. The strong variation of water consumption data shows that it is not
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
87
Background paper – Final meeting for the review of the TXT BREF
appropriate to use water consumption as the basis for an exemption. Also, the
proposed threshold is hard for the authorities to control (AT 4).
Increase the upper end of the BAT-AEL range in Footnote (4) to 250 mg/l
(EURATEX 22, EURATEX 158), or to 150 mg/l (DE 272) or 160 mg/l (FR_A 52),
for waste waters with a high COD content in the influent if the removal efficiency of
the WWTP is at least 90 % (DE 272) or 95 % as a yearly or monthly average (e.g. see
FR131) (FR_A 52). Such a footnote was already added in the FDM BAT conclusions.
Define the high COD content in the influent (DE 272, FR_A 52).
Increase the water consumption level in Footnote (4) to the one reached by the
plants/sites with multiple processes and process routes; according to the data
collection, only a few single-process sites reach the proposed level. Add in the
footnote the expected associated BOD level equal to or less than 25 mg/l as an
indicator of the biodegradability of the effluent (UK 22).
Hydrocarbon oil index (HOI)
Add Footnote (2) to this parameter, because it is not relevant for all processes
(DE 370, CZ_B 7).
Decrease the upper end of the BAT-AEL range to 5 mg/l. From the data collection,
there are 4 data sets for direct discharge applying biological treatment with activated
sludge achieving concentrations below 1 mg/l (AT 14).
Keep or lower the upper end of the BAT-AEL (EEB 154, EEB 165).
Metals / metalloids
Add a Footnote (2) to these parameters as they are not relevant for all processes
(DE 371).
Antimony (Sb)
Increase the upper end of the BAT-AEL range for the cases where both processes are
applied in the plant (pretreatment and/or dyeing of polyester and finishing with flame
retardants using antimony trioxide) to 0.6 mg/l. Increase the upper end of the BAT-
AEL range to 1.2 mg/l for plants doing polyester and modacryl/cotton dyeing
(EURATEX 42).
Increase the upper end of the BAT-AEL range for antimony to 0.5 mg/l. According to
Commission Implementing Decision 2012/119/EU (Section 3.3), rounded values can
be set as BAT-AELs to take into account limitations in the data collection or other
technical aspects (DE 366).
Set separate BAT-AEL ranges for each process: for pretreatment and dyeing the
upper end of the range should be 1.5 mg/l (because antimony used as a catalyst for
polyester production is leached out of fibre at high temperature (above softening
point) and emissions cannot be avoided); and for finishing 0.1-0.4 mg/l
(EURATEX 135) or 0.1-0.5 mg/l (DE 196) (emissions can be minimised by retention
of padding liquor and contaminated rinsing water) (EURATEX 135).
Lower the upper end of the BAT-AEL range to 0.2 mg/l. Collected data show that
around 65 % of the plants are below 0.2 mg/l. Experience from Austrian plants show
that lower values can be achieved by good chemical and water management (e.g. see
BAT 49). Lower values can be achieved with abatement techniques nanofiltration,
microfiltration, ultrafiltration, prevention measures (separate disposal of chemicals)
and precipitation. According to national waste water legislation (AT Textile and AT
Glass), 0.3 mg/l Sb is achieved with prevention measures (separate disposal of
chemicals) and precipitation (AT 46).
Modify the BAT-AEL range (both lower and upper ends) to 0.01–0.15 mg/l. Three
out of four installations that report measurements have values below 0.3 mg/l, two
below 0.15 mg/l. The plant with the lowest emissions has substantial activity in
polyester dyeing. ZDHC limits are 0.01 mg/l, 0.05 mg/l and 0.1 mg/l for their three
performance levels (EEB 155, EEB 165).
Chromium (Cr)
Increase the lower end of the BAT-AEL range to 0.05 mg/l, because the lower limit
would be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS causes excessive costs (EURATEX 43).
Increase the upper end of the BAT-AEL range for chromium to 0.5 mg/l. According
to Commission Implementing Decision 2012/119/EU (Section 3.3), rounded values
88
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
can be set as BAT-AELs to take into account limitations in the data collection or
other technical aspects (DE 366).
Lower the upper end of the BAT-AEL range to 0.1 mg/l. According to the data
collected, a large number of plants can easily comply with 0.1 mg/l. The data sets
from Plants PT102, PT104, PT111 should not be included in the analysis because of
poor measurement quality (e.g. reporting results below the LoD, measuring the same
value repeatedly, etc.). Also, data sets from Plants IT063, IT072 and SE119 cannot be
considered BAT because of too high values (and fluctuations). Also, other standards
are stricter than the proposed level: e.g. ZDHC requires 0.05/0.1/0.2 mg/l as
maximum levels for the three performance classes; and Oeko-tex requires 0.2 mg/l
(EEB 156, EEB 165).
Copper (Cu)
Increase the lower end of the BAT-AEL range to 0.05 mg/l, because the lower limit
would be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS causes excessive costs (EURATEX 43).
Increase the upper end of the BAT-AEL range for copper to 0.5 mg/l. According to
Commission Implementing Decision 2012/119/EU (Section 3.3), rounded values can
be set as BAT-AELs to take into account limitations in the data collection or other
technical aspects (DE 366).
Increase the upper end of the BAT-AEL range to 0.8 mg/l for dyeing products with
high lightfastness, and high quality demands (EURATEX 137).
Lower the upper end of BAT-AEL range to 0.2 mg/l. Add a footnote that in the case
of increased lightfastness requirements (use of copper-containing dyes), the upper end
of the BAT-AEL range is up to 0.4 mg/l. According to the collected data, around
65 % of the plants are below 0.2 mg/l. Abatement technologies reverse osmosis,
nanofiltration, microfiltration could be used (AT 7).
Lower the upper end of the BAT-AEL range to 0.2 mg/l. According to the data
collection, reported values are generally well below 0.2 mg/l (EEB 157, EEB 165).
Nickel (Ni)
Increase the lower end of the BAT-AEL range to 0.05 mg/l, because the lower limit
would be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS causes excessive costs. (EURATEX 43).
Increase the upper end of the BAT-AEL range for nickel to 0.5 mg/l. According to
Commission Implementing Decision 2012/119/EU (Section 3.3), rounded values can
be set as BAT-AELs to take into account limitations in the data collection or other
technical aspects. (DE 366).
Lower the upper end of the BAT-AEL range to 0.08 mg/l and add a footnote
mentioning that the upper end corresponds to the use of nickel-containing dyes.
Indeed, according to the collected data, around 70 % of the plants are below
0.08 mg/l. In addition, nickel is a Priority Substance. Finally, experience from
Austrian plants shows that 0.08 mg/l can be achieved by good chemical and water
management (see BAT 39-42). The plants with emission values > 0.05 mg/l do not
use abatement technologies such as reverse osmosis, ultrafiltration or microfiltration
(except Plant IT092_w(1)) (AT 9).
Change the BAT-AEL range to 0.005-0.05 mg/l to align it with the CWW BAT
conclusions. According to the data collected, reported values are well below 0.4 mg/l,
in most cases even below 0.05 mg/l. The higher reported values show very high error
bars and should not be included in the analysis (poor process control, few
measurements, poor measurement quality, erroneous measurement or sampling,
malfunction of the water treatment facility). Oekotex and ZDHC require maximum
emission levels of 0.2 mg/l (EEB 158, EEB 165).
Zinc (Zn)
Increase the upper end of the BAT-AEL range to 2 mg/l. The source of Zn emissions
is corrosion of pipes (DE 367, EURATEX 157).
Increase the lower end of the BAT-AEL range to 0.2 mg/l, because the lower limit
would be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS causes excessive costs (EURATEX 43).
Lower the lower end of the range to 0.02 mg/l (EEB 165). Lower the upper end of the
BAT-AEL range to 0.3 mg/l to align it with the CWW BAT conclusions. According
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
89
Background paper – Final meeting for the review of the TXT BREF
to the data collected, few data points are between 0.3 mg/l and 0.5 mg/l (EEB 159,
EEB 165).
Sulphide, easily released (S2-)
Change the BAT-AEL range to 0.1-0.5 mg/l. According to the data collected, plants
achieve lower values. There is only one plant (direct discharge) over 0.5 mg/l
(AT 11).
Change the BAT-AEL range to 0.05-0.2 mg/l. According to the data collected, a lot
of measurements are reported at the limit of detection. The ZDHC standard requires
0.01/0.05/0.5 mg/l for their three levels (EEB 160, EEB 165).
Total nitrogen (TN)
Lower the upper end of the BAT-AEL to 10 mg/l (EEB 161, EEB 165) or 15 mg/l
(SE 28). This would align the upper end of the BAT-AEL with an ecosystem-
dependent condition as in the Directive on urban waste water treatment (91/271/EC).
According to the data collected, the upper end could be lowered (SE 28, EEB 161,
EEB 165).
Footnote (5)
Set an upper end of the BAT-AEL range for cold conditions.(EEB 187).
Specify “prolonged” in Footnote (5), because on an average day the temperature of
20 % of the waste water collected over one day is equal to or below 12 °C (AT 41).
Total organic carbon (TOC)
Change the BAT-AEL range to 10-30 mg/l. The collected data for TOC show lower
values and only a few plants are above 30 mg/l (AT 5).
Lower the upper end of the BAT-AEL range to 30 mg/l, because this is supported by
the data collection (SE 28).
Keep the BAT-AEL range as proposed (EEB 162, EEB 165).
Footnote (6)
Modify the footnote allowing a higher upper end of the BAT-AEL for TOC up to 50
mg/l for waste waters with a high TOC content in the influent if the removal
efficiency of the WWTP is at least 90 %. Define the high TOC content in the influent
(DE 369).
Decrease the upper end of the range in Footnote (6) to 40 mg/l if the removal
efficiency is at least 90 %. Indeed, exemption should rather be linked to removal
efficiency because Table 5.1 (BAT-AEPLs for specific water consumption) shows
that for batch processes the specific water consumption ranges are above 25 m3/t
treated textile materials; and for continuous processes below 25 m3/t treated textile
materials. The strong variation of water consumption data shows that it is not
appropriate to use water consumption as the basis for an exemption. Also, the
proposed threshold is hard for the authorities to control (AT 6).
Total phosphorus (TP)
Lower the upper end of the BAT-AEL range to 2 mg/l. Only data sets for plants with
direct discharge using BATs for phosphorus removal should be used for setting a
BAT-AEL (BE 22, DE 368).
Increase the upper-end of the BAT AEL range to 10 mg/l. Add another BAT-AEL
range for flame-retardant treatments using phosphorus compounds (FR_B 8).
Do not consider organophosphates when evaluating Total phosphorus.
Organophosphorus flame retardants are persistent but not bioaccumulative or toxic.
This organic phosphorus does not contribute to the eutrophication of surface water.
Actions regarding pad liquors and highly concentrated rinsing water are taken by
plants to avoid excess of discharge (EURATEX 44).
Modify the BAT-AEL range to 0.01-2 mg/l. The collected data show lower values.
Total phosphorus is easy to precipitate. Such an upper end of the BAT-AEL range
was set in the FDM BAT conclusions (AT 13).
Modify the BAT-AEL range to 0.1-3 mg/l and add a footnote that for the plants
discharging into eutrophication-sensitive areas the upper end of the range is 1 mg/l or
2 mg/l (depending on size) as set by the UWWTD. Finally, the certification scheme
ZDHC as well as the CWW BAT conclusions have emission limit values at 3 mg/l
90
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
(EEB 163, EEB 165). Lower the upper end of the BAT-AEL range to 2 mg/l.
According to the data collected and the UWWTD, the upper end could be lowered
(SE 28).
Total suspended solids (TSS)
Lower the upper end of the BAT-AEL range to 35 mg/l to align with the CWW
BREF. These solids can have metals and metalloids associated with them and can
therefore pose a significant threat to downstream ecology (EEB 164, EEB 165,
UK 23).
Lower the upper end of the BAT-AEL range to 35 mg/l. According to the data
collected and the UWWTD, the upper end could be lowered (SE 28).
General comments
To derive the BAT-AELs for direct discharges, the data reported for direct discharges
have been taken into consideration. However, in the case of sulphides and metals, the
indirect discharges were additionally considered to confirm the assessment. For
details, see the corresponding assessments for parameters below.
According to Section 8.1.1 of the KoM conclusions, the BAT-AELs for emissions to
water are expressed in concentrations, and not in loads.
The proposed BAT-AELs are based on the emission data sets related to the treatment
techniques applied by the different TXT installations. Additional contextual
information like use of raw materials, processes, chemicals and auxiliaries used are
taken into consideration.
Furthermore, a 2nd Data Assessment Workshop was organised in October 2020, in
order to clarify the approach used by the EIPPCB to derive the BAT-AE(P)Ls
proposed in D1, and to discuss the data situation in relation to the BAT-AE(P)Ls
proposed in D1.
The comments from that workshop and additional information provided after it have
been taken into account to formulate the EIPPCB assessments and proposals in this
background paper.
Additional parameters
According to the KoM conclusions, the data on BODn emissions were to be collected
as contextual information, but it was decided not to propose a BAT-AEL for this
parameter. However, BODn indicative emission levels related to COD/TOC BAT-
AELs could be set (e.g. in a footnote to the table) to indicate the abatement efficiency
EIPPCB
of the well-performing biological waste water treatment (e.g. also for checking non-
assessment:
biodegradability of effluent with BOD to COD ratio).
According to the KoM conclusions, data were to be collected for the TWG to decide
at a later stage, based on their availability and comparability, to potentially set a
BAT-AEL for colour. In the data collection, 35 data sets (from 16 emission points, 6
direct / 10 indirect discharge) were reported for colour, 3 reported in units of Pt-Co
scale, 10 in SAC (m-1), 3 in mg/l Pt and 19 reported measurements or ELVs but no
unit (of these, 16 seem to be reporting a dilution factor of 1:20). Data obtained with
different methods do not seem to be comparable. The colour parameter seems to be
qualitative and operational parameter that is measured (e.g. daily) to control the
operation of waste water treatment. Similarly to biodegradability or toxicity for
example, the requirements for monitoring of this parameter are set in BAT 7;
however, setting a BAT-AEL does not seem to be necessary or practical.
According to the KoM conclusions, the data on Total N emissions were to be
collected to set a BAT-AEL. Ammonium nitrogen (NH4-N) was considered to be
included in the Total N. In accordance with the practice of the recent BAT
conclusions, BAT-AELs and monitoring for total nitrogen (TN) are proposed, as this
parameter better reflects the eutrophication potential.
According to the KoM conclusions, data were to be collected for the TWG to decide
at a later stage, based on their availability and comparability, to potentially set a
BAT-AEL for toxicity. As presented in Section 3.4.18 of D1 of the TXT BREF, the
availability and comparability of data was insufficient to set a BAT-AEL for this
parameter.
Regarding nonylphenol, 8 out of 15 emission points to water reported using the
standard method for nonylphenol. Except BE014_{1} who reported WAC/IV/A/01-
05, UNI EN ISO 18857 is the standard method reported for the other 7 emission
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
91
Background paper – Final meeting for the review of the TXT BREF
points to water.
o Of those emission points that reported using the standard method for
nonylphenol, 4 emission points to water (i.e. IT064_{1}, IT071_{1},
IT089_{1} and IT090_{1}) reported the same concentration value of
0.2 µg/l, while the maximum concentration range obtained for the other 4
emission points to water goes from 1.3 µg/l to 20 µg/l.
o The working range set for nonylphenol in UNI EN ISO 18857-2 is 0.5 µg/l
to 50 µg/l.
Taking into account the above information, it seems there are not enough comparable
data available to set a BAT-AEL for nonylphenol of 0.2-5 µg/l.
Regarding DecaBDE, 5 emission points to water reported measured values. 2 out of 5
provide information about the standard method used (i.e. AT004_{1} and
BE011_{1}).
o AT004_{1} reported EPA 8270 and BE011_{1} reported WAC/IV/A/030.
Both methods use Gas Chromatography/Mass Spectrometry (GC-MS).
o AT004_{1} reported 5 measurements, all carried out in 2015 within a range
from 0.46 µg/l to 52 µg/l, while BE011_{1} reported one measurement done
in 2017 of 0.18 µg/l.
Taking into account the above information, it seems there are not enough comparable
data available to set a BAT-AEL for DecaBDE of 1-20 µg/l.
Regarding the BAT-AEL range for the sum of PFOA and PFOS, taking into account
the data collection, 10 emission points to water reported measured values for PFOA,
6 emission points to water reported measured values for PFOS, and DE031_{1}
reported measured values for PFOS:PFOA.
o 4 out of 10 emission points to water reported the standard method used for
PFOA. BE011_{1} and BE014_{1} use Liquid Chromatography with
tandem mass spectrometry (LC-MS-MS); IT092_{1} and IT097_{1}
reported MI1207 rev2:2018. The range of the maximum values reported by
the 4 emission points to water mentioned goes from 13 µg/l to 41 µg/l.
o 1 out of 6 emission points to water reported the standard method used for
PFOS. BE014_{1} uses Liquid Chromatography with tandem mass
spectrometry (LC-MS-MS), and reported 1 measurement, done in 2016, of
0.5 µg/l.
Taking into account the above information, it seems there are not enough comparable
data available to set a BAT-AEL for the sum of PFOA and PFOS of 1-3 µg/l.
Adsorbable organically bound halogens (AOX)
The statistical approach (percentiles) or environmental quality standards are not used
to derive BAT-AELs.
Regarding the proposals to increase the upper end of the BAT-AEL range:
o Due to dyeing of polyester and blends of modacryl/cotton, the relevant
emission points for direct discharge are CZ020_{1}, BE014_{2},
DE025_{1}, FR131_{2} and FR134_{1}. It is not clear how the upper end
could be raised to 1 mg/l, since the highest reported value is 0.86 mg/l
(FR134_{1}).
o If dyeing with vat, metal-complex and reactive dyes is assumed to represent
the category of ‘dyeing products with high lightfastness, and high quality
demands’, the emission points for direct discharge reporting dyeing with
these dyes are BE011_{1}, FR131_{1} and FR134_{1}, with maximum
concentrations of 0.38 mg/l, 0.41 mg/l and 0.86 mg/l. The average
concentration for the one reporting the highest value (FR134_{1}) is
0.3 mg/l; therefore, it seems that the proposed upper end of the range is
mostly respected by all relevant plants.
Regarding the proposals to lower the upper end of the BAT-AEL range:
o
The BAT-AELs are not derived on the basis of certification schemes.
o
The collected data for direct discharges in some cases indicate high
fluctuations in AOX concentrations. Minimal, average and maximal
concentrations for BE011_{1} are 0.08 mg/l, 0.17 mg/l and 0.38 mg/l, for
FR131_{1} 0.02 mg/l, 0.13 mg/l and 0.41 mg/l, for FR132_{2} 0.02 mg/l,
0.2 mg/l and 0.66 mg/l, and for FR134_{1} 0.06 mg/l, 0.3 mg/l and
0.86 mg/l. All plants use activated sludge, but only BE011 also uses sand
filtration, chemical oxidation and coagulation/flocculation which would
92
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
remove AOX. These fluctuations seem to be limited to only a few
measurements/events, with the majority being well below 0.4 mg/l.
Therefore, the upper end of the range for direct discharge could be decreased
to 0.4 mg/l.
Chemical oxygen demand (COD)
Two emission points to water reported maximum concentration values between
100 mg/l and 120 mg/l, i.e. IT067_{1} and FR132_{2}:
o IT067_{1} monitored COD with a monthly frequency and reported 37
values over 3 years with a range of 24 mg/l to 108 mg/l. The maximum
value reported is 108 mg/l, slightly above 100 mg/l.
o FR132_{2} monitored COD with a daily frequency and reported 12 values
for 2016 in the range 52 mg/l to 105 mg/l, and 12 values for 2017 in the
range 97 mg/l to 115 mg/l.
Taking into account the values reported by IT067_{1} and FR132_{2}, there is scope
for lowering the upper end of the BAT-AEL range.
BAT-AELs set in the CWW BAT conclusions for COD refer to a yearly average,
while in TXT D1 the proposed BAT-AELs refer to daily average values, in the case
of continuous discharge, or, in the case of batch discharge, average values over the
release duration taken as flow-proportional composite samples, or, provided that the
effluent is appropriately mixed and homogeneous, a spot sample taken before
discharge, as described in the definition of BAT-AELs for emissions to water in the
General considerations section of the BAT conclusions. Both values are therefore not
directly comparable.
Furthermore, to decrease the lower end of the range to 30 mg/l, there are no data
reported in the data collection with a maximum concentration value for COD below
30 mg/l.
The BAT-AELs are not derived using a statistical approach. The fact that 5 out of 24
of the emission points to water reported a maximum emission level higher than the
proposed higher end of the BAT-AEL range is not per se a reason for increasing the
higher end of the range. Technical reasons explaining why the proposed upper end of
the BAT-AEL range could not be achieved are not provided.
Footnote (4)
In the data collection, only one emission point to water, CZ020)_w{1}, reported
information about the removal efficiency for COD direct discharge. The COD content
in the influent for CZ020)_w{1} is around 127 mg/l, obtained by the calculation
using the maximum concentration value for COD reported (65 mg/l), and the removal
efficiency (95 %).
After the 2nd Data Assessment Workshop held on 21-23 October 2020, more
information about the removal efficiency was provided by EURATEX, France and
Sweden:
o EURATEX provided information for three Belgian plants, two of them
participated in the data collection (i.e. BE009 and BE010) and the third one
was not included in the data collection for the TXT BREF review,
o In the case of BE009, the range of the reported values were for COD influent
from 393 mg/l to 1870 mg/l and for COD effluent from 50 mg/l to 353 mg/l,
with a removal efficiency ranging from 55 % to 96 %. In the case of a
removal efficiency equal to or higher than 90%, the highest COD
concentration reported is 124 mg/l.
o In the case of BE010, the range of the reported values were for COD influent
from 351 mg/l to 1600 mg/l and for COD effluent from 31 mg/l to 128 mg/l,
with a removal efficiency ranging from 79 % to 96 %. In the case of a
removal efficiency equal to or higher than 90 %, the highest COD
concentration reported is 110 mg/l.
o In the case of the third plant which did not participate in the data collection,
the values reported were: COD influent 1200 mg/l and COD effluent
49 mg/l, with a removal efficiency of 96 %.
o France provided information about the daily removal efficiency for the
emission point FR131_w{1} for a complete year from December 2019 to
November 2020. The average value reported for COD influent was
3811 mg/l and for COD effluent 122 mg/l, with a removal efficiency of 97
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
93
Background paper – Final meeting for the review of the TXT BREF
%.
o Sweden provided information about the COD removal efficiency achieved in
the waste water treatment plant called Skene. This plant received the waste
water discharge from four textile-dyeing installations. The COD removal
efficiency reported is in the range of 90-95 %.
Taking into account the above information about removal efficiency, it is not possible
to propose a footnote based on removal efficiency to increase the upper end of the
BAT-AEL range up to 150 mg/l, 160 mg/l or 250 mg/l, as in the information provided
for CZ020)_w{1}, BE010 and FR131_w{1} the COD effluent concentration
corresponding to a removal efficiency of at least 90 % is below 150 mg/l.
Footnote (4) refers to specific waste water discharged, not to specific waste water
consumption. This can be further clarified in the footnote.
Biodegradability of waste water is addressed in BAT 18. It does not appear necessary
to repeat it in Table 5.3.
Hydrocarbon oil index (HOI)
It is considered appropriate to add Footnote (2), as oils in waste water may not
originate from all processes (i.e. typically from washing synthetic fibres and knitting)
or fibres (i.e. typically from synthetic fibres and knitted fabrics).
Only three emission points (IT092_{1}, IT097_{1} and BE007_{1}) reported
concentration values of HOI for direct discharges, with a range from 0.03 mg/l to
0.93 mg/l. The associated processes of these emission points do not seem typical
sources of emissions of oils. However, oils may enter the processes (and effluents)
with incoming textile materials (e.g. for these three plants: polyamide or polyester
fibres, knitted fabrics). All three plants use an appropriate combination of treatment
techniques (e.g. neutralisation, equalisation, activated sludge and sedimentation);
furthermore, two plants also use techniques that would effectively remove oils (i.e.
sand filtration (BE007) and reverse osmosis (IT092)).
Based on these three data sets, less than 1 mg/l seems to be an appropriate BAT-AEL.
However, it seems more representative (due to more typical processes, sources and
materials related to oil emissions) to also include in the BAT-AEL derivation data
reported for indirect discharges (e.g. 30 data sets), especially if the plants use
appropriate abatement techniques. For example, taking data from these three data sets
into account would support decreasing the upper end of the BAT-AEL range for
direct and indirect discharge to 7 mg/l: PT108_{1} (maximum concentration 4 mg/l;
fabric production processes and knitted fabrics; using sand filtration), PT104_{1}
(average/maximum concentrations 2.5 mg/l/7 mg/l; knitted fabrics, ultrafiltration) and
PT114_{1} (average/maximum concentrations 6.7 mg/l/10 mg/l; washing synthetic
fibre, adsorption, sedimentation, sand filtration). .
Metals / metalloids
It is considered appropriate and consistent with BAT 2 and BAT 7 to add Footnote (2)
to metals for which any specific process is mentioned.
Antimony (Sb)
BAT-AELs are not derived based on a statistical approach, and, despite rounded
values having already been set as BAT-AELs according to Commission
Implementing Decision 2012/119/EU, it is not clear on which reported data the
rounded value would be based.
Regarding the comments received for increasing/lowering the range:
o For direct emissions: IT097_{1} reported two values (only in 2018),
0.01 mg/l and 0.5 mg/l (which is in fact the detection limit of the monitoring
method referred to). All of the other five EPs reported values < 0.2 mg/l,
whatever the process or the type of textile fibre used.
o For indirect emissions: three EPs reported values higher than the upper end
of the range of the BAT-AEL proposal in D1: DE051_{1}, DE022_{1} and
SE120_{1}:
SE120_{1} reported the highest value, 1.1 mg/l, and the monitoring
is based on a continuous flow-proportional sampling and the value
represents a whole month and is used together with the flow to
calculate the emissions in kg/year, so this is not directly
comparable.
94
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
DE022_{1}: the monitoring frequency is monthly and this EP
reported a value above the BAT-AEL proposal once, 0.7 mg/l in
2016, while the emission limit value prescribed by the competent
authority in the permit is 0.4 mg/l.
DE051_{1}: the monitoring frequency is monthly and this EP
reported a value above the BAT-AEL proposal once, 0.44 mg/l in
2016.
In addition to the EPs mentioned above, SE119_{1} reported a
value of 0.35 mg/l in 2018 and is not using abatement technique.
Based on this analysis for both direct and indirect emissions, there is scope to lower
the upper end of the BAT-AEL range for both direct and indirect emissions.
Chromium (Cr)
BAT-AELs are derived from the data collection; they are not based on environmental
quality standards referring to the quality of water.
It is not technically clear why it is necessary to set rounded values for increasing the
upper end of the BAT-AEL range.
Regarding the proposal for lowering the upper end of the range, the assessment has
been done for both direct and indirect emissions:
o Among the plants that have reported direct emissions of chromium to water,
there are 6 emission points to water with maximum values higher than
0.1 mg/l: PT111_{1}, PT098_{1}, IT067_{1}, BE007_{1}, BE009_{1}
and BE014_{1}. Taking into account the values based on a standard
monitoring method and considering the number of values reported above
0.1 mg/l versus the number of all the values reported by each EP, the
majority of the values are below 0.1 mg/l.
o Regarding indirect emissions, IT84_{1} is applying coagulation,
flocculation and sedimentation and once reported 0.13 mg/l while the 11
other values are below 0.03 mg/l. All the other emission points reporting
values higher than 0.1 mg/l are not using a relevant abatement technique.
o According to the above data points, there is scope to lower the upper end of
BAT-AEL range.
Copper (Cu)
BAT-AELs are derived from the data collection; they are not based on environmental
quality standards referring to the quality of water.
Despite rounded values having already been set as BAT-AELs according to
Commission Implementing Decision 2012/119/EU, it is not clear on which reported
data the rounded value would be based.
As similar comments have been received for both direct and indirect emissions, the
assessment is presented in this section. According to Section 2.7.2 of D1, high
lightfastness is ensured by the use of vat dyes or metal-complex dyes. In addition,
according to Section 3.4.9.2 of D1, reactive dyes may contain copper too. This could
be reflected in the processes/activities concerned.
Regarding the comments received to increase the upper end of the range:
o Plants using vat dyes reported data from 0.02 mg/l to 0.79 mg/l.
IT071_w{2} and IT072_w{1} reported values higher than the BAT-AEL
proposal in D1 but they are not applying any technique to reduce the Cu
concentration.
o 6 plants using metal-complex dyes reported values higher than the BAT-
AEL proposal in D1 but they are not applying any technique to reduce the
Cu concentration.
o Among the 75 plants that have reported Cu emissions and using reactive
dyes, 8 reported values higher than the BAT-AEL proposal in D1. 7 are not
applying any technique to reduce the Cu concentration. SE120_{1} reported
the highest value, 1.5 mg/l, and is not using techniques such as reverse
osmosis, nanofiltration or microfiltration.
o Based on this information, there is no scope to increase the upper end of the
BAT-AEL range.
Regarding the comments received to decrease the upper end of the range, the BAT-
AELs are not derived on the basis of a statistical approach and it is not technically
clear why it is necessary to add a footnote for plants using the dyes listed above and
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
95
Background paper – Final meeting for the review of the TXT BREF
that have reported values lower than 0.4 mg/l.
Nickel (Ni)
BAT-AELs are derived from the data collection; they are not based on environmental
quality standards referring to the quality of water.
Despite rounded values having already been set as BAT AELs according to
Commission Implementing Decision 2012/119/EU, it is not clear on which reported
data the rounded value would be based.
As similar comments have been received for both direct and indirect emissions, the
assessment is presented in this section. Regarding the comments received for
lowering the upper end of the range, 13 EPs reported values higher than 0.09 mg/l, for
both direct and indirect emissions of Ni:
o 3 EPs are not using any techniques: IT071_w{1}, PT105_w{1} and
PT102_w{1}. PT113_w{1} implements only a screening technique.
o PT111_w{1} reported a yearly value, 0.5 mg/l without referring to a
standard monitoring method twice, and then reported 0.01 mg/l referring to a
standard monitoring method.
o FR134_w{1} monitored Ni 4 times a year and reported 0.19 mg/l once while
3 other values are below 0.083 mg/l and 8 values below 0.01 mg/l.
o In IT092_w{1} Ni is monitored monthly, the highest value (1 mg/l) has been
reported once but all the other values are below 0.1 mg/l.
o BE009_w{1} reported 0.09 mg/l as the highest value, and both IT092_w{1}
and BE009_w{1} use reverse osmosis.
o All the other EPs use techniques that are not relevant for the abatement of Ni
emissions.
o According to the above points, there is scope to lower the upper end of
BAT-AEL range.
According to Section 3.4.9.3 of D1, reactive dyes may contain metals such as nickel,
and this could be reflected in the processes/activities concerned. It is not clear why it
is necessary to add a footnote corresponding to the use of nickel-containing dyes, as
most of the plants that have reported data on nickel emissions and implementing
reactive dying achieve below 0.08 mg/l.
As described in the definition of BAT-AELs for emissions to water in the General
considerations section of the BAT conclusions, BAT-AELs set in the CWW BAT
conclusions for nickel refer to a yearly average, while in TXT D1 the proposed BAT-
AELs refer to:
o daily average values in the case of continuous discharge;
o average values over the release duration taken as flow-proportional
composite samples, or a spot sample taken before discharge (provided that
the effluent is appropriately mixed and homogeneous), in the case of batch
discharge.
Both values (CWW and TXT) are therefore not directly comparable.
Zinc (Zn)
BAT-AELs are derived from the data collection; they are not based on environmental
quality standards referring to the quality of water.
Regarding the comment received on increasing the upper end of the range, the
assessment has been done considering both direct and indirect discharges. Based on
the inputs following the 2nd data workshop, it has not been confirmed that pipes are a
source of zinc emissions to water. Instead, several sources of zinc emissions have
been mentioned, e.g. yarns of mass-coloured acrylic fibres, use of cationic dyes,
bleaching with the dithionite process, and cellulose fibres (regenerated cellulose
fibres, and zinc salts used in the production process).
o The maximum reported concentration of zinc for direct emissions to water is
0.5 mg/l whatever the process.
o Regarding data reported for indirect emissions: 29 EPs reported values
higher than the upper end of the BAT-AEL range proposed in D1, including
18 EPs not using any techniques to reduce water pollution. Among the 11
remaining EPs and comparing the processes and types of fibres used:
DE042_w{1} and IT087_w{1} both report batch cationic dyeing
and are applying only equalisation (while all EPs reporting values
for direct emissions are compliant with the BAT-AEL range
96
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
proposal);
SE120_w{1} is the only EP reporting bleaching with the dithionite
process, and reported 1.7 mg/l for Zn emissions while the Emission
Limit Value is 0.5 mg/l;
IT087_w{1} reported a value of 0.7 mg/l and the use of viscose
(while PT098_w{1} reported values for direct emissions compliant
with the BAT-AEL range proposal).
o It is therefore not clear why the upper end of the BAT-AEL range should be
increased to 2 mg/l.
As described in the definition of BAT-AELs for emissions to water in the General
considerations section of the BAT conclusions, BAT-AELs set in the CWW BAT
conclusions for zinc refer to a yearly average, while in TXT D1 the proposed BAT-
AELs refer to:
o daily average values in the case of continuous discharge;
o average values over the release duration taken as flow-proportional
composite samples, or a spot sample taken before discharge (provided that
the effluent is appropriately mixed and homogeneous), in the case of batch
discharge.
o Both values (CWW and TXT) are therefore not directly comparable.
Sulphide, easily released (S2-)
According to the data collection, 3 emission points to water reported values for
sulphide for direct discharge (i.e. IT067_{1}, IT092_{1} and IT097_{1}). The
concentration values reported by these emission points were close to or below the
detection limit. Maybe these plants are not using sulphur dyes. In that case, the
concentration values reported for indirect discharges were additionally considered to
confirm the proposed higher end of the BAT-AEL range.
Regarding the lower end of the range, there are not emission points to water reporting
a value of 0.3 mg/l in the data collection, while there are 7 emission points to water
(e.g. ES058_{1}, DE024_{1}, IT067_{1}) achieving lower concentration values than
0.3 mg/l and using similar techniques to those reported for other emission points.
According to these values, there is scope for lowering the upper end of the BAT-AEL
range.
BAT-AELs are set based on emission data collected through the questionnaires from
the plants using BAT. BAT-AELs are not based on other standards (e.g. ZDHC).
Total nitrogen (TN)
There are three emission points to water (IT092_w{1}, IT097_w{1} and
BE010_w{1}), using nitrification/denitrification treatment, with reported maximum
values between 10 mg/l and 20 mg/l:
o IT092_w{1} reported one concentration value for TN (17.1 mg/l), while
IT097_w{1} reported two values, 6.0 mg/l and 18.5 mg/l.
o BE010_w{1} reported a minimum of four concentration values per year,
giving more representativeness to the data series reported. Figure 3.28 in D1
shows that the difference between its maximum and average concentration is
more than double.
According to the above points, and looking in detail at all the reported concentration
values and using nitrification/denitrification treatment, there is scope to lower the
upper end of BAT-AEL range.
Footnote (5)
There is only one data set for direct discharge, using nitrification/denitrification and
an appropriate monitoring standard, that reported the effluent temperature data
(BE014). This does not seem a broad basis to set the upper end of the BAT-AEL
proposal for cold conditions.
It seems better for implementation not to specify what is meant by “prolonged” due to
possible different approaches originating from local climatological and environmental
conditions, which are best captured by the competent authority. Additionally, the data
collection was not designed to provide any information on this issue.
Total organic carbon (TOC)
A total of 2 out of 9 emission points to water reported maximum concentration values
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
97
Background paper – Final meeting for the review of the TXT BREF
between 30 mg/l and 40 mg/l, i.e. BE014_w{1} and BE007_w{1}:
o BE014_w{1} reported 4 measurements, all done during the year 2018. The
range of the values was from 20 mg/l to 31 mg/l. For the same year, the
concentration of COD ranges from 44 mg/l to 74 mg/l, below the proposed
BAT-AEL for COD.
o BE007_w{1} reported 12 measurements for 2016, with two measurements
above 30 mg/l (i.e. 32 mg/l and 35 mg/l), and an average value of 24 mg/l in
2016. 11 measurements were reported in 2017, with one value above
30 mg/l (i.e. 35 mg/l), and an average value of 24 mg/l. No values were
reported in 2018.
o Both emission points are equipped with equalisation, activated sludge and a
membrane bioreactor, and seem to be able to achieve lower values than the
maximum reported values.
In addition to the above bullet points, taking into account the assessment done for
COD, there is scope for lowering the upper end of the BAT-AEL range.
Two emission points to water reported concentration values for TOC close to 10 mg/l,
i.e. IT092_w{1} and IT097_w{1}. Both only reported one measurement.
The proposed lower end of the range is considered appropriate in order to maintain
the empirical analogy between COD and TOC of 3:1.
Footnote (6)
No information was submitted about the removal efficiency for TOC direct discharge,
and it is not possible to propose a footnote based on the removal efficiency without
information.
Footnote (6) refers to waste water discharged, not to specific waste water
consumption. This can be further clarified in the footnote.
Total phosphorus (TP)
Regarding the comments to decrease the upper end of the BAT-AEL range (e.g. to
2 mg/l or 3 mg/l):
o Concentrations of Total P for direct discharge were reported for 6 emission
points (DE025_{1}, CZ020_{1}, BE009_{1} and {2}, BE010_{1},
BE011_{1}). All reported using appropriate monitoring standards and
abatement techniques (i.e. apart from BE010 which uses precipitation with
FeCl3, all others use coagulation/flocculation). Their maximal concentrations
are between 0.47 mg/l and 1.7 mg/l, except for BE009_{1} which reports a
maximum concentration of 15 mg/l and average of 1.67 mg/l. The data
support lowering the upper end of the BAT-AEL range to 2 mg/l.
o The BAT-AELs are set on collected data and not on other BAT conclusions
(e.g. FDM), voluntary schemes (e.g. ZDHC) or other EU regulations (i.e. the
IED and BAT conclusions are without prejudice to the Urban Waste Water
Treatment Directive).
Regarding the comments to increase the upper end of the BAT-AEL range (e.g. to 10
mg/l):
o Total P concentrations were reported for 6 emission points (DE022_{1},
DE025_{1}, FR136_{1}, SE118_{1}, SE119 {1}, UK127{1}) from plants
using organophosphorus flame retardants. DE022 is discharging directly,
others indirectly. DE022 is also the only one reporting the use of abatement
techniques that would partially remove organophosphates (activated sludge,
coagulation/flocculation and sedimentation); other plants use only
preliminary or primary treatment (oil/grit separation, neutralisation,
equalisation) which is not appropriate for the removal of organophosphates.
The maximum concentration reported from DE022 is 0.5 mg/l, while the
maximum concentrations for other plants (indirect discharge and no
appropriate abatement) range from 5.1 mg/l (SE119) to 45 mg/l (FR136).
SE119 segregates spent finishing liquors of organophosphate flame
retardants and removes them as waste, preventing them from entering
common effluent.
o It is not clear why plants using organophosphate flame retardants could not
apply appropriate abatement techniques to reach the proposed BAT-AEL
range (e.g. like DE022).
Regarding the comments to decrease the lower end of the BAT-AEL range (e.g. to
98
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
0.01 mg/l or 0.1 mg/l): the lowest complete data set (e.g. reporting using monitoring
standards and abatement techniques), DE025, reported a maximum concentration of
0.5 mg/l. Therefore, the data do not support decreasing the lower end of the BAT-
AEL range to 0.1 mg/l or less.
Total suspended solids (TSS)
Among the plants that have reported emissions of TSS to water, there are four
emission points to water with maximum values between 35 mg/l and 45 mg/l, i.e.
UK124_w{1}, IT092_w{1}, PT098_w{1} and DE025_w{1}:
o UK124_w{1} reported more than 80 measurements per year, with an
average value around 8 mg/l, while the three maximum concentration values
achieved in 2016, 2017 and 2018 were 21.7 mg/l, 37.7 mg/l and 30.4 mg/l,
respectively.
o IT092_w{1} reported 12 measurements per year within a range from 2 mg/l
to 39.2 mg/l. 3 out of 36 measurements were above 30 mg/l, achieving an
average value over the 3 reporting years of 10 mg/l.
o PT098_w{1} monitored TSS twice per year. The range of the first
measurement reported each year was from 33 mg/l to 42 mg/l, while the
range of the second measurement reported each year was from 10 mg/l to
18 mg/l.
o DE025_w{1} monitored TSS with a monthly frequency, and has an ELV for
TSS of 35 mg/l. 2 out of 33 measurements reported are above the ELV,
while the other measurements are below 24 mg/l.
Taking into account the measurements detailed in the above bullet points and that all
of the named emission points to water apply at least one of the specific techniques to
remove solids, e.g. coagulation/flocculation, sedimentation, filtration or flotation, it
seems that the indicated emission points to water are capable of achieving low
emission levels.
Additional parameters
No change for nonylphenol, DecaBDE and Sum of PFOA and PFOS.
To add new footnote associated with indicative emissions levels for BOD related to
COD and TOC BAT-AELs.
Adsorbable organically bound halogens (AOX)
To decrease the upper end of the BAT-AEL.
Chemical oxygen demand (COD)
To decrease the upper end of the BAT-AEL
Footnote (4)
To amend the text to clarify which unit Footnote (4) refers to.
Hydrocarbon oil index (HOI)
EIPPCB
To add Footnote (2).
proposal:
To decrease the upper end of the BAT-AEL.
Metals / metalloids
Antimony (Sb)
To decrease the upper end of the BAT-AEL.
Chromium (Cr)
To decrease the upper end of the BAT-AEL.
Copper (Cu)
To change activities/processes to dyeing/printing.
Nickel (Ni)
To change activities/processes to dyeing/printing.
To decrease the upper end of the BAT-AEL.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
99
link to page 24
Background paper – Final meeting for the review of the TXT BREF
Zinc (Zn)
To add footnote (2).
Sulphide, easily released (S2-)
To decrease the lower end of the BAT-AEL.
Total nitrogen (TN)
To decrease the upper end of the BAT-AEL.
Footnote (5)
No change.
Total organic carbon (TOC)
To decrease the upper end of the BAT-AEL.
Footnote (6)
To amend the text to clarify which unit Footnote (6) refers to.
Total phosphorus (TP)
To decrease the upper end of the BAT-AEL.
Total suspended solids (TSS)
To decrease the upper end of the BAT-AEL.
1.4.6.4
BAT-AELs for indirect discharges to a receiving water body
Location in
P. 735 – Section 5.1.6 – BAT 19 – Table 5.4
D1:
Table 5.4:
BAT-associated emission levels (BAT-AELs) for indirect discharges
to a receiving water body
BAT-AEL (1)
Substance/Parameter
Activities / processes
(2)
(mg/l)
Adsorbable organically bound halogens
All processes
0.1–0.5
(AOX) (3)
Hydrocarbon oil index (HOI)
All processes
1–10
Pre-treatment and/or
dyeing of polyester
Antimony (Sb)
Finishing with flame
0.1–0.4
retardants using
antimony trioxide
Current
Metals / metalloids
Dyeing with
text in D1:
Chromium (Cr)
chromium-containing
0.01–0.3
dyes
Copper (Cu)
All processes
0.03–0.4
Nickel (Ni)
All processes
0.01–0.5
Zinc (Zn)
All processes
0.04–0.5
Dyeing with sulphur
Sulphide, easily released (S2-)
0.3–1
dyes
(1) The averaging periods are defined in the general considerations.
(2) The BAT-AELs may not apply if the downstream waste water treatment plant is
designed and equipped appropriately to abate the pollutants concerned, provided this
does not lead to a higher level of pollution in the environment.
(3) The BAT-AELs only apply when the substance/parameter concerned is identified as
relevant in the waste water stream based on the inventory of inputs and outputs
mentioned in
0.
100
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 27
Background paper – Final meeting for the review of the TXT BREF
The associated monitoring is given in
0.
General comments
Express BAT-AELs as specific loads in kg/ton of treated textile or add an appropriate
expression/factor (× m3/t) for all BAT-AELs. Many important BATs reduce water
and energy consumption, simultaneously increasing the concentration of pollutants
(see also (SE 40)) (SE 27).
Indicate that indirect discharges are not to the receiving water body but into the sewer
(DE 372).
Merge Tables 5.3 and 5.4 into one and refer to Footnote (2), to clarify the
implementation in line with the provisions of the IED (Articles 14(1), 14(3) and
15(1)) (FR_A 16).
Adapt the table in line with the proposals made for Table 5.3 in comments EEB 152-
165 (EEB 188).
Add a further requirement for indirect discharges only, to design and agree a suitable
randomised sampling programme with the competent authority that covers the full
range of discharge conditions likely to be encountered at the installation (e.g. all of
the processing scenarios used during the course of a normal year of operations)
(UK 26).
Additional parameters
Set BAT AEL ranges for:
o COD < 3000 mg/l;
o TSS < 200 mg/l;
o Total N < 50 mg/l;
o Total P < 10 mg/l;
o TOC < 700 mg/l.
These parameters and BODx are important to control although the water is
treated in a municipal sewage treatment plant. The suggested levels are based on
Summary
the data collected and presented in D1 (SE 27).
of
Set a BAT-AEL range for colour for dyeing activities as 1/30 dissolution. This
comments:
parameter is important since it generates a high public response (ES 39).
Set a BAT-AEL range for nonylphenol to 0.0002-0.005 mg/l (= 0.2-5 µg/l).
Nonylphenol is a substance of environmental concern. There are 17 data sets for the
value of NP, of which 13 data sets are in the proposed BAT-AEL range. Emission
limit values for this parameter are set in some national regulations (e.g. in France
0.025 mg/l and in Belgium 0.00008 mg/l) (AT 16).
Set a BAT-AEL range for DecaBDE to 0.001-0.02 mg/l because DecaBDE is a
substance of environmental concern and should have an ELV where relevant. In
addition, there are 5 data sets for the value of DecaBDE. Finally, the use and
production of the substance has been prohibited by the EU POP Regulation
2019/1021 since 2019 (AT 18).
Set a BAT-AEL range for Sum of PFOA and PFOS to 0.001-0.003 mg/l because
PFOA and PFOS are substances of environmental concern. There are 8 data sets for
PFOA and 7 data sets for PFOS. In 2019, PFOA and its salts were listed in category
A (Elimination) in the Stockholm Convention on Persistent Organic Pollutants (entry
into force: December 2020). In the EU, the production, placing on the market and use
of PFOA its salts and polymers have been restricted in Annex XVII to REACH since
2017 (AT 20).
Adsorbable organically bound halogens (AOX)
Increase the upper end of the BAT-AEL range to 1 mg/l. The proposed upper end
corresponds to the 60th percentile value of the maximum measurements According to
the data collection, the companies with specific activities (dyeing of PES, PES/CO,
etc.) report a 90th percentile of the average values corresponding to 1 mg/l. Moreover,
1 mg/l is also 10 times the environmental quality standard (EURATEX 45,
CEFIC 22).
If Hercosett is considered BAT, add a footnote “In case of antifelting treatment of
wool with the Hercosett process, the upper end of BAT-AEL 2.5 mg/l applies.” There
are three installations in Europe that use the Hercosett process in order to increase the
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
101
Background paper – Final meeting for the review of the TXT BREF
antifelting qualities of wool. The process has been approved since 60 years ago and is
still demanded by customers who do not want any change in quality. If Hercosett is
considered BAT, then a footnote for a BAT-AEL for indirect discharge is needed,
because – unlike direct discharge – PAC and GAC filtration would not be considered
BAT (AT 49).
Some of the data sets reported are very low (near the limit of detection) and do not
seem to be credible enough to be used to set BAT AELs (UK 24).
Hydrocarbon oil index (HOI)
Add Footnote (3) to this parameter (DE 200).
AT supports the proposed BAT-AEL range (AT 48).
Some of the data sets reported are very low (near the limit of detection) and do not
seem to be credible enough to be used to set BAT-AELs (UK 24).
Metals / metalloids
Lower the upper end of the BAT-AEL range for all metals/metalloids to 0.2 mg/l.
BAT for indirect discharges is to remove metals on site with suitable pretreatment
(e.g. precipitation, solids removal) (BE 21).
Add Footnote (3) to this group of parameters (DE 201).
Same proposals as for parameters in Table 5.3 (DE 373).
Antimony (Sb)
Increase the upper end of the BAT-AEL range to 0.6 mg/l. It corresponds to the 90th
percentile of the values in the data collection. A higher value should be considered for
the combination of both processes (EURATEX 47).
Increase the upper end of the BAT-AEL range to 1.2 mg/l for polyester and
modacryl/cotton dyeing. Companies with these processes have higher concentrations
of Sb, e.g. according to the data collected 1.0 mg/l (80th percentile) and 1.2 mg/l (90th
percentile). The proposed upper limit does not take into account the majority of well-
performing plants (EURATEX 48).
Lower the upper end of the BAT-AEL range to 0.2 mg/l. The collected data show that
around 65 % of the plants are below 0.2 mg/l. In addition, experience from Austrian
plants shows that lower values can be achieved by good chemical and water
management (e.g. see BAT 49). Finally, lower values can be achieved with abatement
techniques nanofiltration, microfiltration, ultrafiltration, prevention measures
(separate disposal of chemicals) and precipitation. According to national waste water
legislation (AT Textile and AT Glas), 0.3 mg/l Sb is achieved with prevention
measures (separate disposal of chemicals) and precipitation (AT 47)
Some of the data sets reported are very low (near the limit of detection) and do not
seem to be credible enough to be used to set BAT-AELs (UK 24).
Chromium (Cr)
Increase the lower end of the BAT-AEL range to 0.05 mg/l, because the lower limit
should be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS would cause excessive costs
(EURATEX 46).
Copper (Cu)
Increase the lower end of the BAT-AEL range to 0.05 mg/l, because the lower limit
should be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS would cause excessive costs
(EURATEX 46).
Lower the upper end of BAT-AEL range to 0.2 mg/l. Add a footnote that, in the case
of increased lightfastness requirements (i.e. use of copper-containing dyes), the upper
end of the BAT-AEL range is up to 0.4 mg/l. According to the collected data, around
65 % of the plants are below 0.2 mg/l. Abatement technologies reverse osmosis,
nanofiltration, microfiltration could be used to achieve the concentration levels
(AT 8).
Nickel (Ni)
Increase the lower end of the BAT-AEL range to 0.05 mg/l, because the lower limit
should be equal to environmental quality standards (EQS) in the Water Framework
102
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 85 link to page 85 link to page 85 link to page 85
Background paper – Final meeting for the review of the TXT BREF
Directive. Treating waste water below EQS would cause excessive costs
(EURATEX 46).
Lower the upper end of the BAT-AEL range to 0.08 mg/l. Add a footnote that the
upper end applies to the use of nickel-containing dyes. According to the collected
data, around 70 % of the plants are below 0.08 mg/l. Nickel is a Priority Substance.
Experience from Austrian plants shows that 0.08 mg/l can be achieved with good
chemical and water management (see BAT 39-42). The plants with emissions values
> 0.05 mg/l do not use abatement technologies such as reverse osmosis, ultrafiltration
or microfiltration (except Plant IT092_w(1)) (AT 10).
Zinc (Zn)
Increase the lower end of the BAT-AEL range to 0.2 mg/l, because the lower limit
should be equal to environmental quality standards (EQS) in the Water Framework
Directive. Treating waste water below EQS would cause excessive costs
(EURATEX 46).
Sulphide, easily released (S2-)
Footnote (2) should apply only to sulphide, because sulphide can be removed in
activated sludge plants with adapted biomass. All other parameters/substances
currently subject to this footnote (e.g. AOX, HOI, metals) are not removed by the
biological treatment and cannot be subject to such an exemption (AT 12).
Footnote (2)
Extend the footnote to: "This may be demonstrated by the use of actual data (influent
& effluent concentrations and flows) arriving and being discharged from the
downstream WWTW's or by the use of published data such as sewage treatment
reduction factors that are specific to the treatment provided at the downstream
WWTW's." The data on the removal efficiency of downstream WWTPs is not
available to the operator (confidential business information) to demonstrate
compliance to the competent authority (UK 25).
General comments
Regarding the issue on how to express the BAT-AELs, see the assessment done for
direct discharge in Section
1.4.6.3.
Indirect discharge is defined in the Definitions of the BAT conclusions; therefore, it is
not necessary to clarify the concept of indirect discharge in Table 5.4.
The aim of having BAT-AELs for indirect discharge is to protect the environment
when the downstream WWTP is not designed to treat the pollutants concerned. With
this objective in mind, it makes sense to have the same levels as direct discharge. For
clarity in implementation, the BAT-AELs for direct and indirect discharge are kept in
separate tables.
Regarding the comments to change the proposed BAT-AELs, see the assessment of
individual parameters in Section
1.4.6.3 (for direct discharge) and below (for indirect
discharge).
Monitoring for direct and indirect discharges is addressed in BAT 7.
EIPPCB
assessment:
Additional parameters
COD, TSS, Total N, Total P and TOC have not been included in Table 5.4 on the
grounds of the understanding that a downstream treatment plant is, generally, capable
of abating these pollutants, without any special provisions. In the rare cases that the
downstream plant is not capable of abating these parameters, the competent
authorities may apply the BAT-AELs in Table 5.3.
Regarding the comments for BOD, colour, nonylphenol, DecaBDE and Sum of
PFOA and PFOS, see the assessment done for direct discharge in Section
1.4.6.3.
Adsorbable organically bound halogens (AOX)
See the assessment related to direct emissions in Section
1.4.6.3 for use of a statistical
approach or environmental quality standards to derive BAT-AELs.
Regarding the proposals to increase the upper end of the BAT-AEL range due to
dyeing of polyester and blends of modacryl/cotton or due to dyeing with vat, metal-
complex and reactive dyes (assuming it is representative of ‘dyeing products with
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
103
link to page 85 link to page 85
Background paper – Final meeting for the review of the TXT BREF
high lightfastness, and high quality demands’), the conclusions are the same as for
direct discharge (see Sectio
n 1.4.6.3). There seem to be no technical grounds (i.e. due
to lack of use of appropriate treatment and many of the plants achieving values below
the proposal) for increasing for upper end of BAT-AELs to a higher value.
The “Hercosett” process is not considered BAT for shrink-proofing. BAT 51 in D1
promoted the use of chlorine-free antifelting, by using inorganic salts of
peroxymonosulphuric acid. It is not clear, technically or environmentally, why the
upper end of the BAT-AEL for indirect discharge should be increased to 2.5 mg/l
when the “Hercosett” process is used. Only one plant using this process reported an
AOX concentration higher than 2.5 mg/l, without using appropriate technique for
AOX abatement.
According to the Reference Document on Monitoring of Emissions to Air and Water
from IED Installations (ROM), the measurement range of the EN Standard 9562:2004
is 10-300 μg/l and the proposed lower end of the BAT-AEL range for AOX is
100 μg/l, i.e. 10 times higher. Data sets (e.g. AT006) in this range are therefore
considered credible.
Hydrocarbon oil index (HOI)
It is considered appropriate to add Footnote (3), as oils in waste water may not
originate from all processes (i.e. typically from washing synthetic fibres and knitting)
or fibres (i.e. typically from synthetic fibres and knitted fabrics).
For the assessment related to decreasing the upper end of the BAT-AEL range, see
the assessment in Section
1.4.6.3.
The lower limit of the measurement range set in EN ISO 9377-2:2000 for HOI is 0.1
mg/l, 10 times less than the proposed lower end of the BAT-AEL. Data sets in this
range are therefore considered credible.
Metals / metalloids
It is considered appropriate and consistent with BAT 2 and BAT 7 to add Footnote (3)
to metals for which any specific process is mentioned.
Depending on the parameter, EPs from well-performing plants have reported values
higher or lower than 0.2 mg/l, for both direct and indirect emissions. It is not clear on
which basis the upper end of the ranges should be lowered to 0.2 mg/l for all metals
indistinctly. In addition, the aim is to ensure an equivalent level of performance in
both cases (direct and indirect emissions), meaning that when the downstream waste
water treatment plant is not designed and equipped appropriately to abate metal
pollutants, then the textile plant ensures a similar level of performance as for direct
emissions.
When similar comments have been received for a given parameter, assessment of the
comments has been done for both direct and indirect emissions.
Antimony (Sb)
See the assessment related to direct emissions in the previous section.
According to the Reference Document on Monitoring of Emissions to Air and Water
from IED Installations (ROM) and the EN Standard 11885:2007, the limit of
detection range for Sb is 4-100 µ/l and the proposed lower end is 100 µ/l.
Chromium (Cr)
BAT-AELs are derived from the data collection; they are not based on environmental
quality standards referring to the quality of water.
See the assessment related to direct emissions in the previous section.
Copper (Cu)
See the assessment related to direct emissions in the previous section.
Nickel (Ni)
See the assessment related to direct emissions in the previous section.
Zinc (Zn)
BAT-AELs are derived from the data collection; they are not based on environmental
quality standards referring to the quality of water.
See the assessment related to direct emissions in the previous section.
104
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 85 link to page 85
Background paper – Final meeting for the review of the TXT BREF
Sulphide, easily released (S2-)
The downstream waste water treatment plant mentioned in Footnote (2) may be an
urban waste water treatment plant which indeed may not be designed or equipped to
reduce a number of the pollutants targeted by this footnote. However, it may also be
an industrial waste water treatment plant equipped for example with physico-
chemical treatment and capable of abating AOX, metals or HOI, in addition to
sulphide.
Regarding BAT-AELs, see the assessment for direct emissions in Sectio
n1.4.6.3.
Footnote (2)
Footnote (2) is used in a number of recently published BAT conclusions. The
verification of the actual removal efficiency of the downstream WWTP seems to be
an implementation issue.
Total P
Regarding the use of organophosphates as flame retardants and related BAT-AELs,
see the assessment for direct emissions in Sectio
n1.4.6.3.
General comments
No change.
Additional parameters
No change for nonylphenol, DecaBDE and Sum of PFOA and PFOS.
Adsorbable organically bound halogens (AOX)
To decrease the upper end of the BAT-AEL range.
Hydrocarbon oil index (HOI)
To add footnote (3).
To decrease the upper end of the BAT-AEL range.
Metals / metalloids
Antimony (Sb)
To decrease the upper end of the BAT-AEL.
EIPPCB
proposal:
Chromium (Cr)
To decrease the upper end of the BAT-AEL.
Copper (Cu)
To change activities/processes to dyeing/printing.
Nickel (Ni)
To change activities/processes to dyeing/printing.
To decrease the upper end of the BAT-AEL.
Zinc (Zn)
To add footnote (3).
Sulphide, easily released (S2-)
To decrease the lower end of the BAT-AEL.
Footnote (2)
No change.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
105
Background paper – Final meeting for the review of the TXT BREF
1.4.7
Emissions to soil and groundwater
1.4.7.1
Techniques to prevent or reduce emissions to soil and
groundwater
Location in
P. 737 – Section 5.1.7 – BAT 20
D1:
BAT 20. In order to prevent or reduce emissions to soil and groundwater, BAT is to
use all of the techniques given below.
Technique
Description
Applicability
This includes:
slow immersion into and
withdrawal of textile materials
from the process liquor to avoid
spillages;
automatic level adjustment of
process liquor (see BAT 3);
avoiding direct injection of water
to heat or cool the process liquor;
overflow detectors;
Techniques to reduce the
likelihood
and
channelling overflows to another
environmental impact of
tank;
a.
overflows and failures of
tanks for liquids are located in a
process
and
storage
suitable secondary containment;
tanks
their
volume
is
sized
to
accommodate
at
least
the Generally
complete loss of the liquid of the applicable
largest tank that is within the
Current
secondary containment;
text in D1:
isolation of tanks and secondary
containment (e.g. by closing
valves);
the surfaces of the process and
storage areas are impermeable to
the liquids concerned.
The plant and the equipment are
regularly inspected and maintained to
ensure
proper
functioning;
this
Regular inspection and includes in particular checking the
b.
maintenance of plant and integrity and/or leak-free status of
equipment
valves, pumps, pipes, tanks and
containments/bunds as well as the
proper
functioning
of
warning
systems (e.g. overflow detectors).
The
The storage areas are located in such applicability
a way to eliminate or minimise the
Optimised
storage
to
existing
unnecessary transport of process
c.
location
of
process
plants may be
chemicals within the plant (e.g. the
chemicals
restricted by
transport distances on site are space
minimised).
availability
Dedicated
area
for Hazardous process chemicals are Generally
d.
unloading
hazardous unloaded in a bunded area connected applicable
process chemicals
to a dedicated drainage system.
106
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Incompatible process chemicals are
kept separated. This segregation
Segregated storage of
e.
relies on physical separation and on
process chemicals
the chemicals inventory and tracking
system (see BAT 14).
Return of unused process chemicals
f.
Unused process chemicals (i.e. which remain in their original
containers) are returned to their suppliers.
Packaging containing liquid process
chemicals is completely emptied by
gravity or by mechanical means (e.g.
Handling and storage of brushing, wiping) without the use of
g.
packaging
containing water. Packaging containing process
process chemicals
chemicals in powder is emptied using
suction. Empty packaging is stored in
a dedicated area.
BAT statement:
Delete the words "or reduce" as the aim of this BAT is to prevent emissions
(DE 374).
Whole BAT:
Move techniques (c), (e) and (g) to BAT 13 as part of chemical management.
Optimised storage of chemicals is indeed related to chemical management (DE 375
and DE 378).
Technique a:
Add that the 9 points listed are applicable to new plants and major plant upgrades
(EURATEX 50).
Technique d:
Delete "connected to a dedicated drainage system" since drainage would be
connected to the common drainage system (DE 376).
Add in the BAT statement the possibility to "use a suitable combination of the
techniques given below", or limit the applicability of technique d to new plant or
major refurbishments of existing plant. Many old or historic sites could have
difficulty due to space constraints caused by the evolving layout of the installation
(UK 27).
Summary
Technique f:
of
Delete bullet point “return of unused process chemicals”, which belongs to BAT 28
comments:
“waste handling” (DE 377).
Add in the description that unused process chemicals can also be “properly disposed
of”, as suppliers are not obliged to accept the unused process chemicals (IT 22).
Add in the BAT Statement the possibility to "use a suitable combination of the
techniques given below", or mention that the applicability of technique f may be
limited. Many chemicals suppliers could be reluctant to take back used or even
unused process chemicals due to quality control issues and restocking constraints
(UK 27).
Technique g:
Revise the description as follows “powder products used in small quantities are
usually picked up manually with pallets and their packaging is emptied manually. The
widely consumed powders are taken by suction for loading into the automatic dosing
and dissolving plants” (IT 23).
Mention that the technique is only applicable to major plant upgrades as suction is not
general applicable (EURATEX 49).
Additional technique:
Add a technique about storage of waste to protect soil and groundwater because it can
cause emissions to soil and groundwater, in the same way as process chemicals
(SE 29).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
107
Background paper – Final meeting for the review of the TXT BREF
BAT statement:
Not all techniques listed in BAT 20 allow complete prevention of emissions, for
instance technique a only reduces the likelihood of overflows and failures, which may
nevertheless still happen.
Whole BAT:
The scope of BAT 13 is the overall environmental performance, within the general
principle of the elaboration and implementation of a chemicals management system
(CMS) as part of the EMS. On the other hand, techniques e., c. and g. in BAT 20 are
related to process or equipment used in the plant, and consequently are directly
operational. BAT 13 and BAT 20 are indeed linked and this is highlighted in
feature VII of BAT 13 which points at BAT 20. The link with the overall
environmental performance could be clarified in the statement in BAT 20.
Technique a:
No rationale has been provided to explain why technically it is needed to change the
applicability of technique a. The listed points are measures commonly applied.
Technique d:
The dedicated drainage for the area for unloading hazardous process chemicals aims
to avoid mixing the possible spillages with any other effluent with low level of
pollution such as collected run-off water.
This being said, the focus of the techniques is not on the drainage itself but on the
EIPPCB
dedicated collection and treatment of occasional spillages and this could be reflected
assessment:
in technique d.
It is not clear technically why it is needed to add an applicability criteria since it is
possible to share an existing area and to use temporary spillage collection devices
when unloading hazardous process chemicals.
Technique f:
Even though technique f would allow to reduce the risks associated to the storage of
chemicals, the prime objective of technique f is to reduce the amount of waste sent for
disposal and it would be therefore be better placed in BAT 28.
The return of unused chemicals indeed depends on the agreement of the suppliers, but
it is not clear why such agreement could not be negotiated when placing the order.
Technique g:
According to the description of the technique in Section 4.1.6.6 of D1, small
packaging containing process chemicals in plastic or paper bags up to 25 kg are
handled manually.
Additional technique:
The separate collection and storage of waste contaminated with hazardous chemicals
is already covered in BAT 28 b.
Technique a covers all types of liquids, including liquid waste, which could be
clarified.
To specify that liquid waste are also addressed by technique a.
To reword technique d to focus on collection of spillages
EIPPCB
To add a mention to small packaging in technique g.
proposal:
To move technique f. to BAT 28
To complement the statement
108
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 18 link to page 109
Background paper – Final meeting for the review of the TXT BREF
1.4.8
Emissions to air
No comments.
1.4.8.1
Techniques for reducing channelled emissions to air
Location in
P. 738 – Section 5.1.8 – BAT 22
D1:
BAT 22. In order to facilitate the recovery of energy and the reduction of channelled
emissions to air, BAT is to limit the number of emission points.
Description
Current
The combined treatment of waste gases with similar characteristics ensures more effective
text in D1:
and efficient treatment compared to the separate treatment of individual waste gas
streams. The extent to which the number of emission points can be limited depends on
technical (e.g. compatibility of the individual waste gas streams) and economic factors
(e.g. distance between different emission points).
In the wording of the statement, replace “to limit” with “to optimise” as limiting the
number of points of emissions is not always a feasible option for existing plants,
taking into account the type, nature and localisation of the channelled emissions. In
addition, this would give flexibility to the competent authorities (IT 24).
Change the wording of the statement to "BAT is to collect and concentrate the waste
gas streams in as few emission points as technically possible" as the mere limitation
of number of emission points is not sufficient (DE 73).
Add the following provision to avoid dilution when combining waste gas streams: the
Summary
emissions from the common stack do not exceed the emission level of the individual
of
waste gas streams if they were channelled individually (DE 123).
comments:
Change the applicability to new plants and major plant upgrades because collecting
all emissions is not generally applicable as it can lead to a higher concentration of
pollutants and contribute to a loss of efficiency of the oven (EURATEX 53).
Change the last sentence of the description into an applicability restriction (IT 25).
Add an applicability restriction to major refurbishment programmes across the site in
general, upgrading to existing abatement technologies or replacement of existing
thermal treatment or other processes which result in significant emissions to air
(UK 28).
BAT 22 as proposed in D1 focuses on the limitation of the number of emission
points, i.e. on the non-augmentation of the number of emission points beyond a
certain limit. As mentioned in the description of BAT 22, this limit is set by
considering a number of technical and economic factors. In other words, this limit is
as low as these factors allow, which is equivalent to the proposed wording “optimise”
and partially equivalent to the proposed wording “to concentrate the waste gas
streams in as few emission points as technically possible.” The difference with the
latter is the consideration of the economic factor, when for example two emission
points are very far away from each other. In that case, even if technically feasible, it
EIPPCB
may not be economically viable to connect these two emission points.
assessment:
Concerning the dilution of emissions to air, see the assessment related to the General
considerations, in Section
1.3.1.
The collection of emissions is covered by BAT 21, not by BAT 22. See the related
assessment in Section
1.4.8.1.
The principle of limiting the number of emission points
per se is generally applicable,
which is reflected in the proposal of D1. This principle can also be applied to existing
plants and not only to plant upgrades. Of course, as mentioned in the technique
description, the extent to which the number of emission points can be limited may
vary and depends on technical and economic factors.
EIPPCB
No change.
proposal:
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
109
Background paper – Final meeting for the review of the TXT BREF
1.4.8.2
Techniques for reducing channelled emissions of organic
compounds (e.g. formaldehyde) to air
Location in
P. 738 – Section 5.1.8 – BAT 23
D1:
BAT 23. In order to reduce channelled emissions of organic compounds (e.g.
formaldehyde) to air, BAT is to use one or a combination of the techniques given
below.
Current
Technique
Description
text in D1:
a.
Condensation
b.
Ionisation
See Section 5.9.2.
c.
Thermal oxidation
d.
Wet scrubbing
General comment about BAT 23
Add additional information about the abatement techniques such as typical pollutants
targeted, removal efficiency and applicability (DE 274).
BAT statement
Delete the reference to formaldehyde as only technique c. is relevant for this pollutant
(DE 206, EURATEX 117).
Summary
Technique b.
of
Delete technique b. as it is not a technique suitable for the removal of volatile organic
comments:
compounds because there is a risk of explosion during use (CZ_B 8).
Additional techniques
Add electrostatic precipitator (ESP) as it is an efficient abatement technique for oil
mist (SE 46).
Add catalytic oxidation which is used for singeing (DE 74).
Add adsorption which is a well-recognised technique for minimising emissions of
organic solvents to air (UK 29).
General comment about BAT 23
The format of the table used in BAT 23 is consistent with the format used in the
recently published BAT conclusions where abatement techniques for emissions to air
are presented. In the standard format, removal efficiency is not mentioned but this
information may be found in other documents such as the CWW BREF.
Concerning the typical target pollutants, they are mentioned in the BAT statement
(i.e. organic compounds including formaldehyde).
As mentioned in the General considerations, the BAT conclusions are generally
applicable unless otherwise stated.
BAT statement
According to the CWW BREF, scrubbing is widely used as a raw material and/or
EIPPCB
product recovery technique for the separation and purification of gaseous streams
assessment:
which contain high concentrations of VOCs, especially compounds soluble in water
such as alcohols, acetone or formaldehyde (Section 3.5.1.2.4 of the CWW BREF). It
is also a technique used to abate formaldehyde in the WBP and the GLS BAT
conclusions.
According to the first draft of the WGC BREF (see Section 2.3.2.10.2 of the WGC
BREF), the techniques most commonly applied to abate formaldehyde in the
chemical sector are:
o absorption (wet scrubbing);
o adsorption;
o condensation;
o thermal or catalytic oxidation.
Wet scrubbing and condensation are therefore techniques used to abate formaldehyde.
Concerning ionisation, no clear evidence has been found that ionisation was used to
110
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
abate channelled emissions of formaldehyde to air.
The BAT statement has been clarified with activities/processes mentioned in table
5.5.
Technique b.
According to the CWW BREF (Section 3.5.1.3.7), ionisation targets the abatement of
VOCs. No specific risk of explosion is mentioned.
However, ionisation is used only for one EP (IT083_{14}) in combination with
condensation.
Additional techniques
Oil mist is not addressed by BAT 23 as it was concluded at the KoM that oil mist was
not a KEI (see Section 4.2 of the KoM report).
Adsorption is used by two plants of the data collection (CZ015 uses adsorption to
abate emissions from lamination and IT074 to abate emissions from dry cleaning) and
catalytic oxidation is used only by Plant DE047 to abate emissions from singeing.
CZ015 is the only plant reporting emission values for TVOC, and none of the three
plants have reported values for formaldehyde.
In any case, even if a technique is not mentioned in BAT 23, it can be used if it
ensures at least an equivalent level of environmental protection.
To delete ionisation.
EIPPCB
To introduce adsorption.
proposal:
To harmonize the BAT statement with table 5.5.
1.4.8.3
BAT-AELs for channelled emissions of organic compounds (e.g.
formaldehyde) to air
Location in
P. 738 – Section 5.1.8 – BAT 23 – Table 5.5
D1:
Table 5.5:
BAT-associated emission levels (BAT-AELs) for channelled emissions
of organic compounds (e.g. formaldehyde) to air
BAT-AEL
(Average
Mass flow
over the
Substance/Parameter
Activities / Processes
threshold
sampling
(g/h)
period)
(mg/Nm3)
Coating (1) (2)
Current
Flame lamination (3)
text in D1:
Printing (1) (4)
Singeing
Formaldehyde
1–5
2.5
Thermal treatment in finishing
(1)
Thermal treatment in printing
(1) (4)
Coating
Lamination
TVOC
Printing
3–40 (5)
100
Singeing
Thermal treatment
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
111
link to page 40
Background paper – Final meeting for the review of the TXT BREF
(1) The BAT-AEL only applies when formaldehyde is identified as relevant in the waste
gas stream based on the inventory of inputs and outputs mentioned in BAT 2.
(2) The BAT-AEL does not apply where the organic solvent consumption for coating
exceeds 5 tonnes per year.
(3) The BAT-AEL does not apply where the organic solvent consumption for lamination
exceeds 15 tonnes per year.
(4) The BAT-AEL does not apply where the organic solvent consumption for rotary
screen printing exceeds 30 tonnes per year.
(5) The lower end of the BAT-AEL range is typically achieved when using thermal
oxidation.
The associated monitoring is given in
0. General comments on the mass flow thresholds
Clarify the approach for setting the mass flow thresholds (BE 10).
Delete the mass flow thresholds for all air emission because they are very low and
almost no installation reports emissions below the thresholds (DE 379).
Processes concerned
Add "Thermal treatment with direct heating" as a process concerned for formaldehyde.
Indeed formaldehyde is generally relevant for all direct heating treatments like
fixation, heat setting, drying as well as the thermosol dyeing process, dyeing with
carriers, etc. and not only for finishing or printing (DE 77).
Add finishing as a process concerned for formaldehyde and TVOC as these pollutants
may be emitted during finishing (DE 382).
TVOC
Delete the mass flow threshold, as there are many plants with emissions below 100 g/h
using BAT (e.g. thermal oxidation). In addition, the data show that the proposed mass
flow threshold would exclude 63 % of the emission points from the BAT’AELs
(AT 26).
Delete the mass flow threshold because it is uncommon in BREFs and creates
unnecessary complication. If an air stream is channelled and is linked to any of these
activities, it is likely to have loads higher than this (EEB 197).
Change the BAT-AEL range to 3-20 mg/Nm3 as about two thirds of the reported data
are below 20 mg/Nm3 and techniques are available to achieve this level (AT 25). In
Summary
addition, some installations reporting high TVOC emissions (e.g. Plants IT074{5} and
of
IT079{3}) use poor measurement techniques, as shown by the reported measurement
comments:
uncertainties of the order of 30-50 % of the measured value. Other measurement data
with high TVOC concentrations (Plants DE026 and DE048) have uncertainties of
2 mg/Nm3, which indicates good quality measurements (EEB 184).
The lower end of the range may be difficult to monitor with handheld devices which
are proven for use at ELVs of greater than or equal to 6 mg/Nm3 (UK 32).
Formaldehyde
Check the correctness of the mass flow threshold (2.5 g/h) for formaldehyde (BE 11).
Delete the mass flow threshold because it is uncommon in BREFs and creates
unnecessary complication. If an air stream is channelled and is linked to any of these
activities, it is likely to have loads higher than this (EEB 196).
Delete the mass flow threshold because emission points below the proposed mass flow
threshold are within the BAT-AEL range. In addition, formaldehyde is a CMR
substance (AT 24).
Change the mass flow threshold to 25 g/h in line with the WGC BAT conclusions
(CEFIC 23) and because the mass flow of 25 g/h in correlation with the proposed
upper end of the range of 5 mg/Nm3 would mean an air flow of 50 000 Nm3/h, which is
more in line with the usual values (EURATEX 51).
Modify the upper end of the range as follows:
o 10 mg/Nm3 for finishing processes (coating, starching - including combustion
processes in thermal aggregates with direct heating) and for easy-care
finishing, water and soil repellent finishing, thermosol process;
o 15 mg/Nm3 for thermo-fixation;
112
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
o 20 mg/Nm3 for wrinkle-free finishing and flame-retardant finishing.
German LAI14 recommendations are attached to the comment (EURATEX 132, DE 209).
Increase the upper end of the range to 20 mg/Nm3 for fire retardants applications, easy-
care and water repellence applications. Measurement results are attached to the
comment (EURATEX 54).
Change the BAT-AEL range to 1-3 mg/Nm3 because plants with emissions between 3
and 5 mg/Nm3 do not apply BAT (EEB 185).
Monitoring data support the application of such a low end of the range for
formaldehyde based on a limit of detection that is 1/20 of the proposed 1 mg/Nm3
value. However, the extended sample time required to achieve such a low level of
detection may result in additional costs to operators (UK 31).
Oil mist
Add a BAT-AEL for emissions of oil mist from thermal treatment, with a range of 1-
8 mg/Nm3 and a mass flow threshold of 100 g/h (SE 30).
Footnote (1)
Apply Footnote (1) to singeing also because formaldehyde is not mentioned as a
relevant pollutant for singeing in Section 2.6.1.1 of D1 and because it cannot be
deduced from Figure 3.56 in D1 if data on emissions of formaldehyde also refer to
waste gases from singeing (IT 26).
Footnotes (2), (3) and (4)
In order to ensure consistency with the IED, add the following text at the end of
Footnotes (2), (3) and (4): “(…) and the mass flow of formaldehyde is greater than, or
equal to, 10 g/h, an emission limit value of 2 mg/Nm3 shall be complied with (IED,
Annex VII, Part 4)” (AT 21, AT 22, AT 23).
In order to ensure consistency with the IED, add the following text at the end of
Footnotes (2), (3) and (4): “ (…) technical provisions of Part 4, Annex VII to Directive
2010/75/UE apply” (IT 27).
Delete these footnotes because they are not substantiated. Indeed, these footnotes are
not useful to avoid overlaps between the TXT and the STS BAT conclusions. The final
draft of the STS BAT conclusions covers consumption of organic solvent over 200
t/year, leaving an unregulated gap between the values proposed here and the 200 t/year
of the STS BAT conclusions (EEB 194).
Move the application of these footnotes from formaldehyde to TVOC because
formaldehyde is not considered to be an organic solvent (CZ_B 9).
For the sake of clarity, delete Footnotes (2), (3) and (4) and replace them with one
unique footnote that would apply for all processes, for both formaldehyde and TVOC:
“the BAT-AEL does not apply for installations falling under Chapter V of the IED"
(DE 76).
Additional footnotes
Add the following footnote to TVOC emissions in order to clarify that legislative
provisions apply even when the mass flow is below the threshold of 100 g/h: “In the
case of a TVOC mass flow of less than 100 g/h, the provisions laid down by the
Directive 2010/75/UE for activities using organic solvents (Chapter V) apply to TVOC
emissions to air from coating, lamination and printing processes where the organic
solvent consumptions exceed the thresholds set out in the Part 2 of the Annex VII to
IED” (IT 28).
Add a similar footnote to Footnote (1) for TVOC emissions from coating, lamination,
printing and thermal treatment as the BAT-AELs are only relevant if TVOC is present
in the waste gas streams from these processes, i.e. if organic solvents are used
(CEFIC 24, EURATEX 56).
Add a similar footnote to Footnote (1) for TVOC emissions from thermal treatment
because the BAT conclusions also consider drying to be a thermal treatment where
VOCs cannot be present in the waste gases (CZ_B 10)
14 Vollzugsempfehlung Formaldehyd, Bund/Länder-Arbeitsgemeinschaft Immissionsschutz, 2015 at
https://www.lai-
immissionsschutz.de/documents/2015-12-09_vollzugsempfehlung_formaldehyd_1503573754.pdf
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
113
Background paper – Final meeting for the review of the TXT BREF
Add the following footnote to TVOC emissions: “an additional mass concentration of
no more than 20 mg/Nm3, to be indicated as total carbon, may be emitted from carry-
overs and residues of preparations. The additional mass concentration only applies
when using an air-textile goods ratio of 20 m3/kg is used” (DE 380).
Add the following footnote to TVOC emissions: “after deduction of measured
emissions of unavoidable unburnt methane, carryover and residual preparations, based
on air- textile- ratio of 20:1 for energy efficiency” (EURATEX 159).
Add the following footnote to TVOC emissions: “For existing direct heated thermal
apparatus, up to a maximum emission concentration of 20 mg C/Nm3 can be
discounted if it is proven from the unburnt fuel and all possibilities for a reduction have
been carried out (e.g. like optimisation of burning process, minimum annual
maintenance of the burners)”. This is to account for cases where e.g. unburnt methane
contributes to TVOC emissions (DE 349).
General comments on the mass flow thresholds
As mentioned in Section 3.5.1 of D1, abatement techniques are used by only 120
emission points out of 567:
o
Concerning TVOC, only 43 emission points (EPs) out of the 344 EPs that
reported TVOC emissions are equipped with techniques to abate emissions of
organic compounds to air, as listed in BAT 23.
o
Concerning formaldehyde, only 19 EPs out of the 60 EPs that reported
formaldehyde emissions are equipped with techniques to abate emissions of
formaldehyde to air, as listed in BAT 23.
o
Concerning dust, 26 EPs out of the 180 EPs that reported dust emissions are
equipped with techniques to abate emissions of dust to air, as listed in
BAT 24.
o
Concerning NH3, 4 EPs out of the 27 EPs that reported NH3 emissions are
equipped with techniques to abate emissions of NH3 to air, as listed in
BAT 25.
This situation where only a minority of EPs are equipped with abatement techniques
(12-15 % for dust, TVOC and NH3 and 32 % for formaldehyde) may be explained by
the significance of the emission, which is best appreciated by looking at the emission
mass flows.
One could note in particular that a number of unabated emission sources are even
smaller in terms of mass flow than abated emission sources, as shown in the graphs
below for TVOC:
EIPPCB
assessment
:
TVOC emissions to air from EPs equipped with relevant abatement techniques,
expressed in mass flow (g/h)
TVOC emissions to air from EPs not equipped with relevant abatement techniques,
expressed in mass flow (g/h)
The mass flow thresholds proposed in D1 attempt to reflect those cases where unabated
emissions are already smaller than abated emissions and for which abatement techniques
114
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
would therefore not necessarily be needed.
The proposed mass flows thresholds are indeed low but a significant number of EPs
have reported emissions even lower than the mass flow thresholds:
o TVOC: 209 out of the 344 emission points that reported TVOC emissions
have a mass flow below 100 g/h.
o Formaldehyde: 11 out of the 60 emission points that reported formaldehyde
emissions have a mass flow below 2.5 g/h.
o Dust: 132 out of the 180 emission points that reported dust emissions have a
mass flow below 50 g/h.
o NH3: 16 out of the 27 emission points that reported NH3 emissions have a
mass flow below 50 g/h.
Processes concerned
Formaldehyde may be a product of combustion of natural gas (in particular methane)
and indeed the data collection shows formaldehyde emissions from thermal treatment
which is not connected to finishing or printing (EP DE029_{1}) and this could be
better reflected in Table 5.5.
When natural gas is burnt, formaldehyde emissions may be generated whatever the
type of heating (direct or indirect). Considering that the scope of the BAT conclusions
covers both cases, it does not appear necessary to restrict the application of the BAT-
AEL to direct heating only. This would also be in line with the BAT-AEL on TVOC
which applies to both direct and indirect heating.
According to the definition, thermal treatment includes fixing and heat-setting, and
process steps of other processes such as pretreatment, dyeing, finishing or printing.
Based on the data collection, it is not clear whether any emission point that reported
formaldehyde or TVOC emissions to air is connected directly to the wet finishing
process and/or associated with emissions from other processes (coating or lamination).
It is not clear either how emissions to air would arise from the wet process itself. It is
considered these must be related to the thermal treatment step and it could be clarified
that finishing is a process concerned for both formaldehyde and TVOC, and that
thermal treatment is included as part of the other activities and processes mentioned.
TVOC
Concerning the mass flow threshold, see the general remarks above.
When abatement techniques for TVOC removal are applied, the lowest mass flows
reported from EPs are around 40 – 50 g/h. Assuming a moderate abatement efficiency
of 80%, gives a conservative unabated (raw) mass flow of 200 g/h, which is considered
an appropriate mass flow threshold for the relevant EPs from the textile processes.
For emission points without abatement which have:
o the emission mass flow is below the proposed value, and
o the emission concentration is between 3 mg/Nm3 and 40 mg/Nm3.
around 71% of the EPs fulfil both conditions. It is considered that these EPs are not
significant. This could be reflected by adding a footnote to acknowledge when the
BAT-AEL applies.
Concerning the upper end of the range, the derivation of the BAT-AELs is not based
on a statistical approach. Even though two thirds of the plants have reported emission
levels below 20 mg/Nm3, it is not clear why 20 mg/Nm3 should be the upper end of the
range.
The values reported by emission points IT074{5} and IT079{3} do not correspond to
concentrations but to mass flows expressed in g/h. Plant DE026 has reported maximal
emission concentrations between 30 mg/Nm3 and 70 mg/Nm3 so it is not clear how this
supports the lowering of the upper end of the range to 20 mg/Nm3. Plant DE048 did
not take part in the data collection.
More generally speaking, out of the 326 EPs which have reported a monitoring
standard for TVOC, 216 have reported using the standard EN 12619. The use of the
same standard ensures an equivalent measurement quality level.
Concerning the lower end of the range, the standard used for monitoring TVOC is
EN 12619:2013, which is done by sample extraction and sample filtration followed by
flame ionisation detection. The measurement is not carried out with a handheld device.
Formaldehyde
Concerning the mass flow threshold, see the general remarks above. While consistency
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
115
Background paper – Final meeting for the review of the TXT BREF
with other BAT conclusions is an element to consider, the mass flow threshold in D1
has been proposed on the basis of the data collection for the TXT BREF review, which
differs from the data collection carried out for the drawing up of the WGC BREF.
Following the interventions of the different TWG members during the informal
meeting of 19/02/2021, it seemed that there was not a common position on how to
determine which of the emission points reporting formaldehyde emissions are
considered relevant and would need to comply with BAT-AEL, and which are
irrelevant (or insignificant in terms of environmental impact) and would not need to
comply with BAT-AEL. Therefore, the mass flow threshold for this parameter will not
be proposed.
The air flow reported by the emission points where formaldehyde is measured ranges
from 470 m3/h to 38 100 m3/h, with an average of 12 900 m3/h. It is not clear whether
there is a correlation between the upper end of the range and the mass flow threshold.
Concerning the upper end of the range, the BAT-AELs are not based on national
legislation or guidelines but on the data collection. According to the data collection,
none of the plants that reported a maximum formaldehyde concentration above
5 mg/Nm3 use a technique to abate formaldehyde emissions, except Plant UK127.
No information has been collected about wrinkle-free finishing during the data
collection; however, the following is available:
o EPs IT094_a{3}, IT094_a{4}, IT094_a{1}, DE042_a{1}, DE032_a{1},
UK127_a{6}, UK127_a{1}, DE050_a{1}, DE023_a{2}, UK127_a{2} and
UK127_a{4} apply flame retardants and have reported achieving
formaldehyde emissions below 5 mg/Nm3 by using one or a combination of
techniques mentioned in BAT 23;
o EPs IT094_a{3}, IT094_a{4}, IT094_a{1}, DE042_a{1}, DE032_a{1},
UK127_a{6}, DE049_a{3}, UK127_a{1}, UK127_a{2}, UK127_a{4} apply
easy-care finishing and have reported achieving formaldehyde emissions
below 5 mg/Nm3 by using one or a combination of techniques mentioned in
BAT 23;
o EPs IT083_a{14}, IT094_a{3}, IT094_a{4}, IT094_a{1}, DE042_a{1},
DE032_a{1}, UK127_a{6}, UK127_a{1}, DE050_a{1}, DE023_a{2},
UK127_a{2} and UK127_a{4} apply water repellents and have reported
achieving formaldehyde emissions below 5 mg/Nm3 by using one or a
combination of techniques mentioned in BAT 23;
o EPs UK124_a{1}, UK124_a{6}, UK127_a{6}, UK127_a{1}, UK127_a{2}
and UK127_a{4} apply thermosol dyeing and have reported achieving
formaldehyde emissions below 5 mg/Nm3 by using one or a combination of
techniques mentioned in BAT 23;
o EPs IT094_a{3}, IT094_a{4}, IT094_a{1}, DE042_a{1}, UK124_a{1},
DE032_a{1}, UK124_a{6}, UK127_a{6}, DE050_a{1}, DE023_a{2} and
UK127_a{4} apply thermofixation and have reported achieving formaldehyde
emissions below 5 mg/Nm3 by using one or a combination of techniques
mentioned in BAT 23.
No conclusive evidence was found in the data collection for plants using abatement
techniques to support the different upper ends for different finishing processes (e.g. 10,
15 or 20 mg/m3). However, many plants (particularly from DE) not using abatement
techniques did report values around 10 or 20 mg/m3, respecting such emission limit
values. The pollution reduction and control in these plants is potentially ensured by
process-integrated techniques.
Plants DE023 and DE050 report emission levels between 3 mg/Nm3 and 5 mg/Nm3
and apply wet scrubbing which is a technique to reduce formaldehyde emissions to air.
Concerning the lower end of the range, the sampling duration reported by the plants of
the data collection which monitor formaldehyde ranges from 0.3 to 6 hours. One of the
plants that reported the shortest sampling period is UK124 which has reported
formaldehyde emissions below or close to 1 mg/Nm3. Therefore it does not seem
necessary to mention a longer sampling time for formaldehyde.
Oil mist
Oil mist is not a KEI as concluded by the TWG at the Kick-off Meeting (see Section
4.2 - Table 1 of the Kick-off Meeting report).
Footnote (1)
116
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 18
Background paper – Final meeting for the review of the TXT BREF
Footnote (1) as proposed in D1 targets the emissions of formaldehyde due to the
formaldehyde or formaldehyde precursors that may be present in the process chemicals
used in coating, printing or finishing. These formaldehyde emissions can be identified
in the inventory of inputs and outputs, based on the inventory of the process chemicals
used.
In addition, formaldehyde emissions are also generated by the combustion of
methane15, which is relevant for singeing, flame lamination and thermal treatment (for
the latter, see the assessment above). In these cases, formaldehyde emissions will
always be relevant and Footnote (1) is not necessary.
Footnotes (2), (3) and (4)
The objective of Footnotes (2), (3) and (4) is to avoid conflict with the provisions of the
IED (mainly Part 4 of Annex VII). The BAT conclusions do not aim to repeat or
interpret the IED provisions such as those laid down in Part 4 of Annex VII and in
particular in its point 1.
The footnotes do not aim to avoid overlaps or gaps with the STS BAT conclusions but
to avoid conflict with the provisions of the IED.
The footnotes are not linked to formaldehyde being used as organic solvent but to
processes using organic solvent as listed in Annex VII to the IED and generating
emissions of formaldehyde.
Point 1 in Part 4 of Annex VII states for the processes concerned that “for emissions of
the volatile organic compounds referred to in Article 58 where the mass flow of the
sum of the compounds causing the labelling referred to in that Article is greater than,
or equal to, 10 g/h, an emission limit value of 2 mg/Nm3 shall be complied with. The
emission limit value refers to the mass sum of the individual compounds”. As
formaldehyde is classified as CMR, this means that there could be a conflict with the
IED as the proposed upper end of the BAT-AEL range is 5 mg/Nm3. The same may be
valid for any other CMR substance, which could be clarified in the footnote.
The justification for the footnotes as proposed in D1 could be unclear to the reader,
which could be clarified by simply referring to the activities covered by Chapter V of
the IED instead of referring to the activities and solvent consumption thresholds.
Additional footnotes
Concerning the reference to Annex VII to the IED, as mentioned above, the BAT
conclusions do not aim to repeat or interpret the IED and it does not seem necessary to
mention that the IED applies, which it does in any case, even if the TVOC mass flow is
greater than the proposed value.
When establishing the inventory of waste gas streams (BAT 2), the use of organic
solvent in a process can be an element of consideration when evaluating whether
organic compounds are present in the waste gas from this process (for instance in the
case of printing). The use of organic solvent may however not be a determining factor
as far as thermal treatment is concerned, because organic compounds may also be
generated by the evaporation or degradation of residues or of substances previously
applied on the textile fibres and it seems difficult to exclude this situation
a priori in
the inventory of waste gas streams. Concerning coating and lamination, according to
Section 2.10.3 of D1, the emissions of organic compounds to air are not necessarily
linked to the use of solvent-based formulations, but also to the use of water-based
formulations (where dispersing agents and residues may be responsible for the
emissions) as well as to the use of coating pastes and melamine resins.
No data have been collected on the emissions due to the carry-over and residues of
preparation. In addition, it is not clear why this would lead to an additional emission
concentration of 20 mg/Nm3.
A number of pieces of data have been collected on TVOC emissions from directly
heated systems. In these cases, the reported emissions include emissions from the
process itself and from the combustion and have been the basis for proposing BAT-
AELs in D1. It is not clear why 20 mg/Nm3 should be deducted in these cases.
Concerning the air-textile ratio of 20, see the assessment of the General considerations
in Section
1.3.1.
15 CIMAC Position Paper 04-2014
“Methane and formaldehyde emissions of gas engines”
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
117
Background paper – Final meeting for the review of the TXT BREF
To add finishing as a process for formaldehyde and TVOC.
To delete “thermal treatment in finishing” and “thermal treatment in printing” for
formaldehyde.
To mention in the BAT statement the processes from which the emissions originate.
EIPPCB
To delete the proposed mass flow for formaldehyde.
proposal:
To add a new footnote to restrict the applicability of the BAT-AEL based on the
TVOC mass flow without CMR substances.
To replace Footnotes (2), (3) and (4) with a new footnote and refer to activities covered
by Chapter V of the IED.
1.4.8.4
Techniques for reducing channelled dust emissions to air
Location in
P. 739 – Section 5.1.8 – BAT 24
D1:
BAT 24. In order to reduce channelled dust emissions to air, BAT is to use
one or a combination of the techniques given below.
Current
text in D1:
Technique
Description
a.
Cyclone
b.
Electrostatic precipitator (ESP)
See Section 5.9.2.
c.
Wet scrubbing
Change the BAT statement to state that cyclones can only be used in combination
with other abatement techniques, as the upper end of the range of the proposed BAT-
AELs cannot be achieved with a cyclone alone (UK 30).
Add fabric filters to the list of techniques as they can achieve low levels of emissions,
Summary
are used for mechanical processes in textile processing or dye handling and have been
of
reported by various plants (IT061 and IT096) (DE 79, IT 29, EEB 195).
comments:
Add absolute filters to the list of techniques as dust filtration systems allowing the
achievement of the dust emissions at the lower end of the proposed BAT-AEL range.
In addition, those techniques are efficiently being used, e.g. by IT061, IT072, IT083
and IT094 (IT 29).
According to the data collection, 4 EPs are equipped with cyclones as the only
abatement technique and have reported dust emissions to air up to 6.1 mg/Nm3
(IT078_a{4}, PT115_a{4}, IT069_a{1} and PT115_a{11}). These EPs are related to
singeing and thermal treatment in finishing.
However, cyclones are generally used as pre-treatment, as is mentioned for example
in the WT BAT conclusions.
Two EPs are equipped with bag filters (IT061_{3} and IT061_{4}), with dust
emissions to air of 8.5 mg/Nm3 and 2.5 mg/Nm3 respectively. The dust emissions
originate from beating and folding of wool.
Two EPs are equipped with absolute filters (IT083_{15} and IT072_{4}), with dust
emissions to air of 0.4 mg/Nm3 and 6.8 mg/Nm3 respectively. EP IT083_{15} is
EIPPCB
associated with weighing of hydrosulphite and EP IT072_{4} is associated with
assessment:
pressing and packaging.
EP IT094_{02} reported the use of a bag filter but did not report dust emissions.
Bag filters and absolute filters are therefore used to abate dust emissions from
handling textile material or process chemicals but, according to the data collection,
they are not used to abate dust emissions from the processes addressed in Table 5.6,
i.e. singeing, fabric production or thermal treatment. This could be clarified in the
BAT statement.
In any case, the techniques listed in BAT 24 are neither prescriptive nor exhaustive.
Other techniques may be used that ensure at least an equivalent level of
environmental protection.
To mention that cyclones are generally used as pre-treatment.
EIPPCB
To mention in the BAT statement the processes from which the dust emissions
proposal:
originate (see the assessment in Section 1.4.8.5).
118
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 40
Background paper – Final meeting for the review of the TXT BREF
1.4.8.5
BAT-AEL for channelled dust emissions to air
Location in
P. 739 – Section 5.1.8 – BAT 24 – Table 5.6
D1:
Table 5.6:
BAT-associated emission level (BAT-AEL) for channelled dust
emissions to air
BAT-AEL
(Average over
Mass flow
Activities /
Substance/Parameter
the sampling
threshold
Processes
period)
(g/h)
Current
(mg/Nm3)
text in D1:
Fabric production
Dust
Singeing
< 1–10
50
Thermal treatment
The associated monitoring is given i
n 0. Processes concerned
Delete thermal treatment because normally there is no dust emission from thermal
treatment (however dust may be relevant for combustion process for heat production
or directly heated stenters if other fuel besides LPG or natural gas is used) (DE 80).
Delete fabric production and thermal treatment because dust emissions are only
relevant for singeing (DE 383).
Add "handling processes with solids like dyes" as another activity concerned
(DE 80).
Threshold
Delete the mass flow threshold because it is uncommon in BREFs and creates
unnecessary complication. If an air stream is channelled and is linked to any of these
activities, it is likely to have loads higher than this (EEB 198).
Delete the mass flow threshold because many emission points below the proposed
mass flow threshold are within the BAT-AEL range and therefore BAT. In addition,
there are many plants below 50 g/h using abatement techniques and about 75 % of the
emission points are below 50 g/h and excluded from the BAT-AEL (AT 27).
BAT-AEL range
Lower the upper end of the range to 5 mg/Nm3 and consider lowering the lower end
Summary
to take into account the good performance of fabric filters (EEB 199).
of
comments:
Increase the upper end of the range to 20 mg/Nm3 to account for emissions due to the
quality of the textile and not to the burning of fuel (e.g. if cotton is singed with
medium- and low-quality cotton and organic cotton, because this might cause higher
emissions of burnt cotton dust, e.g. due to low staple length, increased hairiness)
(EURATEX 160).
Increase the upper end of the range to 50 mg/Nm3 and the mass flow threshold to
250 g/h because these values cannot be reached by using only BAT. To do so, it
would be necessary to install abatement techniques at all stacks, which may not be
possible due to product quality (CZ_B 78).
Increase the lower end of the range to 5 mg/Nm3 because demonstrating compliance
at such low levels is likely to prove extremely challenging for operators and their
monitoring contractors and will likely result in additional costs for the monitoring
programme. In particular:
o it is not clear how many of the collected data are from results reported as
less than values, which will have an associated high level of uncertainty
attached to them;
o the scope of the standard EN 13284-1:2017 is stated as being “up to
50 mg/Nm3 and typically 5 mg/Nm3”;
o the standard EN 13284-1:2017 specifies that the overall field blank must be
< 10 % of the ELV; an ELV of 1 mg/Nm3 would require a field blank of
< 0.1 mg/Nm3, which may not be possible to achieve;
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
119
link to page 111
Background paper – Final meeting for the review of the TXT BREF
o the standard specifies that the expanded uncertainty of the result should not
exceed 20 % of the ELV;for an ELV of 1 mg/Nm3 this means that the
maximum allowable uncertainty should not exceed 0.2 mg/Nm3; this is less
than the limit of detection of the standard (UK 33).
Additional footnotes
Add a footnote to emissions from singeing mentioning that the upper end of the range
could be 20 mg/Nm3 if cotton is singed with medium- and low-quality cotton and
organic cotton, because this might cause higher emissions of burnt cotton dust, e.g.
due to low staple length, increased hairiness (DE 214).
Add a footnote to emissions from thermal treatment mentioning that the BAT-AEL
does not apply if natural gas is used as fuel (EURATEX 57).
Processes concerned
Dust emissions have been reported for 83 EPs associated with thermal treatment. This
does not concern heat production, which is not in the scope of the BAT conclusions.
Of these 83 EPs, 77 are connected to direct heating (i.e. the flue-gas is in contact with
the textile) and 64 of these 77 EPs are connected to direct heating with natural gas.
The dust emissions from these 64 EPs range from 0 mg/Nm3 to 24.1 mg/Nm3.
Of the 83 EPs associated with thermal treatment, 4 are connected to indirect heating
and report dust emissions from 0.5 mg/Nm3 to 4 mg/Nm3.
This shows that dust emissions are also relevant in those cases, possibly coming from
the textile material itself.
Dust emissions from fabric production have been reported from 13 EPs and range
from 1.1 mg/Nm3 to 23 mg/Nm3. However, after further analysis, it appears that these
13 EPs are all connected to thermal treatment (e.g. to dryers or stenters) and not to the
fabric production itself (e.g. knitting or weaving).
Dust may also be generated from handling process chemicals in the form of powder
but little data were reported about such emissions (the EPs concerned are IT072_{3},
IT072_{4} and IT_96_{1}).
Besides singeing, dust emissions seems to be generated as a thermal treatment step in
processes such as dyeing (e.g. PT109_{5}, ES058_{24}, IT137_{6}), printing (e.g.
PT108_{10}, ES058_{28}) or finishing (e.g. CZ015_{4}, CZ015_{3}, PT117_{4}).
This could be reflected in the title of the table.
Threshold
Regarding the deletion of mass flow thresholds in the TXT sector, see the assessment
EIPPCB
of comments related to Table 5.5 in Section
1.4.8.3.
assessment:
When abatement techniques for dust removal are applied, the lowest mass flows
reported from EPs are around 10-15 g/h. Assuming a moderate abatement efficiency
of 80%, gives an unabated (raw) mass flow of 50 g/h, which is considered an
appropriate mass flow threshold for the relevant EPs from the textile processes.
For the emission points without abatement which have:
o either an emission mass flow below 50 g/h;
o or an emission concentration below 10 mg/Nm3 (proposed upper end of
BAT-AEL).
the average gas flow is 4 800 Nm3/h and the median is 3 100 Nm3/h.
Based on the small mass flows emitted, around 63% of the EPs without abatement
fulfil both conditions, it is considered that these EPs are not significant. This could be
reflected by adding a footnote to acknowledge when the BAT-AEL applies.
CMR substances could be bound on particulate matter (dust). Such dust emissions
could have significant environmental impact, therefore, the emission point would
need to comply with BAT-AEL.
BAT-AEL range
According to the data collection, fabric filters are not used for the processes targeted
in Table 5.6.
The BAT-AELs proposed in D1 are based on the values reported via the data
collection. The reported values are values measured at the emission points, therefore
including dust from the combustion and from the textile itself and it is not clear why
the upper end of the range should be increased to 20 mg/Nm3.
The proposed upper end of the range is based on the data collection and reflects the
120
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 118
Background paper – Final meeting for the review of the TXT BREF
emission levels which are achieved by plants of the data collection when applying
one or a combination of the techniques listed in BAT 24. If an unabated emission
point cannot achieve this level, it may be necessary to install an abatement technique
but it is not clear why it would not be possible due to product quality.
Concerning the lower end of the range, while the measurement uncertainty could
increase as a percentage at lower emission levels, it should be noted that 17 EPs have
reported dust emission levels below 1 mg/Nm3.
It is also stated in EN 13284-1 that increasing the “sampling time to 60 min or to 90
min would naturally improve significantly the reproducibility of measurements”.
The proposed lower end of the range is also consistent with the levels that have been
considered appropriate for other BAT conclusions (e.g. STS).
Additional footnotes
No information has been collected via the data collection or made available about the
dust emissions to air from singeing of medium- and low-quality cotton or organic
cotton.
As mentioned above, dust emissions to air have also been reported from thermal
treatment burning natural gas, possibly coming from the textile material itself.
To amend the title of Table 5.6 to identify the processes for which the BAT-AEL
EIPPCB
applies.
proposal:
To add a new footnote to restrict the applicability of the BAT-AEL based on the dust
mass flow.
1.4.8.6
Techniques for reducing channelled ammonia emissions to air
Location in
P. 739 – Section 5.1.8 – BAT 25
D1:
BAT 25. In order to reduce channelled ammonia emissions to air, BAT is to
use wet scrubbing.
Current
text in D1:
Description
See Section 5.9.2.
Summary
Add adsorption as an additional technique because otherwise the BAT is prescriptive.
of
In addition, the applicability of the BAT may be limited by the waste water treatment
comments:
plant capacity (CEFIC 13).
As mentioned in the General considerations, these BAT are neither prescriptive nor
EIPPCB
exhaustive. Other techniques may be used that ensure at least an equivalent level of
assessment:
environmental protection.
EIPPCB
To mention in the BAT statement the processes from which the emissions originate
proposal:
(see the assessment of BAT 24 in Section
1.4.8.4).
1.4.8.7
BAT-AEL for channelled ammonia emissions to air
Location in
P. 739 – Section 5.1.8 – BAT 25 –Table 5.7
D1:
Table 5.7:
BAT-associated emission level (BAT-AEL) for channelled ammonia
emissions to air
BAT-AEL (1)
Mass flow
Current
(Average over
threshold
text in D1:
Substance/Parameter
Activities / Processes
the sampling
(g/h)
period)
(mg/Nm3)
Coating
NH3
3–10
50
Printing
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
121
link to page 40 link to page 111
Background paper – Final meeting for the review of the TXT BREF
Thermal treatment in
finishing
Thermal treatment in
printing
(1) The BAT-AEL only applies when NH3 is identified as relevant in the waste gas stream based
on the inventory of inputs and outputs mentioned in BAT 2.
The associated monitoring is given i
n 0.
Delete the mass flow threshold as many emission points below the proposed mass
flow threshold are within the BAT-AEL range and therefore BAT. There are many
plants below 50 g/h using abatement techniques and about 64 % (16 emission points
out of 25) of the emission points are below 50 g/h and excluded from the BAT-AEL
(AT 28).
Increase the upper end of the range to 20 mg/Nm3 for fire retardant processes as the
proposed upper and of the range is not achievable for such processes (e.g. when using
Summary
ammonium sulphamate) (FR_B 7, EURATEX 59).
of
Add a footnote mentioning that the upper end of the range is 30 mg/Nm3 for plants
comments:
producing technical textiles, PPE (personal protection equipment) or other textiles
which need to comply with safety standards such as flame retardance. This is because
flame retardant finishing of technical textiles and PPE leads to higher NH3 emissions
and wet scrubbing is not applicable as a low waste gas temperature leads to adverse
conditions of the waste gas (DE 347, EURATEX 161).
Concerning the lower end of the range, the value proposed of 3 mg/Nm3 is likely to
lead to additional monitoring costs for the operator associated with monitoring for
longer periods in order to achieve the stated limit of detection required (UK 34).
Regarding the deletion of mass flow thresholds in the TXT sector, see the assessment
of comments related to Table 5.5 in Section
1.4.8.3.
Only 4 our if 34 plants reporting ammonia emissions use appropriate abatement
technique (i.e. wet scrubbing). They report mass flows from 21 g/h to 168 g/h. 27 EPs
that report not using the abatement techniques have mass flows from 0.1 g/h to 666
g/h. The related processes included coating, printing and finishing (same as the plants
using abatement), but also others like dyeing and shrink-proofing. It is not clear why
they do not use abatement techniques, since none of them reported using process
integrated techniques e.g. to reduce urea use in printing.
Following the interventions of the different TWG members during the informal
meeting of 19/02/2021, it seemed that there was not a common position on how to
determine which of these emission points are considered relevant and would need to
comply with BAT-AEL, and which are irrelevant (or insignificant in terms of
environmental impact) and would not need to comply with BAT-AEL. Therefore, the
mass flow threshold for this parameter will not be proposed.
Based on the data collection many of the emission points related to Functional
EIPPCB
finishing. It was not clear whether they are originating from the wet treatment or the
assessment:
following thermal treatment step. Therefore, it was considered best to specify that
BAT-AELs relate to thermal treatment associated with finishing (and other processes
included in Table 5.7 like coating and printing).
Concerning the upper end of the range, Plant BE010 uses ammonium sulphamate for
flame-retardance finishing, which could explain the level of NH3 emissions (up to a
concentration of 16 mg/Nm3 and a mass flow of 264 g/h). However, this plant does
not use wet scrubbing to abate the ammonia emissions to air and it is not clear why
the upper end of the range should be increased to 20 mg/Nm3 or 30 mg/Nm3. Since
this substance is alternative to using brominated flame-retardants the footnote for
increased upper end of the BAT-AEL range could accommodate the plants using it.
It is not clear how a low waste gas temperature would prevent the use of wet
scrubbing. In addition, the waste gas temperature reported by Plant BE010 is between
64 °C and 95 °C.
Concerning the lower end of the range, it may indeed be necessary to extend the
sampling duration according to standard EN ISO 21877. In D1, this is reflected in
Footnote (1) of the table for emissions to air in the General considerations.
EIPPCB
To add that all Activities/Processes concerned include associated thermal treatment.
proposal:
Delete the mass flow threshold.
122
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
To add footnote for upper end of the range in case of using ammonia-based
substances in flame retardant finishing.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
123
Background paper – Final meeting for the review of the TXT BREF
1.4.8.8
Techniques for reducing emissions of organic compounds to air
from thermal treatment of synthetic textile materials
Location in
P. 740 – Section 5.1.8 – BAT 27
D1:
BAT 27. In order to reduce emissions of organic compounds to air from the thermal
treatment of synthetic textile materials, BAT is to wash them.
Current
text in D1:
Description
Synthetic textile materials are washed prior to thermal treatment. If needed, the washing
water is sent to treatment (see BAT 19).
Link this BAT to BAT 23 as it also concerns emissions of organic compounds to air
(FR_A 17).
Add the following words at the end of the BAT statement “(…) or use techniques to
reduce the emissions to air” because in certain applications it is necessary to apply
thermofixation to thin synthetic textiles before washing them (SE 31).
Add the possibility of treatment of emissions to air as an alternative to washing
Summary
(EURATEX 60).
of
Add other techniques or open the formulation, because otherwise the BAT would be
comments:
prescriptive as it mentions only one technique (CEFIC 15).
Add an applicability clause to consider that:
o depending on product specifications, such a washing is not applied;
o depending on the pace of production, washing the fabric may lead to mould
development (FR_A 17).
Clarify when a treatment is needed for the washing water because it is not obvious
why the washing water would not need any treatment. (FR_A 18).
BAT 27 is about emissions of organic compounds. As it is a primary technique (i.e.
process-integrated technique) and not a secondary technique (i.e. abatement
technique), it would be clearer and more logical to have this BAT placed immediately
before BAT 23. The same applies for BAT 26.
Section 4.4.6 of D1 mentions that some synthetic knitted fabrics need to be
thermofixed before washing; however, no further details are available.
This being said, Section 4.4.6 of D1 focuses on synthetic knitted fabrics and not on
synthetic fibres because knitted fabrics may contain more residual preparation agents
than woven fabrics, in particular knitting oil, which may end up in emissions to air if
the fabrics are not washed before thermal treatment. This could be reflected in
BAT 27.
The thermal treatment which is referred to here is thermofixation. As mentioned in
Section 2.6.4.1 of D1, thermofixation is a step of the pretreatment of synthetic textile
EIPPCB
material. This could be reflected in BAT 27.
assessment:
Concerning the applicability restriction due to textile characteristics such as thin
fabrics or due to product specifications, no information has been made available as to
why the textile material concerned needs to undergo thermofixation before washing.
As mentioned in the General considerations, BAT are neither prescriptive nor
exhaustive. Other techniques may be used that ensure at least an equivalent level of
environmental protection.
Concerning the development of mould on wet textile materials, this seems rather to be
an operational consideration which can be addressed when planning the production
operations.
The washing water contains the preparation agents removed from the textile materials
(e.g. knitting oil) but could in principle be reused without treatment if the content of
impurities allows (see BAT 9). In any case, the reuse and treatment of water is
already covered by other BAT and it does not seem necessary to repeat it in BAT 27,
the focus of which is emissions to air.
To move BAT 27 before BAT 23.
EIPPCB
To focus BAT 27 on the washing of knitted synthetic fabrics prior to thermofixation.
proposal:
To delete the reference to water treatment.
124
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.5
BAT conclusions for the pre-treatment of raw wool fibres
by scouring
1.5.1
Techniques for using resources efficiently and for reducing
water consumption and waste generation
Location in
P. 742 – Section 5.2 – BAT 29
D1:
The BAT conclusions in this section apply to the pre-treatment of raw wool fibres by
scouring and apply in addition to the general BAT conclusions in Section 5.1.
BAT 29. In order to use resources efficiently as well as to reduce water consumption
and waste water generation, BAT is to recover wool grease and recycle waste water.
Current
text in D1:
Description
Waste water from wool scouring is treated (e.g. by a combination of centrifugation and
sedimentation) to separate grease, dirt and water. Grease is recovered, water is partially
recycled to scouring and dirt is sent to further treatment.
Summary
of
No comments.
comments:
EIPPCB
Not applicable.
assessment:
EIPPCB
No change.
proposal:
1.5.2
BAT-AEPLs for the recovery of wool grease from the pre-
treatment of raw wool fibres by scouring
Location in
P. 742 – Section 5.2 – BAT 29 – Table 5.8
D1:
Table 5.8:
BAT-associated environmental performance levels (BAT-AEPLs)
for the recovery of wool grease from the pre-treatment of raw wool fibres
by scouring
BAT-AEPL
Type of wool
Unit
(Yearly average)
Coarse wool (i.e.
wool fibre
Current
11–15
diameter typically
text in D1:
higher than 35 µm)
kg of recovered grease per tonne of
Extra and super
raw wool pre-treated by scouring
fine wool (i.e.
wool fibre
50–60
diameter typically
lower than 20 µm)
The associated monitoring is given in BAT 5.
Amend the proposed BAT-AEPL range for kg of wool grease recovered from coarse
wool to 10-15 kg/t. The data submitted from the 2 UK plants show that the average
achieved over the last 3 years would fit a range of 10-15 kg/t of raw wool processed
Summary
and not a range of 11-15 kg/t (UK 36).
of
Change the BAT-AEPL range for “Extra and super fine wool” to 40-60 kg of
comments:
recovered grease per tonne of raw wool pretreated by scouring. Indeed, due to global
warming and worse conditions for sheep breeding in general, the lower value of
50 kg/t has shifted to 40 kg/t for some wool (CZ_B 75).
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
125
Background paper – Final meeting for the review of the TXT BREF
The BAT-AEPLs have been determined on the basis of the data collection.
According
to the data reported by UK128 and UK129 for quantity of wool grease recovered
EIPPCB
from coarse wool, there is scope to decrease the lower end of the range to 10 kg/t.
assessment:
Regarding the range for “Extra and super fine wool”, it is not clear on exactly which
data the modified range values could be based.
EIPPCB
To decrease the lower end of the range for quantity of wool grease recovered from
proposal:
coarse wool.
126
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.6
BAT conclusions for the production of yarn and fabric
1.6.1
Techniques for reducing emissions to water
Location in
P. 744 – Section 5.3 – BAT 32
D1:
The BAT conclusions presented in this section apply to the production of yarn
and fabric and apply in addition to the general BAT conclusions in Section 5.1.
BAT 32. In order to reduce emissions to water from the use of sizing
chemicals, BAT is to use all of the techniques given below.
Technique
Description
Applicability
Sizing
chemicals
with
improved
environmental performance in terms of
Current
Selection
of quantity needed, washability, recoverability
text in D1:
a.
sizing chemicals
and/or biodegradability (e.g. modified Generally
starches, certain galactomannans, polyvinyl applicable
alcohol and certain polyacrylates) are used.
The cotton yarns are dipped into hot water
Pre-wetting
of
b.
prior to sizing. This allows a reduction of
the cotton yarns
the amount of sizing chemicals.
The fibre strands are compressed by The applicability
Compact
suction or by mechanical or magnetic may be restricted
c.
spinning
compacting. This allows a reduction of the by
product
amount of sizing chemicals.
specifications
Technique a.
Delete “polyvinyl alcohol and certain polyacrylates” which have a worse
environmental performance, and polyvinyl alcohol is biodegradable only under
certain conditions. In the current Austrian waste water ordinance on textiles, there is
one BAT conclusion recommending the replacement of polyvinyl alcohol (AT 45,
EURATEX 118).
Add that yarns and fabrics with such sizing chemicals are purchased at the end of the
description. This is to clarify that the correct choice of size applies not only to the
choice of the sizing chemical but also to the choice of yarn or fabric purchased
(EEB 42).Add a reference to BAT 36 below the table. Indeed, selecting based on
recoverability is BAT, but so is actually recovering which is described in BAT 36
(EEB 42).
Replace generally applicable with “applicability may be restricted by product
Summary
specifications”. Product specifications sometimes require specific sizing chemicals
of
which cannot be recovered or are not biodegradable (e.g. sizing of PES yarns) (
comments:
EURATEX 63).
Technique b.
Restrict the applicability as follows: "Generally applicable if it does not lead to a
higher energy consumption and if compatible with operational constraints, sizing
equipment or product specifications”. This technique may not be compatible with
high-speed weavers. This can lead to bad "sizing" performance and the cotton fibres
have to be dried for longer; this will increase the energy consumption and need a big
investment for one material only (FR_A 55, EURATEX 58).
Technique c.
Replace "by product specifications" with "in line with the descriptions in Section
4.3.1.2.3" (EEB 110).
Technique a.
According to Sections 4.3.1.2.1, 4.1.7.3.5.4.1 and 4.1.7.4.3 of D1, polyvinyl alcohol
EIPPCB
and certain polyacrylates are indeed only biodegradable under certain conditions, but
assessment:
are widely used. These substances are mentioned in brackets as examples and could
be deleted from the description of technique a.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
127
Background paper – Final meeting for the review of the TXT BREF
This BAT refers to the sizing process, while the choice of yarn or fabric purchased is
covered in BAT 4 (a).
Although sizing chemicals are part of BAT 36 b, a link between both BAT would
apply only when sizing and desizing are done in the same plant.
It is not clear why biodegradable sizing agents could not be used on the polyester
yarns.
Technique b.
According to Section 4.3.1.2.2 of D1, there are no technical restrictions to the
applicability restriction of this technique, and in particular there is no information
about a poorer performance of the sizing step and no reference to the product
specifications or operational constraints. Concerning sizing, existing sizing machines
with two sizing boxes can be upgraded by using the first sizing box for pre-wetting
and the second one for sizing and it is not clear why it could not technically be done.
Finally, concerning the energy consumption, more energy may indeed be needed to
dry the cotton yarns but on the other hand this technique leads to an increase in sizing
machine speed of about 22 %.
Technique c.
Examples from Section 4.3.1.2.3 of D1such as hairiness of the yarns would facilitate
the understanding of the applicability of technique c.
To delete “polyvinyl alcohol and certain polyacrylates” in technique a.
EIPPCB
To add an example in the applicability restriction of technique c.
proposal:
1.6.2
Techniques for using energy efficiently
Location in
P. 745 – Section 5.3 – BAT 34
D1:
BAT 34. In order to use energy efficiently, BAT is to use technique a and one or both
of techniques b and c given below.
Technique
Description
This includes:
reducing the volume of the production area to reduce the
Use of common
a.
amount of energy needed for humidifying the ambient air;
techniques
using advanced sensors that detect thread breaks to stop the
spinning or weaving machines.
This includes:
using lighter spindles and bobbins in ring frames;
using spindle oil with optimal viscosity;
Current
text in D1:
maintaining an optimal oiling level of the yarn;
Use of common
optimising the ring diameter with respect to the yarn
b.
techniques
in
diameter in ring frames;
spinning
gradual start-up of the ring spinning machines;
using vortex spinning;
optimised movement of empty bobbin conveyors in cone
winding machines.
This includes:
Use of common
c.
techniques
in
avoiding excessive air pressure for air-jet weaving;
weaving
using a double-width loom for large-volume batches.
128
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Technique a.
Change the applicability of technique a. to "applicable to new plants or major
upgrades of plants", as a reduction of the volume of the production area requires a
change of the configuration of the installation (FR_A 56, UK 39, CEFIC 25,
Summary
EURATEX 62, EURATEX 162).
of
comments:
Technique c.
Change the applicability of technique c. to "Applicable to new plants or major
upgrades of plants". Changing the whole configuration of the production area is not
always possible (UK 39).
Technique a.
According to Section 4.3.2.1 of D1, one way to reduce the volume of the
production area is to install a suspended ceiling, which does not seem to be a
major plant upgrade which is defined as “a major change in the design or
technology of a plant with major adjustments or replacements of the process.”
EIPPCB
This example could however bring clarity to the technique description.
assessment:
Technique c.
Replacing an existing loom with a double-width loom would indeed be a
major plant upgrade according to the definition mentioned above.
The names of the techniques a, b and c could be related to energy savings to
make them technically more relevant.
To add the example of suspended ceiling in technique a.
EIPPCB
To add an applicability criteria related to the double-width loom in technique c.
proposal:
To amend the name of the techniques a, b and c.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
129
link to page 47
Background paper – Final meeting for the review of the TXT BREF
1.7
BAT conclusions for the pretreatment of textile materials
other than raw wool fibres
1.7.1
Techniques for using energy efficiently and reducing water
consumption and waste water generation
Location in
P. 746 – Section 5.4 – BAT 35
D1:
The BAT conclusions in this section apply to the pre-treatment of textile materials other
than raw wool fibres and apply in addition to the general BAT conclusions in Section 5.1.
BAT 35. In order to use energy efficiently as well as to reduce water consumption
and waste water generation, BAT is to use both of the techniques given below.
Current
text in D1:
Technique
Description
Applicability
Combined pre-
Various pre-treatment operations of cotton Only applicable to
a. tr eatment
of textiles (e.g. desizing, scouring and new plants or
cotton textiles
bleaching) are carried out simultaneously.
major
plant
Cold pad-batch Desizing and/or bleaching are carried out upgrades
b. tr eatment
of with the cold-pad batch technique (see
cotton textiles
Section 5.9.4).
Delete technique a. or link it to BAT 15 since it contradicts enzymatic pretreatment
Summary
(EURATEX 119).
of
Amend the applicability so that both techniques a. and b. are generally applicable.
comments:
The proposed techniques may be implemented even at the occasion of minor
upgrades (SE 33, UK 40).
It is not clear how technique a. contradicts enzymatic pretreatment described in BAT
15.
According to the information in Section 4.4.3 in D1, existing plants with new
machinery suitable for this process could apply this technique. In addition, 20 plants
from the data collection have reported using technique a.
EIPPCB
Regarding an applicability restriction for technique b., according to Section 4.5.1.8 in
assessment:
D1, there are no technical restrictions to the applicability of this technique.
Taking into account that techniques a. and b. of BAT 35 can also be applied to use
resources efficiently, there is justification for merging BAT 35 with BAT 36, as both
have the same environmental objectives.
To provide more examples in the description of technique a. (see assessment done in
Section
1.4.3.1 for technique b.).
EIPPCB
To change the applicability of techniques a. and b.
proposal:
To merge BAT 36 with BAT 35.
1.7.2
Techniques for using resources and energy efficiently and
reducing water consumption and waste water generation
Location in
P. 746 – Section 5.4 – BAT 36
D1:
BAT 36. In order to use resources and energy efficiently as well as to reduce water
consumption and waste water generation, BAT is to use one of the techniques given
below.
Current
text in D1:
Technique
Description
Applicability
A single desizing liquor is used to remove
Single desizing different types of sizing chemicals. This Generally
a.
liquor
solution is strongly alkaline (pH higher applicable
than 13) and contains hydrogen peroxide.
130
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
link to page 130
Background paper – Final meeting for the review of the TXT BREF
When desizing is carried out by washing Only applicable in
with hot water, water-soluble sizing
Recovery
and
plants
where
chemicals (e.g. polyvinyl alcohol and
reuse of water-
sizing
and
b.
polyacrylates) are recovered from the
soluble
sizing
desizing
are
washing water by ultrafiltration. The
chemicals
carried out at the
concentrate is reused for sizing, whereas same plant
the permeate is reused for washing.
Technique a.
Delete technique a. The desizing method depends on the sizing agent used and a
single desizing liquor for all sizing agents is not reasonable (DE 319).
Delete “This solution is strongly alkaline (pH higher than 13) and contains hydrogen
peroxide”. Some sizing agents like polyvinyl alcohol precipitate in alkaline solutions,
so the formulation of the single desizing liquor needs to be adapted (FR_A 60,
EURATEX 64).
Summary
Add that applicability may be restricted by product specifications. The conditions of
of
desizing are not always as mentioned in the technique description, e.g. PES warm
comments:
washing is carried out without hydrogen peroxide (EURATEX 65).
Technique b.
Add that applicability may be restricted by product specifications; not all sizing
chemicals can be recovered from the washing water by ultrafiltration e.g. PES sizing
(EURATEX 66).
Add a reference to BAT 32 (EEB 45).
Technique a.
According to Section 4.4.1 of D1, there are no technical restrictions to the use of the
same desizing liquor for various sizing chemicals. On the contrary, Section 4.4.1
mentions that the use of a single desizing liquor is particularly suitable when several
products are used.
As for the exact characteristics of the desizing solution, this may indeed change to
take into account the specificities related to the sizing chemicals used.
EIPPCB
assessment:
Technique b.
The technique aims to recover water-soluble chemicals from the washing water by
ultrafiltration. According to Section 4.4.8.1 of D1, this technique is suitable for water-
soluble chemicals, as stated in the BAT description.
According to Section 4.4.8.1 of D1, more examples of water-soluble sizing chemicals
could be added.
Although sizing chemicals are part of BAT 32, a link between both BAT would apply
only when sizing and desizing are done in the same plant.
To merge BAT 36 with BAT 35 (see assessment in Section
1.7.1).
EIPPCB
To remove the second sentence in the description of technique a.
proposal:
To add carboxymethyl cellulose as an example of water-soluble sizing chemicals.
1.7.3
Techniques for preventing or reducing emissions to water of
chlorine-containing compounds and complexing agents
Location in
P. 746 – Section 5.4 – BAT 37
D1:
BAT 37. In order to prevent or reduce emissions to water of chlorine-containing
compounds and complexing agents, BAT is to use one or both of the techniques given
Current
below.
text in D1:
Technique
Description
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
131
link to page 74
Background paper – Final meeting for the review of the TXT BREF
Bleaching is carried out with chlorine-free bleaching
Chlorine-free
a.
chemicals (e.g. hydrogen peroxide, peracetic acid or ozone),
bleaching
possibly catalysed with enzymes.
The use of complexing agents can be completely avoided or
minimised by reducing the concentration of hydroxyl
radicals during bleaching. This is achieved by:
Optimised
hydrogen
using demineralised water;
b.
peroxide
prior removal of metal impurities from textile materials
bleaching
(e.g. by magnetic separation or chemical extraction);
controlling the pH and the peroxide concentration during
bleaching.
Technique a.
Delete “possibly catalysed with enzymes” as enzymes are not stable in combination
with peroxide (EURATEX 120).
Add the following applicability clause “the applicability may be restricted by the
characteristics of the textile materials and/or product specifications” (IT 31).
Hypochlorite bleaching is needed for some specific fabrics (EURATEX 67).
Technique b.
Summary
Replace “demineralised water” with “softened water”. Demineralised water is not
of
necessary to reduce the need for complexing agents, and will increase the amount of
comments:
waste baths (CZ_B 12, FR_A 58, EURATEX 67).
Add information on applicability or delete “magnetic separation”; magnetic
separation works with magnetisable elements (DE 320, EURATEX 121).
Delete “chemical extraction” because it is unclear and may imply the use of solvent
(DE 320).
Add an additional bullet point: "pretreatment of textile fabrics (removal of Mn and Fe
residues)” (EURATEX 67).
Technique a.
During the 2nd Data Assessment Workshop held on 21-23 October 2020, EURATEX
clarified that enzymes are used as a pretreatment, before bleaching. This can be
clarified in the description of technique a.
According to the data collection, several plants reported using enzymes in
combination with peroxide for bleaching (DE034, DE040, FR131, IT097 and PT108).
Although this technique seems widely used, examples have been reported where this
technique may not apply, and this could be reflected in the applicability.
Technique b.
EIPPCB
The replacement of “demineralised water” by “softened water” would be in line with
assessment:
the EIPPCB proposal for BAT 15 (see Section
1.4.5.3).
Obviously, magnetic separation will function only with ferromagnetic metals and it
does not seem necessary to mention it in the BAT conclusions.
The term “chemical extraction” refers in fact to two methods which are mentioned in
Section 4.4.7.2 of D1: acid demineralisation and reductive treatment. This term can
indeed be misleading as it could be understood from it that solvent is used. This could
be clarified by replacing “extraction” with “treatment”.
Pre-washing of textiles could also be used to reduce the presence of metal impurities.
According to Section 4.4.7 of D1, it is relevant to check the decomposition of
hydrogen peroxide. This could be clarified in the description.
To clarify the use of enzymes in the description of technique a.
To add an applicability restriction to technique a.
EIPPCB
To replace the terms “demineralised” and “chemical extraction” and to add a
proposal:
reference to pre-washing in technique b.
To clarify the need to control of the hydrogen peroxide concentration.
132
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.7.4
Technique for using resources efficiently and for reducing the
amount of alkali discharged to the waste water treatment
Location in
P. 747 – Section 5.4 – BAT 38
D1:
BAT 38. In order to use resources efficiently and to reduce the amount of
alkali discharged to waste water treatment, BAT is to recover caustic soda
used for mercerisation.
Current
text in D1:
Description
Caustic soda is recovered from the rinsing water by evaporation and further
purified, if needed.
Modify the applicability as it may be restricted by product specifications, or add an
applicability criteria to new plants or plants with major upgrade. Difficulties to
reconcentrate the soda can occur (EURATEX 76).
Summary
Add an applicability restriction as when distillation process recovers alkali from
of
mercerising, the alkali rinsing water is heated up and the water is evaporated and
comments:
condensed. Distillation needs a lot of energy to heat the liquor and evaporate the
water (EURATEX 122).
It is not clear technically which difficulties can restrict the applicability of this
technique. According to the data collection, several plants that have different products
achieve the proposed BAT-AEPL.
EIPPCB
According to the data collection, several plants (e.g. FR134, DE030, PT108, UK127
assessment:
ES058 and BE013) are using this technique and did not report more energy
consumption than other plants not using evaporation to recover caustic soda from the
rinsing water.
EIPPCB
No change.
proposal:
1.7.5
BAT-AEPL for the recovery of caustic soda used for
mercerisation
Location in
P. 747 – Section 5.4 – BAT 38 – Table 5.9
D1:
Table 5.9:
BAT-associated environmental performance level (BAT-AEPL) for
the recovery of caustic soda used for mercerisation
BAT-AEPL
Parameter
Unit
(Yearly average)
Current
Recovery of caustic soda used for
text in D1:
%
75–95
mercerisation
The associated monitoring is given in BAT 5.
Summary
No comments.
of
comments:
EIPPCB
Not applicable.
assessment:
EIPPCB
To simplify the table.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
133
Background paper – Final meeting for the review of the TXT BREF
proposal:
134
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
1.8
BAT conclusions for dyeing
Location in
P. 748 – Section 5.5.
D1:
Current
Entire Section 5.5.
text in D1:
Shorten and simplify the techniques, just including the major ones with proven
environmental impact and proven applicability. Indeed a lot of BATs include
extensive lists of techniques, which are extremely detailed for different sub-processes,
types of dyes, raw materials etc. This degree of detail leads to an unnecessary
complexity, which might complicate the implementation of the BAT conclusions via
permits and/or national binding rules. In addition, a number of BATs might contradict
each other, are common practice (e.g. pH control), are just dyeing processes without
any reference to a specific BAT (e.g. cold pad-batch dyeing), are not applicable at all
(e.g. vat dyeing without steaming), are wrong interpretations of BAT candidates in
Chapter 4 (e.g. printing carried out without urea) (DE 393).
Specify the techniques called "optimised process" (or using similar expressions). The
added value of the BAT conclusions would be higher if there was a common picture
Summary
in Europe on what "optimised processes" are. In the descriptions of the BAT
of
conclusions there are examples of those processes, but the relevance of the
comments:
descriptions is quite low in comparison with the technique itself (DE 393).
Add in BAT 39 and BAT 40 a missing technique which is described in
Section 4.5.1.4 of D1 (optimised removal of unfixed dyestuff in reactive dyeing)
(CZ_B 13):
Technique
Description
Applicability
Unfixed
dyestuff
is
removed from the textile
Optimised removal of materials
by
using
unfixed dyestuff in enzymes
and/or
vinyl Generally applicable
reactive dyeing
polymers. This reduces the
number of rinsing steps
needed.
Concerning the comments about the complexity of the BAT conclusions related to
dyeing and the use of the wording “optimised process”, they are relatively general
and are not specific as to why exactly they would need to be changed. See the BAT-
specific assessments below for the assessment of specific proposals for modifications.
EIPPCB
Concerning the additional technique proposed, it is already proposed in BAT 39c in
assessment:
D1. The proposed addition about the reduction of rinsing steps could bring further
clarity though.
It is not clear why this technique would need to be repeated in BAT 40 which is
specific to cellulosic fibres.
EIPPCB
To add a reference to the reduction of rinsing steps in BAT 39c.
proposal:
1.8.1
Techniques for using resources efficiently and reducing
emissions to water
Location in
P. 748 – Section 5.5 – BAT 39
D1:
The BAT conclusions in this section apply to dyeing and apply in addition to the
general BAT conclusions in Section 5.1.
Current
BAT 39. In order to use resources efficiently and to reduce emissions to
text in D1:
water from dyeing, BAT is to use one or a combination of the techniques
given below.
Technique
Description
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
135
Background paper – Final meeting for the review of the TXT BREF
Technique for batch and continuous dyeing
Dyes without dispersing agents are used or, where this is
a.
Selection of dyes
not
possible,
with
dispersing
agents
that
are
biodegradable (e.g. based on fatty acid esters).
Techniques for batch dyeing
For textile materials with zwitterionic characteristics,
dyeing is carried out at constant temperature and
b.
pH-controlled dyeing
controlled by gradually lowering the pH of the dyeing
liquor below the isoelectric point of the textile materials.
Optimised removal of Unfixed dyestuff is removed from the textile materials
c.
unfixed
dyestuff
in by using enzymes (see BAT 15 b) and/or vinyl polymers.
reactive dyeing
Technique a.
Delete the use of dyes without dispersing agent because disperse dyes cannot be
formulated and applied in water-based systems without dispersing agents. Indeed,
disperse dyes are only in a metastable state and will precipitate quickly without
dispersing agents (DE 236, EURATEX 123).
Expand technique a. to a more general technique on the selection of dyes because
technique a. is too restrictive and move the use of biodegradable dispersing agents to
BAT 42 (UK 41).
Technique b.
Add that the pH for wool dyeing depends on the dyestuff class and is normally
selected in a manner so that exhaustion of the dye is maximal and wool damage kept
Summary
at a minimum (DE 321).
of
Move technique b to BAT 40 and BAT 41 because it is also relevant for continuous
comments:
dyeing and expand it as follows because it is too restrictive: “dye profiles and
chemical additions are optimised and controlled, i.e. amounts of dye and chemical,
temperatures and pH control to the material being dyed.” (UK 41).
Technique c.
Delete technique c. because there is no known application (DE 237).
Delete technique c. because it is in contradiction with BAT 40f (EURATEX 69).
Add that the applicability of this technique is restricted by the characteristics of the
textile materials and/or product specifications (IT 32).
Move technique c. as worded to BAT 40 and expand technique BAT 39c. as follows:
“Unfixed dye removal is optimised to reduce water and surfactant use while
maintaining the required fastness specifications” (UK 41).
Technique a.
Section 4.5.1.1 of D1 mentions that pre-reduced liquid sulphur dyes without
dispersing agents are provided for all kinds of fabric. Nothing similar is mentioned
for other types of dyes. After further investigation, no clear evidence has been found
that dispersant-free dyes were used on an industrial scale, for any type of dyes.
The selection of dyes is already addressed in BAT 13 as all other process chemicals.
According to Section 8.6.3 of D1, dispersing agents are contained in vat, sulphur and
disperse dyes and may be added in other classes of dyes. The technique therefore fits
better in BAT 39 which concerns all types of dyes than in BAT 42 which concerns
only disperse dyes.
EIPPCB
assessment:
Technique a1.
New information was submitted to EIPPCB by the TWG (supporting document to
comment DE 408). The technique promotes dyeing with levelling agents from
recycled vegetable oil. These agents can be used in batch or continuous processes.
Technique b.
This technique is used for fibres with zwitterionic behaviour such as wool,
polyamide, silk, etc. Section 4.5.1.5 of D1 does not contain specific information about
the pH selection for wool dyeing and no information has been made available about
this. Moreover, the technique does not concern the selection of pH as such but
136
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
describes the principle of controlling the dyeing process by progressively lowering
the pH.
pH is indeed not the only parameter to be controlled for dyeing. Amounts of dye and
auxiliary chemicals, temperature and amount of textile materials are also important
parameters that need to be controlled and monitored. This is covered by BAT 3.
BAT 39 does not refer to the monitoring and control of dyeing parameters in general
but to a specific technique, only applicable to textile material with zwitterionic
characteristics, which consists of keeping the temperature constant and changing the
pH instead of keeping the pH stable and changing the temperature, which allows
energy savings. It is not clear whether this technique can be used for continuous
dyeing.
Technique c.
Technique c. has been reported by Plants IT089 and IT090.
Both BAT 39 and BAT 40 state that BAT is to use one or a combination of the
techniques described in these BAT. It means that technique BAT 39c and BAT 40f
are not necessarily used at the same time. Moreover, deleting technique BAT 39c
would result in a loss of information as it does not concern only dyeing of cellulosic
materials (which is the case of BAT 40).
It is not clear which characteristics of the textile materials and/or product
specifications may limit the applicability of this technique.
The optimised removal of unfixed dyestuff does not concern only dyeing of cellulosic
fibres and seems therefore better placed in BAT 39 than in BAT 40.
Concerning the proposed wording, the objective of the technique is indeed to have an
optimal removal of unfixed dyestuff, in the sense that it reduces water and surfactant
use while maintaining the required fastness specifications. However this does not
describe the technique, i.e. how it is done.
To remove the reference to dispersant-free dyes from the description of technique a.
EIPPCB
To add new technique a1 on dyeing with levelling agents made from recycled
proposal:
vegetable oil.
Location in
P. 748 – Section 5.5 – BAT 40
D1:
BAT 40. In order to use resources efficiently and to reduce emissions to
water from the dyeing of cellulosic materials, BAT is to use one or a
combination of the techniques given below.
Technique
Description
Applicability
Technique for dyeing with sulphur dyes
Dyeing is carried out without sodium
sulphide or hydrosulphite as reducing The applicability
Minimised use agents.
may be restricted
a. o f sulphur-based Where this is not possible, partially by
product
reducing agents
chemically pre-reduced dyes (e.g. indigo
Current
specifications
dyes) are used so that less sodium sulphide
text in D1:
or hydrosulphite is added for dyeing.
Technique for continuous dyeing with vat dyes
May
not
be
Vat dyes are selected to enable dyeing
Selection of vat
applicable
to
b.
without subsequent steaming, oxidising and
dyes
dyeing with dark
washing.
shades
Techniques for dyeing with reactive dyes
Use of high-
Use of poly-functional reactive dyes with
c. fi xation reactive more than one reactive functional group.
Generally
dyes
applicable
Use of cationic Dyeing is carried out on cationic cotton,
d.
cotton
which does not require the use of salts.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
137
Background paper – Final meeting for the review of the TXT BREF
Only applicable to
Cold pad-batch Dyeing is carried out with the cold pad-
new
plants
or
e.
dyeing
batch technique (see Section 5.9.4).
major
plant
upgrades
Rinsing after dyeing with reactive dyes is
carried out at a high temperature (e.g. up to
Optimised
Generally
f.
95 °C) and without using detergents. The
rinsing
applicable
heat of the rinsing water is recovered (see
BAT 10 f).
Techniques for continuous dyeing with reactive dyes
In
cold
pad-batch
dyeing
(see May
not
be
Use
of Section 5.9.4.), concentrated aqueous alkali applicable
to
g.
concentrated
solutions without sodium silicate are used dyeing with dark
alkali solution
for the fixation of dyes.
shades
The applicability
may be restricted
by
the
The reactive dyes are fixed with steam,
Steam fixation
characteristics of
h.
which avoids the use of chemicals for
of reactive dyes
the
textile
fixation.
materials and by
product
specifications
Technique a.
Change the applicability restriction to “generally applicable” as the only restriction
mentioned in Chapter 4 of D1 is that some colours may not be available. The
restriction based on product specifications is too wide (EEB 111).
Make reference to sulphur and vat dyes (as should Section 4.5.2.1 of D1) to put this
technique into context. In addition, specify the use of alternative reducing agents as
given in Section 4.5.2.1 especially the use of glucose which has been widely adopted
(UK 42).
Technique b.
Delete technique b. because vat dyeing cannot be carried out without steaming and
oxidising (DE 322, EURATEX 124).
Technique c.
Change the applicability of the technique to reflect that it may be restricted by the
characteristics of the textile materials and/or product specifications (IT 33, UK 42).
Mention that the degree of fixation not only depends on the number of reactive
groups but also on the affinity and build-up behaviour of a dye molecule (DE 322).
Summary
Technique d.
of
Delete technique d. because the chemicals to produce cationic cotton are carcinogenic
comments:
and skin-sensitive (DE 239, DE 322).
Change the applicability of the technique to reflect that it may be restricted by the
product specifications (EURATEX 68) and/or characteristics of the textile materials
(UK 42).
Technique e.
Delete technique e. because it does not have added value: cold pad-batch is one of the
most simple applications and is widely used (DE 322).
Technique f.
Change the applicability of the technique to reflect that it may be restricted by the
characteristics of the textile materials and/or product specifications (IT 34).
Change the applicability of the technique to new plants or major plant upgrades and if
it is economically feasible. Indeed the thermal energy needs to be sufficiently high for
recovery and there needs to be a use for the recovered heat (EURATEX 70).
Combine technique f. with BAT 39c. as they are both about the same technique but
cover different aspects (UK 42).
In view of energy use, this BAT is questionable. There are new generation dyes
available which offer the opportunity to wash off at lower temperature, with less
138
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
water and reduced washing off agents (DE 322).
Technique g.
There are different application processes: processes with no sodium silicate
(processes using caustic soda or a combination of caustic soda and soda ash) are more
popular (DE 322).
Technique h.
Specify the applicability restrictions with information from Chapter 4 of D1 as it is
too vague (EEB 112).
Pad steam dyeing is a normal application process (DE 322).
Technique a.
Section 4.5.2.1 of D1 explains that the use of alternative reducing agents may lead to
differences of shade compared to common sulphur dyeing. The shade required by the
product specifications may therefore limit the applicability of this technique and this
could be reflected in the BAT conclusions.
Section 2.7.3.3 of D1 mentions that the reducing agents used for vat dyes are mainly
hydrosulphite and sulphoxylic acid derivatives (zinc sulphoxylate), the latter being
used when the pad-steam process is applied. It is mentioned that sulphur-free organic
reducing agents such as hydroxyacetone are also available for some applications.
According to Section 9.1 of D1, indigo dyes are a kind of vat dye.
Technique b.
Section 4.5.1.2. of D1 mentions that in some cases vat dyeing can be carried out
without steaming and subsequent washing (pad-dry process). No comments were
made on Section 4.5.1.2 and it is not clear why this technique is not feasible.
Furthermore, no conclusion was taken at the Kick-off meeting to remove this
technique.
This technique was reported by plant PT 105.
Technique c.
Concerning the applicability of this technique, the comments are not specific as to
which textile materials and/or product specifications would limit its applicability.
The degree of fixation of a dye depends indeed on its substantivity for the fibre.
Technique c however is specific to use of polyfunctional reactive dyes, not to the
high-fixation dyes in general, which could be clarified in the name of the technique.
EIPPCB
assessment:
Technique d.
It is not clear which product specifications or textile materials may limit the use of
cationic cotton.
According to one comment received on Section 4.1.5.3.2 of D1, cationisation solution
is produced and distributed by INOTEX (CZ). Cationisation is therefore a technique
which is used.
The cationisation agent is 3-chloro-2-hydroxypropyltrimethylammonium chloride
(CHPTAC) which is suspected to be carcinogenic. In the waste water from the
cationisation process, CHPTAC goes through an intermediate reactive stage and
forms 2,3-epoxypropyltrimethylammonium chloride (EPTAC), which is carcinogenic
and a skin sensitiser. Section 4.1.5.3.2 of D1 mentions alternative eco-friendly
substances to CHPTAC based on chitosan but these are still under development.
Technique e.
A total of 7 of the 105 plants from the data collection have reported using cold pad-
batch dyeing (DE026, IT059, IT064, IT065, IT068, IT094 and PT114). This shows
that, although well-known, this technique is not overwhelmingly used.
Technique f.
It is not clear which product specifications or textile materials may limit the
applicability of this technique.
BAT 39c and BAT 40f present two options for optimal rinsing, which are not
necessarily carried out at the same time. In that sense, both techniques could be
merged. However, BAT 39c is relevant for all types of dyes while BAT 40f concerns
only reactive dyes; it seems therefore clearer to keep them separated.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
139
Background paper – Final meeting for the review of the TXT BREF
No information has been provided about the new generation of dyes which offer the
opportunity to wash off at lower temperature, with less water and reduced washing
off agents.
Technique g.
It is not clear what changes are proposed by the comment.
Technique h.
Section 4.5.2.6 of D1 mentions that this technique is not applicable, for example, for
high-grade dyeing of PES/CO working clothes, which could usefully specify the
applicability restriction.
Concerning pad-steam dyeing, it is indeed a current process but it is not clear what
changes are proposed by the comment.
To extend the relevance of technique a to vat dyes.
To specify the applicability restriction of technique a.
EIPPCB
To clarify that technique c is about the use of polyfunctional reactive dyes.
proposal:
To delete technique d.
To specify the applicability restriction of technique h.
140
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
Location in
P. 749 – Section 5.5 – BAT 41
D1:
BAT 41. In order to reduce emissions to water from the dyeing of wool, BAT
is to use one of the techniques given below in the following order of priority.
Technique
Description
Applicability
The applicability
Chromium-free
Wool dyeing is carried out with reactive or may be restricted
a.
dyeing
acid dyes.
by
product
specifications
Dyeing is carried out with metal-complex
Current
The applicability
Optimised
dyes under optimised conditions in terms of
text in D1:
may be restricted
b.
metal-complex
pH, auxiliaries and acid used, in order to by
product
dyeing
increase the exhaustion of the dyeing liquor specifications
and the fixation of the dyes.
When the use of chromates is authorised,
chromates are dosed as a function of the
amount of dye taken up by the wool.
Minimised use
Generally
c.
Dyeing
parameters
(e.g.
pH
and
of chromates
applicable
temperature of the dyeing liquor) are
optimised to ensure that the dyeing liquor
is exhausted as much as possible.
Technique a.
Specify and justify the applicability restriction, considering the technical information
given in Chapter 4 of D1 or, if not possible, delete the applicability restriction
(EEB 100, EEB 113).
Specify the applicability restriction as follows: “the applicability may be restricted by
product specifications, e.g. where black or very dark shades are essential and cannot
be produced by other reactive or acid dyes.” Indeed chromium-free dyeing should be
widely practised by now across the wool industry and any continuing use should
require detailed justification (UK 43).
Specify the content below which a dye would be chromium-free (0.1 %/kg in dye)
and quote the relevant standard as chemical analytical methods are limited by their
Summary
limit of detection and limit of quantification (CEFIC 16).
of
comments:
Technique b.
Change the applicability restriction to generally applicable because no technically
meaningful explanation for possible restriction is given in Section 4.5.3.2 of D1
(EEB 114).
Technique c.
Delete technique c. because the use of chromates is not BAT and chromates can
always be substituted (there are chromium-free alternatives for wool and PA dyeing)
(DE 323).
Replace “chromates” with “dichromates”, which is technically the correct term
(EURATEX 71).
Technique a.
According to Section 4.5.3.1 of D1, the use of technique a may be limited by the
required fastness and shade, which could usefully specify the applicability restriction.
The BAT statement is clear about the order of priority of the three techniques:
technique a is prioritised over the other two except when product specifications (e.g.
fastness or shade) limit its application.
The wording “chromium-free” does not refer to the absence of chromium as an
EIPPCB
impurity but to the use of dyes with formulations which are not based on chromium,
assessment:
i.e. not metal-complex or do not require chromium mordant i.e. chrome dyes. Some
reactive dyes do not require chromium mordant as is reflected by the description of
the technique but could be clarified in the technique name.
Technique b.
Metal-complex dyes are brighter than chrome dyes but duller than acid dyes;
therefore metal-complex dyes may not be applicable when very dark shades are
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
141
Background paper – Final meeting for the review of the TXT BREF
needed.
Technique c.
Technique c is not about the use of dichromates but about the minimised use of
dichromates when this use has been authorised as per Article 60 of the REACH
Regulation.
The analysis of alternatives to the use of dichromates is part of the authorisation
procedure (see Article 62 of the REACH Regulation) and is done on a case-by-case
basis.
Sodium or potassium dichromate is used for chrome dyeing, which could be better
reflected in technique description.
To specify the applicability restriction of technique a and modify the technique name.
EIPPCB
To specify the applicability restriction of technique b.
proposal:
To change the wording of technique c to reflect the use of dichromates.
Location in
P. 749 – Section 5.5 – BAT 42
D1:
BAT 42. In order to reduce emissions to water from the dyeing of polyester
with disperse dyes, BAT is to use one or a combination of the techniques
given below.
Technique
Description
Applicability
Batch dyeing of polyester and wool-free
Batch
dyeing polyester blends is carried out at high
a.
without dyestuff temperature (e.g. 130 ºC) without the use of
carriers
dyestuff carriers.
Generally
Optimised
use
applicable
Batch dyeing of polyester-wool blends is
of
dyestuff
b.
carried
out
with
chlorine-free
and
carriers in batch biodegradable dyestuff carriers.
dyeing
The use of a
reducing
agent
Current
that can be used in
text in D1:
This includes:
acidic conditions
using a desorption accelerator based on may
not
be
carboxylic acid derivatives;
applicable
to
Optimised
using a reducing agent that can be used polyester-elastane
desorption
of
c.
in the acidic conditions of the spent blends.
unfixed dye in
dyeing liquor;
The use of dyes
batch dyeing
using disperse dyes that can be desorbable
in
desorbed in alkaline conditions by alkaline
hydrolysis instead of reduction.
conditions may be
restricted
by
product
specifications
Supercritical CO2 is used as a dyeing Only applicable to
Supercritical
medium instead of water in a closed loop new
plants
or
d.
CO2 dyeing
process to transport disperse dye into the major
plant
polyester fibres.
upgrades
Technique b.
Mention that technique b. is only relevant for PES-wool blends or alternatively that
the applicability is restricted by product specifications (EURATEX 87).
Technique c.
Summary
Specify the wording of the applicability restriction under alkaline conditions in line
of
with the information given in Section 4.5.4.2 of D1, as it is too vague (EEB 115).
comments:
To improve clarity, make the following changes:
o change the technique name to: “Optimised reduction of unfixed dye in batch
dyeing”;
o change first line of description of technique to read: “This includes: using a
reducing agent”;
142
March 2021
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
Background paper – Final meeting for the review of the TXT BREF
o change the last sentence of the applicability to read: “The use of alkali
reducable disperse dyes may be restricted by product specification.”
(UK 44).
Technique d.
Delete technique d. because this technique is not used in Europe (only one site in
Thailand uses it). In addition, there are concerns in terms of costs, security due to
high pressure, energy consumption, result of the dyeing process and emissions of CO2
to air (AT 44, FR_A 36, CZ_B 14, EURATEX 125).
Technique b.
The relevance of technique to PES-wool blends is already mentioned in the
description.
The name of the technique could reflect the concern to use the environmentally
friendly carriers.
Technique c.
Section 4.4.4.2 of D1 mentions that dyes that are desorbable in alkaline conditions do
not cover all shades and that it may not be applicable for disperse dyes with very high
fastness requirements. This could usefully specify the applicability restriction.
Technique c is not only about the reduction of unfixed dye but also about the
desorption of the dye which can be done without reduction (see the third bullet point).
The use of reducing agents is mentioned in the second bullet point.
Technique d.
According to Section 2.3.7.2.9 of the BREF Guidance (Commission Implementing
EIPPCB
Decision 2012/119/EU), an example plant can be located in the EU or the rest of the
assessment:
world. Not having an example plant in the EU does therefore not impede the
derivation of BAT. However, in the present case, it has limited the available
information.
Concerning the costs, Section 4.5.4.3 of D1 mentions lower operational costs than
conventional dyeing but high investment costs. No information is available about the
investment costs.
Concerning the energy consumption, Section 4.5.4.3 od D1 mentions that it is 20-
50 % lower compared to other water-based dyeing.
No information has been made available about safety issues or the efficiency of the
CO2-based dyeing process.
Concerning CO2 emissions, Section 4.5.4.3 of D1 mentions that 5 % of the CO2 is not
recovered and is therefore emitted. This does not bring useful information about the
environmental impact of this technique as it would be necessary to compare these
emissions with the CO2 emitted from the combustion plant which generates heat for a
water-based process (and expressed for example in kg of CO2 per kg of textiles
treated).
To specify the type of cariers to be used in the name of technique b
To specify the applicability restriction of technique c.
EIPPCB
To delete technique d.
proposal:
To add the research of information about the supercritical CO2 dyeing in the
“Recommendations for future work” in Chapter 7 of the BREF.
BZ/JR/JG/DDG/EIPPCB/TXT FM BP
March 2021
143
Background paper – Final meeting for the review of the TXT BREF
1.9
BAT conclusions for finishing
1.9.1
Finishing with flame-retardants
Location in
P. 752– Section 5.7.3 – BAT 49
D1:
BAT 49. In order to improve the overall environmental performance of finishing
with flame retardants, BAT is to use one or both of the techniques given below,
giving priority to technique a.
Technique
Description
Applicability