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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe
Date of issue/ Date of 

30-11-2016
Date of previous issue
17-05-2016
revision
SAFETY DATA SHEET
KIVISIL JULKISIVUMAALI
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier

Product name
KIVISIL JULKISIVUMAALI
Product code
353-s
Product description
Silicone emulsion paint.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use: Painting work
1.3 Details of the supplier of the safety data sheet
Manufacturer or Distributor
Tikkurila Oyj
P.O. Box 53
FI-01301 VANTAA
FINLAND 
Telephone +358 20 191 2000
e-mail address of person 
Tikkurila Oyj,
responsible for this SDS
Product Safety,
e-mail: [adresse e-mail]
1.4 Emergency telephone number
Telephone number
112
(24h)
Supplier or Manufacturer
Telephone number
Tikkurila Oyj
+358 20 191 2000  Mon-Fri 8-16
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Product definition
Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Aquatic Chronic 3, H412
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended.
2.2 Label elements
Signal word
No signal word.
Hazard statements
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements
General
Not applicable.
Prevention
P273 - Avoid release to the environment.
Response
Not applicable.
Storage
Not applicable.
Disposal
Not applicable.
Supplemental label 
Contains 1,2-benzisothiazol-3(2H)-one, reaction mass of: 5-chloro-2-methyl-
elements
4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no.
220-239-6] (3:1) and 4,5-dichloro-2-octyl-2H-isothiazol-3-one.  May produce an 
allergic reaction.
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Wear protective gloves.
Treated articles
This product contains a biocidal product for the preservation of the product during storage. Contains reaction mass of:
5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1).
2.3 Other hazards
Other hazards which do 
None known.
not result in classification
SECTION 3: Composition/information on ingredients
3.2 Mixtures

Mixture
Classification
Product/ingredient 
Identifiers
%
Regulation (EC) No.
Notes
name
1272/2008 [CLP]
4,5-dichloro-2-octyl-2H-isothiazol-
EC: 264-843-8
<0,1
Acute Tox. 4, H302
-
3-one
CAS: 64359-81-5
Acute Tox. 4, H312
Acute Tox. 2, H330
Skin Corr. 1C, H314
Skin Sens. 1A, H317
STOT SE 3, H335
Aquatic Acute 1, H400 (M=100)
Aquatic Chronic 1, H410 (M=10)
3-iodo-2-propynyl butylcarbamate
EC: 259-627-5
<0,1
Acute Tox. 4, H302
-
CAS: 55406-53-6
Acute Tox. 3, H331
Eye Dam. 1, H318
Skin Sens. 1, H317
STOT RE 1, H372 (larynx)
Aquatic Acute 1, H400 (M=10)
Aquatic Chronic 1, H410 (M=1)
1,2-benzisothiazol-3(2H)-one
EC: 220-120-9
<0,05
Acute Tox. 4, H302
-
CAS: 2634-33-5
Skin Irrit. 2, H315
Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 2, H411
reaction mass of: 5-chloro-2-methyl- CAS: 55965-84-9
<0,0015
Acute Tox. 3, H301
-
4-isothiazolin-3-one [EC no.
Acute Tox. 3, H311
247-500-7] and 2-methyl-2H-
Acute Tox. 3, H331
isothiazol-3-one [EC no. 220-239-6]
Skin Corr. 1B, H314
(3:1)
Skin Sens. 1, H317
Aquatic Acute 1, H400 (M=1)
Aquatic Chronic 1, H410 (M=1)
See Section 16 for the full 
text of the H statements 
declared above.

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and 
contribute to the classification of the substance and hence require reporting in this section.
There are no additional ingredients present which, within the current knowledge of the supplier and in the 
concentrations applicable, are classified as hazardous to health or the environment, are PBTs or vPvBs or have been 
assigned a workplace exposure limit and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Notes, if applicable, refer to Notes given in Annex VI of 1272/2008/EC.
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SECTION 4: First aid measures
4.1 Description of first aid measures

General
In all cases of doubt, or when symptoms persist, seek medical attention.  Show this 
safety data sheet or label to the doctor if possible.
Eye contact
Check for and remove any contact lenses.  Immediately flush eyes with plenty of 
lukewarm water, keeping eyelids open.  Continue to rinse for at least 10 minutes.
Inhalation
Remove to fresh air.
Skin contact
Wash skin thoroughly with soap and water or use recognized skin cleanser.  Do 
NOT use solvents or thinners.
Ingestion
If accidentally swallowed rinse the mouth with plenty of water (only if the person is 
conscious).  If significant amounts have been swallowed or if symptoms persist,
seek medical attention.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
Contains:
1,2-benzisothiazol-3(2H)-one
mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no.
220-239-6] (3:1)
4,5-dichloro-2-octyl-2H-isothiazol-3-one
May produce an allergic reaction.
4.3 Indication of any immediate medical attention and special treatment needed
None.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing 
Use an extinguishing agent suitable for the surrounding fire.  Recommended:
media
Alcohol resistant foam, CO₂, powders or water spray/mist.
Unsuitable extinguishing 
Do not use a direct water jet that could spread the fire.
media
5.2 Special hazards arising from the substance or mixture
Hazards from the 
This product is not classified as flammable.  Fire will produce dense black smoke.
substance or mixture
Exposure to decomposition products may cause a health hazard.
Hazardous combustion 
When exposed to high temperatures, hazardous decomposition products may be 
products
produced, such as carbon monoxide and dioxide, smoke, oxides of nitrogen etc.
5.3 Advice for firefighters
Special protective actions 
Use water spray to keep fire-exposed containers cool.  This material is hazardous to 
for fire-fighters
aquatic organisms.  Fire water contaminated with this material must be contained 
and prevented from being discharged to any waterway, sewer or drain.
Special protective 
Appropriate breathing apparatus may be required.
equipment for fire-fighters
SECTION 6: Accidental release measures
6.1 Personal precautions,

Refer to protective measures listed in sections 7 and 8.
protective equipment and 
emergency procedures

6.2 Environmental 
Hazardous to aquatic environment.  Do not allow to enter drains, water courses or 
precautions
soil.
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6.3 Methods and materials 
Contain and collect spillage with non-combustible, absorbent material e.g. sand,
for containment and 
earth, vermiculite or diatomaceous earth and place in container for disposal 
cleaning up
according to local regulations.  Preferably clean with water or detergent. Avoid using 
solvents.
6.4 Reference to other 
See Section 1 for emergency contact information.
sections
See Section 13 for additional waste treatment information.
SECTION 7: Handling and storage
7.1 Precautions for safe 

Skin contact with the product and exposure to spray mist and vapor should be 
handling
avoided.  Avoid inhalation of dust from sanding.  See Section 8 for information on 
appropriate personal protective equipment.  Eating, drinking and smoking should be 
prohibited in areas where this material is handled and stored.  Wash hands before 
breaks and immediately after handling the product.  Avoid release to the environment.
7.2 Conditions for safe 
Store in original container protected from direct sunlight in a dry, cool and well-
storage, including any 
ventilated area, away from incompatible materials (see Section 10) and food and 
incompatibilities
drink.  Keep container tightly closed.  Containers that have been opened must be 
carefully resealed and kept upright to prevent leakage.  Recommended storage 
temperature is +5°C ...+25°C.  Do not allow to freeze.  Store in accordance with local 
regulations.
7.3 Specific end use(s)
None.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Occupational exposure limits
No exposure limit value known.
Recommended monitoring  : If this product contains ingredients with exposure limits, personal, workplace 
procedures
atmosphere or biological monitoring may be required to determine the effectiveness 
of the ventilation or other control measures and/or the necessity to use respiratory 
protective equipment.
DNELs/DMELs
No DNELs/DMELs available.
PNECs
No PNECs available.
8.2 Exposure controls
Appropriate engineering controls
Provide adequate ventilation.  Comply with the health and safety at work laws.
Individual protection measures
Eye/face protection
Safety eyewear should be used when there is a likelihood of exposure.  Use safety 
eyewear (EN166), especially during spray-application.
Hand protection
Wear protective gloves.  Gloves should be replaced regularly and if there is any 
sign of damage to the glove material.  The instructions and information provided by 
the glove manufacturer on use, storage, maintenance and replacement must be 
followed.
Recommended glove material (EN374):
> 8 hours (breakthrough time): nitrile rubber
  Not recommended: PVA gloves
Skin protection
Wear appropriate personal protective clothing to prevent skin contact.
Respiratory protection
If ventilation during spray-application is inadequate, use respirators with 
combination filter AP, gas/dust filter (EN405:2001).  Wear a respirator with type P2 
filter during sanding  (EN149:2001).  Be sure to use an approved/certified respirator 
or equivalent.  Check that mask fits tightly and change filter regularly.
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Environmental exposure 
For information regarding environmental protection measures, please refer to 
controls
section 13 for waste handling, section 7 for handling and storage and section 1.2 
for relevant identified uses of the substance or mixture and uses advised against.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance
Physical state
Liquid.
Color
Various
Odor
Mild.
Odor threshold
Not relevant for the hazard assessment of the product.
pH
Not relevant for the hazard assessment of the product.
Melting point/freezing point
0°C (water)
Initial boiling point and 
100°C (water)
boiling range
Flash point

> 100 °C
Evaporation rate
Not relevant due the nature of the product.
Flammability (solid, gas)
Not applicable. Product is a liquid.
Upper/lower flammability or 
No flammable ingredients present.
explosive limits
Vapor pressure

3,2 kPa [room temperature] (water)
Vapor density
Not relevant for the hazard assessment of the product.
Density
1,5 g/cm³
Solubility(ies)
Miscible in water.
Partition coefficient: n-octanol/ : Not available.
water
Auto-ignition temperature

Not relevant due the nature of the product.
Decomposition temperature
Not relevant for the hazard assessment of the product.
Viscosity
Not relevant for the hazard assessment of the product.
Explosive properties
No explosive ingredients present.
Oxidizing properties
No oxidizing ingredients present.
9.2 Other information
No additional information.
SECTION 10: Stability and reactivity
10.1 Reactivity

See Section 10.5.
10.2 Chemical stability
Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of 
Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid
Avoid extreme heat and freezing.
10.5 Incompatible materials
Keep away from the following materials to prevent strong exothermic reactions:
oxidizing agents
strong acids
strong alkalis
10.6 Hazardous 
When exposed to high temperatures, hazardous decomposition products may be 
decomposition products
produced, such as carbon monoxide and dioxide, smoke, oxides of nitrogen etc.
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SECTION 11: Toxicological information
11.1 Information on toxicological effects

There is no testdata available on the product itself.
The product is not classified as hazardous according to Regulation (EC) 1272/2008 as amended.
Long term exposure to spray mist may produce respiratory tract irritation.  Prolonged or repeated contact can defat 
the skin and lead to irritation, cracking and/or dermatitis.
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
4,5-dichloro-2-octyl-2H-
LD50 Oral
Rat
1636 mg/kg
-
isothiazol-3-one
3-iodo-2-propynyl 
LD50 Oral
Rat
1470 mg/kg
-
butylcarbamate
1,2-benzisothiazol-3(2H)-
LD50 Oral
Rat
1020 mg/kg
-
one
reaction mass of: 5-chloro-
LD50 Oral
Rat
53 mg/kg
-
2-methyl-4-isothiazolin-
3-one [EC no. 247-500-7]
and 2-methyl-2H-isothiazol-
3-one [EC no. 220-239-6] (3:
1)
Not classified.
Irritation/Corrosion
Not classified.
Sensitization
The product is not classified as sensitizing by skin contact, but it contains following preservatives or other biocides 
which may produce an allergic reaction:
1,2-benzisothiazol-3(2H)-one
mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H -isothiazol-3-one [EC no.
220-239-6] (3:1)
2-methyl-2H-isothiazol-3-one
3-iodo-2-propynyl butylcarbamate
2,2'-dithiobis[N-methylbenzamide]
4,5-dichloro-2-octyl-2H-isothiazol-3-one
Mutagenicity
Not classified.
Carcinogenicity
Not classified.
Reproductive toxicity
Not classified.
Teratogenicity
Not classified.
Specific target organ toxicity (single exposure)
Not classified.
Specific target organ toxicity (repeated exposure)
Not classified.
Aspiration hazard
Not classified.
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SECTION 12: Ecological information
Ecological testing has not been conducted on this product.
Do not allow to enter drains, water courses or soil.
 
The product is classified as environmetally hazardous according to Regulation (EC) 1272/2008.
Harmful to aquatic life with long lasting effects.
12.1 Toxicity
Product/ingredient name
Result
Species
Exposure
4,5-dichloro-2-octyl-2H-
Acute EC50 0,003 mg/l Fresh water
Algae - Pseudokirchneriella 
72 hours
isothiazol-3-one
subcapitata
Acute EC50 0,004 mg/l Fresh water
Daphnia - Daphnia magna -
48 hours
Neonate
3-iodo-2-propynyl 
EC50 0,053 mg/l
Algae
72 hours
butylcarbamate
EC50 0,16 mg/l
Daphnia
48 hours
LC50 0,067 mg/l
Fish
96 hours
NOEC 0,05 mg/l
Daphnia - Daphnia magna
21 days
1,2-benzisothiazol-3(2H)-one Acute EC50 0,36 mg/l
Algae - Skeletonema costatum
72 hours
Acute LC50 0,74 mg/l
Fish
96 hours
reaction mass of: 5-chloro-
Acute EC50 0,379 mg/l
Algae - Pseudokirchneriella 
72 hours
2-methyl-4-isothiazolin-
subcapitata
3-one [EC no. 247-500-7]
and 2-methyl-2H-isothiazol-
3-one [EC no. 220-239-6] (3:
1)
Acute EC50 0,16 mg/l
Daphnia - Daphnia magna
48 hours
Acute LC50 0,19 mg/l
Fish - Oncorhynchus mykiss
96 hours
Chronic NOEC 0,0012 mg/l
Algae - Pseudokirchneriella 
72 hours
subcapitata
Chronic NOEC 0,004 mg/l
Daphnia - Daphnia magna
21 days
12.2 Persistence and 
degradability

Product/ingredient name
Aquatic half-life
Photolysis
Biodegradability
reaction mass of: 5-chloro-
-
-
Readily
2-methyl-4-isothiazolin-
3-one [EC no. 247-500-7]
and 2-methyl-2H-isothiazol-
3-one [EC no. 220-239-6] (3:
1)
12.3 Bioaccumulative 
No specific data.
potential
12.4 Mobility in soil
Soil/water partition 
Not available.
coefficient (KOC)
Mobility

Not available.
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12.5 Results of PBT and vPvB assessment
PBT
Not applicable.
vPvB
Not applicable.
12.6 Other adverse effects
Not available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product
Methods of disposal
Remove as much product as possible from the tools before cleaning.  Liquid residue 
and cleaning liquids are hazardous waste and must not be emptied into drains or 
sewage system, but handled in accordance with national regulations.  Product 
residues should be left at special companies which have permission for gathering 
this kind of wastes.
European waste catalogue (EWC)
Waste code
Waste designation
08 01 11*
waste paint and varnish containing organic solvents or other hazardous substances
If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate 
code should be assigned.  For further information, contact your local waste authority.
Packaging
Methods of disposal
Empty packaging should be recycled or disposed of in accordance with national 
regulations.
Special precautions
No additional information.
SECTION 14: Transport information
This product is not regulated for carriage according to ADR/RID, IMDG, IATA.
ADR/RID
IMDG
IATA
14.1 UN number
Not regulated.
Not regulated.
Not regulated.
14.2 UN proper 
-
-
-
shipping name
14.3 Transport 
-
-
-
hazard class(es)
14.4 Packing 
-
-
-
group
14.5 
No.
No.
No.
Environmental 
hazards

Additional 
-
-
-
information
14.6 Special precautions for  : Transport within user’s premises: always transport in closed containers that are 
user
upright and secure. Ensure that persons transporting the product know what to do in 
the event of an accident or spillage.
14.7 Transport in bulk 
Not available.
according to Annex II of 
MARPOL and the IBC Code

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SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

EU Regulation (EC) No. 1907/2006 (REACH)
Other EU regulations

Europe inventory
Not determined.
VOC Directive
This product is in scope of Directive 2004/42/CE.
15.2 Chemical Safety 
This product contains substances for which Chemical Safety Assessments are still 
Assessment
required.
SECTION 16: Other information
Indicates information that has changed from previously issued version.
Abbreviations and 
ATE = Acute Toxicity Estimate
acronyms
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No.
1272/2008]
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = CLP-specific Hazard statement
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification
Justification
Aquatic Chronic 3, H412
Calculation method
Full text of abbreviated H 
H301
Toxic if swallowed.
statements
H302
Harmful if swallowed.
H311
Toxic in contact with skin.
H312
Harmful in contact with skin.
H314
Causes severe skin burns and eye damage.
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H318
Causes serious eye damage.
H330
Fatal if inhaled.
H331
Toxic if inhaled.
H335
May cause respiratory irritation.
H372
Causes damage to organs through prolonged or repeated exposure.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
H411
Toxic to aquatic life with long lasting effects.
H412
Harmful to aquatic life with long lasting effects.
Full text of classifications 
Acute Tox. 2, H330
ACUTE TOXICITY (inhalation) - Category 2
[CLP/GHS]
Acute Tox. 3, H301
ACUTE TOXICITY (oral) - Category 3
Acute Tox. 3, H311
ACUTE TOXICITY (dermal) - Category 3
Acute Tox. 3, H331
ACUTE TOXICITY (inhalation) - Category 3
Acute Tox. 4, H302
ACUTE TOXICITY (oral) - Category 4
Acute Tox. 4, H312
ACUTE TOXICITY (dermal) - Category 4
Aquatic Acute 1, H400
AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1, H410 AQUATIC HAZARD (LONG-TERM) - Category 1
Aquatic Chronic 2, H411 AQUATIC HAZARD (LONG-TERM) - Category 2
Aquatic Chronic 3, H412 AQUATIC HAZARD (LONG-TERM) - Category 3
Eye Dam. 1, H318
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
Skin Corr. 1B, H314
SKIN CORROSION/IRRITATION - Category 1B
Skin Corr. 1C, H314
SKIN CORROSION/IRRITATION - Category 1C
Skin Irrit. 2, H315
SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1, H317
SKIN SENSITIZATION - Category 1
Skin Sens. 1A, H317
SKIN SENSITIZATION - Category 1A
STOT RE 1, H372
SPECIFIC TARGET ORGAN TOXICITY (REPEATED 
EXPOSURE) - Category 1
STOT SE 3, H335
SPECIFIC TARGET ORGAN TOXICITY (SINGLE 
EXPOSURE) (Respiratory tract irritation) - Category 3
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Date of issue/ Date of 
30-11-2016
revision
Date of previous issue

17-05-2016
Version
2.01
Notice to reader
This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No 1907/2006 (REACH). The 
information contained in this Safety Data Sheet is based on the present state of knowledge and current EU 
and national legislation. It provides guidance on health, safety and environmental aspects of the product and 
should not be construed as any guarantee of  technical performance or suitability for particular applications.

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